Breaking viscoelastic surfactant gelled fluids using breaker nanoparticles
View Patent ↗Breaker nanoparticles may be added to gelled aqueous fluids where the gelled aqueous fluid may include an aqueous base fluid, e.g. a drilling fluid, gelled with at least one viscoelastic surfactant (VES) in an amount to increase the viscosity of the aqueous base fluid. The addition of the breaker nanoparticles may reduce the viscosity, or break the gel, of the gelled aqueous fluid by the direct or indirect action of the breaker nanoparticles. The breaker nanoparticles may be or include, but are not limited to inorganic semiconductor particles, organic semiconductor particles, and combinations thereof. The inorganic semiconductor particles may be or include, but are not limited to cupric oxide, cuprous oxide, silicon, silicon carbide, germanium, and gallium arsenide, indium antimonide, gallium nitride, and combinations thereof; wherein the organic semiconductors selected from the group consisting of pentacene, anthracene, rubrene, poly(3-hexylthiophene), poly(p-phenylene vinylene), polypyrrole, polyaniline, and combinations.
1. A method for breaking the viscosity of a gelled aqueous fluid where the gelled aqueous fluid comprises an aqueous fluid gelled with at least one viscoelastic surfactant (VES), wherein the method comprises adding breaker nanoparticles to a gelled aqueous fluid, wherein the breaker nanoparticles are added to the gelled aqueous fluid in an effective amount to decrease the viscosity of the gelled aqueous fluid as compared to a gelled aqueous fluid absent the breaker nanoparticles; and wherein the breaker nanoparticles are selected from the group consisting of cupric oxide, cuprous oxide, inorganic semiconductors, organic semiconductors, and combinations thereof.
2. The method of claim 1 , wherein the inorganic semiconductors selected from the group consisting of silicon, silicon carbide, germanium, gallium arsenide, indium antimonide, gallium nitride, and combinations thereof; wherein the organic semiconductors selected from the group consisting of pentacene, anthracene, rubrene, poly(3-hexylthiophene), poly(p-phenylene vinylene), polypyrrole, polyaniline, and combinations thereof.
3. The method of claim 1 , wherein the effective amount of the breaker nanoparticles added to the gelled aqueous fluid ranges from about 0.1pptg to about 100 pptg.
4. The method of claim 1 , wherein the average size of the breaker nanoparticles is less than about 1000 nm.
5. The method of claim 1 , wherein the VES is selected from the group consisting of non-ionic, cationic, amphoteric, and zwitterionic surfactants and combinations thereof.
6. The method of claim 1 , wherein the VES surfactant is selected from the group consisting of quaternary ammonium salts, amidoamine oxides, dihydroxyl alkyl glycinate; alkyl ampho acetate or propionate; alkyl betaine; alkyl amidopropyl betaine and alkylimino mono- or di-propionates derived from certain waxes, fats and oils; and combinations thereof.
7. A method for breaking the viscosity of a gelled aqueous fluid where the gelled aqueous fluid comprises an aqueous base fluid gelled with at least one viscoelastic surfactant (VES), wherein the method comprises adding breaker nanoparticles to the gelled aqueous fluid in an amount ranging from about 0.1 pptg to about 100 pptg to decrease the viscosity of the gelled aqueous fluid; and wherein the breaker nanoparticles are selected from the group consisting of cupric oxide, cuprous oxide, inorganic semiconductors, organic semiconductors, and combinations thereof; wherein the inorganic semiconductors selected from the group consisting of silicon, silicon carbide, germanium, gallium arsenide, indium antimonide, gallium nitride, and combinations thereof; wherein the organic semiconductors selected from the group consisting of pentacene, anthracene, rubrene, poly(3-hexylthiophene), poly(p-phenylene vinylene), polypyrrole, polyaniline, and combinations; and
wherein the VES is selected from the group consisting of non-ionic, cationic, amphoteric, and zwitterionic surfactants and combinations thereof.
8. The method of claim 7 , wherein the average size of the breaker nanoparticles is less than about 1000 nm.
9. The method of claim 7 , wherein the VES surfactant is selected from the group consisting of quaternary ammonium salts, amidoamine oxides, dihydroxyl alkyl glycinate; alkyl ampho acetate or propionate; alkyl betaine; alkyl amidopropyl betaine and alkylimino mono- or di-propionates derived from certain waxes, fats and oils; and combinations thereof.