Reduced puffing needle coke from coal tar
View Patent ↗A reduced puffing needle coke is formed, which includes a lesser amount of nitrogen within the coke so that carbon articles produced from such coke experience minimal expansion upon heating to graphitization temperatures.
1. A calcined reduced puffing needle coke derived from coal tar comprising needle coke with a nitrogen content of less than about 0.2% nitrogen and a coefficient of thermal expansion of below about 2.0 cm/cm ° C.*10 −7 .
2. The needle coke of claim 1 , which has a coefficient of thermal expansion below about 1.25 cm/cm ° C.*10 −7 .
3. The needle coke of claim 2 , which has a coefficient of thermal expansion below about 1.0 cm/cm ° C.*10 −7 .
4. The needle coke of claim 1 , which has a nitrogen content of from about 0.03% to less than about 0.2% by weight and a sulfur content of less than about 1.0% by weight.
5. A graphite electrode formed using a calcined reduced puffing needle coke derived from coal tar comprising needle coke with a nitrogen content of less than about 0.4% nitrogen and a coefficient of thermal expansion of below about 2.0 cm/cm ° C.*10 −7 .
6. The graphite electrode of claim 5 , formed using a calcined reduced puffing needle coke derived from coal tar comprising needle coke with a nitrogen content of less than about 0.4% nitrogen and needle cokes not derived from coal tar comprising needle coke with a nitrogen content of less than about 0.4% nitrogen.