Styrene butadiene rubber with novel styrene incorporation
View Patent ↗The present invention relates to improved compositions of SSBR rubber. The improved compositions exhibit sufficient or improved balance of characteristics such as rolling resistance, HBU, abrasion, grip, and/or tear. The compositions may be made in an efficient, cost-effective manner.
1. A composition comprising a styrene butadiene rubber wherein the styrene butadiene rubber is characterized before any vulcanization by the following:
(a) two or more portions in one polymer chain which are incompatible with each other;
(b) two or more glass transition temperatures that vary by at least about 6° C.;
(c) two or more δ (SBR) values which differ by at least more than about 0.65 (J/cm 3 ) 0.5 ; and
(d) two or more portions which vary in styrene content based on the total weight of each portion by at least about 20 weight percent;
wherein the styrene butadiene rubber comprises at least a portion which is compatible with a second rubber and a portion which is not compatible with said same second rubber;
wherein at least a portion of the styrene butadiene rubber is chain end functionalized, and
wherein the portion of the styrene butadiene rubber that is chain end functionalized comprises less styrene content than a portion of the styrene butadiene rubber that is not chain end functionalized.
2. The composition of claim 1 wherein the styrene butadiene rubber is characterized by (b) two or more glass transition temperatures that vary by at least about 8° C.
3. The composition of claim 1 wherein the styrene butadiene rubber is characterized by (b) two or more glass transition temperatures that vary by at least about 9° C.
4. The composition of claim 1 wherein the styrene butadiene rubber is coupled in an amount up to 40% by weight based on the total weight of the rubber as determined by size exclusion chromatography.
5. The composition of claim 1 wherein the styrene butadiene rubber is characterized by a ML 1+4 of from about 20 to about 120 at 100° C.
6. The composition of claim 1 wherein the styrene butadiene rubber comprises a portion in the polymer chain which comprises a styrene content of from about 0 to about 27 weight percent based on the total weight of the first portion and a second portion in the polymer chain which comprises a styrene content of from about 21 to about 70 weight percent based on the total weight of the second portion.
7. The composition of claim 1 which comprises a first portion in the polymer chain which is incompatible with a second portion in the polymer chain wherein the weight ratio of said first portion to said second portion is from about 90:10 to about 10:90.
8. The composition of claim 1 which further comprises a second rubber compound.
9. A vulcanized composition comprising the styrene butadiene rubber of claim 1 and at least one other rubber wherein:
(1) the absolute value of the difference between the solubility parameter 6 (rubber) and the solubility parameter δ (SSBR, portion i) of at least one portion of styrene butadiene rubber of claim 1 is lower than about 0.65 (J/cm 3 ) 0.5 and;
(2) the absolute value of the difference between the solubility parameter δ (rubber) and the solubility parameter δ (SSBR, portion j) of at least one portion of styrene butadiene rubber of claim 1 is higher than about 0.65 (J/cm 3 ) 0.5 .
10. The composition of claim 8 wherein said second rubber compound is selected from the group consisting of natural rubber, cis-polybutadiene, emulsion polymerized styrene-butadiene rubber, high vinyl polybutadiene, and mixtures thereof.
11. The composition of claim 1 which further comprises at least one filler.
12. The composition of claim 11 wherein the filler comprises carbon black or silica.
13. The composition of claim 1 wherein the composition is vulcanized.
14. The composition of claim 13 wherein upon vulcanization the vulcanized composition is characterized by at least two maxima in the tan delta course with the temperature.
15. The composition of claim 1 wherein for the (d) two or more portions which vary in styrene content based on the total weight of each portion by at least about 20 weight percent, the portion with the higher styrene content has a lower vinyl content than the portion with the lower styrene content.
16. The composition of claim 1 wherein the styrene butadiene rubber does not include isoprene and is characterized by (b) only two glass transition temperatures that vary by at least about 6° C.
17. The composition of claim 1 , wherein the styrene-butadiene rubber is characterized by (d) two or more portions each comprising styrene and butadiene and which vary in styrene content, based on the total weight of each portion, by at least about 20 weight percent.