Graphene nano-sheets and methods for making the same
View Patent ↗Various embodiments provide materials and methods for forming a graphene product by vacuum induction heating expandable graphite. The graphene product can include graphene nano-sheets with high purity and uniform thickness. The graphene nano-sheets can contain carbon of more than about 99% by weight. The graphene nano-sheets can be exfoliated or dispersed within a matrix of a semiconducting polymer to form a graphene-containing composite.
1. A method of making graphene nano-sheets, comprising:
placing an expandable graphite within a chamber;
applying vacuum to the chamber, such that a vacuum pressure in the chamber ranges from about 10 −1 mbar to about 10 −7 mbar in the chamber;
applying an electric current to induction heat the expandable graphite within the chamber under the vacuum to form an expanded graphite; and
exfoliating the expanded graphite in a solvent to form one or more graphene nano-sheets dispersed in the solvent.
2. The method of claim 1 , further comprising expanding the expandable graphite by about 200% to about 1000% by volume within the chamber to form the expanded graphite.
3. The method of claim 1 , wherein the expandable graphite is heated to a temperature ranging from about 500° C. to about 1100° C.
4. The method of claim 3 , wherein the expandable graphite is heated at the temperature for a time length ranging from about 1 second to about 5 minutes.
5. The method of claim 1 , wherein the expandable graphite comprises an intercalation agent.
6. The method of claim 5 , wherein the intercalation agent is selected from the group consisting of halogens, alkali metals, sulfate, nitrate, acids, metal halides, and combinations thereof.
7. A method of making a graphene product comprising:
placing expandable graphite within a chamber, the expandable graphite comprising an intercalation agent capable of producing thermal expansion;
applying vacuum to the chamber, wherein a vacuum pressure ranges from about 10 −1 mbar to about 10 −7 mbar in the chamber;
applying an electric current to induction heat the expandable graphite under the vacuum to form expanded graphite; and
exfoliating the expanded graphite in a solvent to forms one or more graphene nano-sheets dispersed in the solvent.
8. The method of claim 7 , wherein the electric current is applied to reach a heating temperature ranging from 500° C. to about 1100° C.
9. The method of claim 7 , wherein each of the one or more graphene nano-sheets is formed to have an average thickness ranging from about 0.3 nm to about 15 nm.
10. The method of claim 7 , wherein the one or more graphene nano-sheets are substantially free of impurity species comprising S, N, Cl, O atoms, or their combinations.
11. The method of claim 7 , wherein the one or more graphene nano-sheets comprise carbon of at least about 99% by weight.
12. The method of claim 7 , wherein the step of exfoliating the expanded graphite comprises sonicating the expanded graphite to form the one or more graphene nano-sheets in the solvent.
13. The method of claim 7 , wherein the solvent comprises toluene, chiorotoluene, chlorobenzene, dichlorobenzene, xylene, mesitylene, chloroethane, chloromethane, dimethylformamide (DMF), N-Methyl-2-pyrrolidone (NMP), or combinations thereof.
14. The method of claim 7 , wherein the step of exfoliating the expanded graphite is carried out in a presence of a conjugated polymer.
15. The method of claim 14 , wherein the conjugated polymer comprises a polythiophene.
16. The method of claim 14 , further comprising coating the graphene dispersion on a substrate to form a graphene-containing composite comprising the one or more graphene nano-sheets dispersed in a matrix of the conjugated polymer.
17. The method of claim 14 , wherein the one or more graphene nano-sheets are present in an, amount ranging from about 0.001% to about 5.0% by weight of a total of the one or more graphene nano-sheets and the conjugate polymer.