Carbon-deuterium protective overcoat layer
A substrate having a carbon-deuterium protective overcoat layer, and method for making the same. In some embodiments, the substrate includes a recording structure having a magnetic recording layer. A protective overcoat layer is Formed on the recording structure, the protective overcoat layer composed of carbon-carbon (C—C) and carbon-deuterium (C-D) bonds and having no carbon-hydrogen (C—H) bonds.
1. An apparatus, comprising:
a base substrate;
a recording structure in contact with the base substrate comprising a magnetic recording layer; and
a protective overcoat layer in contact with the recording structure, the protective overcoat layer composed of carbon-carbon (C—C) and carbon-deuterium (C-D) bonds and having no carbon-hydrogen (C—H) bonds, the protective overcoat layer comprising C 2 D 4 and having a bond strength of at least about 110 kcal/mole.
2. The apparatus of claim 1 , further comprising a layer of lubricant in contact with the protective overcoat layer on a side opposite the recording structure.
3. The apparatus of claim 1 , characterized as a heat assisted magnetic recording (HAMR) recording medium.
4. The apparatus of claim 1 , in which the recording structure further comprises a heat sink layer and a magnetically permeable return layer.
5. The apparatus of claim 1 , in which the protective overcoat layer is formed by introducing a feed gas into a deposition chamber having an ionization source, the feed gas having a stoichiometry of CpDq, where p is equal to two and q is equal to four.
6. The apparatus of claim 1 , in which the protective overcoat layer is formed using a direct current (DC) arc plasma source.
7. The apparatus of claim 1 , wherein the protective overcoat layer has a thickness of from about 0.5 nanometers (nm) to about 5.0 nm.
8. The apparatus of claim 5 , wherein the protective overcoat layer is further formed by evacuating the chamber prior to introduction of the feed gas so that the chamber is devoid of hydrogen during the deposition of the protective overcoat layer.
9. The apparatus of claim 1 , wherein the recording structure comprises a ferromagnetic recording layer of a heat assisted magnetic recording (HAMR) data recording medium, and the protective overcoat layer is formed directly on the recording layer.
10. The apparatus of claim 9 , in which the recording structure further comprises a heat sink layer and a magnetically permeable return layer, wherein the heat sink layer is disposed between the recording layer and the return layer.
11. An apparatus comprising a protective overcoat layer supported by a magnetic recording layer, the protective overcoat layer composed of carbon-carbon (C—C) and carbon-deuterium (C-D) bonds with no carbon-hydrogen (C—H) bonds, the protective overcoat layer comprising C 2 D 4 and having a bond strength of at least about 110 kcal/mole.
12. The apparatus of claim 11 , further comprising a substrate which supports the magnetic recording layer.
13. The apparatus of claim 11 , further comprising a layer of lubricant in contact with the protective overcoat layer on a side opposite the magnetic recording layer.
14. The apparatus of claim 11 , characterized as a heat assisted magnetic recording (HAMR) recording medium.
15. The apparatus of claim 11 , further comprising a heat sink layer and a magnetically permeable return layer adjacent the magnetic recording layer on a side opposite the protective overcoat layer.
16. The apparatus of claim 11 , in which the protective overcoat layer is formed by introducing a feed gas into a deposition chamber having an ionization source, the feed gas having a stoichiometry of CpDq, where p is equal to two and q is equal to four.
17. The apparatus of claim 11 , in which the protective overcoat layer is formed using a direct current (DC) arc plasma source.
18. The apparatus of claim 11 , wherein the protective overcoat layer has a thickness of from about 0.5 nanometers (nm) to about 5.0 nm.
19. The apparatus of claim 11 , wherein the protective overcoat layer is deposited onto the magnetic recording layer using an ion beam supplied with a current of from about 10 milliamps (mA) to about 100 mA and a voltage of from about 100 electron volts (eV) and about 2 , 000 eV.
20. The apparatus of claim 11 , characterized as a heat assisted magnetic recording (HAMR) recording medium, wherein the protective overcoat layer has an overall thickness of from about 0.5 nanometers (nm) to about 2.5 nm.