IP Library Granted Patent US 8,753,231
Granted Patent B2
US 8,753,231 · App. 13/335,084 · Granted Jun 17, 2014

Golf ball having a thermoplastic positive hardness gradient inner core layer and a thermoset shallow positive hardness gradient outer core layer

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Quick Facts
Patent No.
US 8,753,231
App. No.
13/335,084
Granted
Jun 17, 2014
Kind
B2
Abstract

A golf ball has an inner core layer including a thermoplastic highly-neutralized ionomer and having a geometric center hardness less than a surface hardness to define a first positive hardness gradient. An outer core layer is formed about the inner core and includes a homogenous thermoset composition. The outer core has an interior hardness less than an outer surface hardness to define a second positive hardness gradient. An inner and outer cover layers are disposed about outer core layer. The first and second hardness gradients each have a slope and the slope of the second hardness gradient is less than the slope of the first hardness gradient such that a ratio of the first and second slopes is 0.8 to 0.85.

Claims (23)

1. A golf ball comprising:

an inner core layer comprising a thermoplastic highly-neutralized ionomer comprising a copolymer of ethylene and an α,β-unsaturated carboxylic acid, an organic acid or salt thereof, and sufficient cation source to neutralize the acid groups of the copolymer by 80% or greater, and having a geometric center hardness less than a surface hardness to define a first positive hardness gradient;

an outer core layer disposed about the inner core, the outer core being formed from a homogenous thermoset composition and having an interior hardness less than an outer surface hardness to define a second positive hardness gradient;

an inner cover layer disposed about outer core layer; and

an outer cover layer disposed about the inner cover layer,

wherein the first and second hardness gradients each have a slope and the slope of the second hardness gradient is less than the slope of the first hardness gradient such that a ratio of the first and second slopes is 0.8 to 0.85.

2. The golf ball of claim 1 , wherein the ratio of the first and second slopes is 0.8 to 0.83.

3. The golf ball of claim 2 , wherein the ratio of the first and second slopes is 0.81 to 0.82.

4. The golf ball of claim 1 , wherein the slope of the first hardness gradient is greater than about 1 and the slope of the second hardness ratio is less than about 1.

5. The golf ball of claim 4 , wherein the slope of the first hardness gradient is greater than about 1.15 and the slope of the second hardness ratio is less than about 0.98.

6. The golf ball of claim 1 , wherein the inner core layer has an outer diameter of about 0.5 inches to about 1.13 inches.

7. The golf ball of claim 1 , wherein the acid groups of the copolymer are neutralized by 90% or greater.

8. The golf ball of claim 7 , wherein the acid groups of the copolymer are neutralized by about 100%.

9. The golf ball of claim 1 , wherein the organic acid or salt thereof comprises barium, lithium, sodium, zinc, bismuth, chromium, cobalt, copper, potassium, strontium, titanium, tungsten, magnesium, cesium, iron, nickel, silver, aluminum, tin, or calcium salts, or salts of fatty acids.

10. The golf ball of claim 9 , wherein the fatty acid salt comprises stearic acid, behenic acid, erucic acid, oleic acid, linoelic acid or dimerized derivatives thereof.

11. The golf ball of claim 9 , wherein the organic acid or salt thereof comprises a magnesium salt of oleic acid.

12. The golf ball of claim 1 , wherein the outer core layer comprises a soft and fast agent.

13. The golf ball of claim 12 , wherein the soft and fast agent comprises a halogenated thiophenol.

14. A golf ball comprising:

an inner core layer consisting of a thermoplastic material and having a geometric center hardness less than a surface hardness to define a first positive hardness gradient having a slope of about 1.15 or greater;

an outer core layer disposed about the inner core, the outer core being formed from a substantially homogenous thermoset composition comprising a diene rubber and having a second positive hardness gradient having a slope of about 0.98 or less;

a cover layer disposed outer core layer, the cover layer comprising an inner cover layer comprising an ionomer and an outer cover layer comprising a castable polyurethane or polyurea material.

15. The golf ball of claim 14 , wherein a ratio of the second positive hardness gradient to the first positive hardness gradient is about 0.8 to 0.85.

Assignments (6)
SECURITY INTEREST Recorded Aug 3, 2022
From: ACUSHNET COMPANY
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 061099/0236 →
ASSIGNMENT OF SECURITY INTEREST IN PATENTS (ASSIGNS 039506-0030) Recorded Aug 3, 2022
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS RESIGNING ADMINISTRATIVE AGENT
To: JPMORGAN CHASE BANK, N.A., AS SUCCESSOR ADMINISTRATIVE AGENT
Reel/Frame 061521/0414 →
RELEASE OF SECURITY INTEREST IN PATENTS PREVIOUSLY RECORDED AT REEL/FRAME (027853/0350) Recorded Sep 7, 2016
From: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
To: ACUSHNET COMPANY
Reel/Frame 039939/0315 →
SECURITY INTEREST Recorded Jul 28, 2016
From: ACUSHNET COMPANY
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 039506/0030 →
SECURITY AGREEMENT Recorded Mar 13, 2012
From: ACUSHNET COMPANY
To: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
Reel/Frame 027853/0350 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 14, 2012
From: SULLIVAN, MICHAEL J.; COMEAU, BRIAN
To: ACUSHNET COMPANY
Reel/Frame 027699/0595 →