Organosilane condensate coating composition
Organosilane condensates are described as well as their use in coating compositions, processes for making them and process for applying the coating compositions. The organosilane condensates can be formed from the hydrolysis of at least one medium to long chain trialkoxy silane compound, an amino silane and optionally one or more additional reactants. Coating compositions containing the organosilane condensates can provide coatings having improved scratch and mar resistance and can have excellent recoat adhesion.
1. A solvent-based coating composition comprising:
A) a pre-formed organosilane condensate,
wherein the pre-formed organosilane condensate consists of a reaction product that is formed by hydrolysis of a reaction mixture that consists of mixture ingredients (1) - (6) as follows:
(1) a medium to long chain trialkoxy silane selected from the group consisting of:
propyltrimethoxysilane and gamma-glycidoxypropyltrimethoxysilane, and combinations thereof,
(2) water and optionally one or more solvents,
(3) about 0.03 percent to about 1 percent by weight, based on total weight of the medium to long chain trialkoxy silane, of 3-(2-aminoethylamino)propyl trialkoxysilane,
(4) at least one silicon-containing additional reactant compound including at least a tetraalkyl orthosilicate and optionally one or more of: at least one di-alkoxy or mono-alkoxy silane, silane functional polymers, and colloidal silica,
(5) at least one acid catalyst, and
(6) optionally a further medium to long chain trialkoxy silane according to the formula: (RO) 3 —Si—R 1 , wherein R 1 is an unsubstituted alkyl group having 3 to 20 carbon atoms, wherein the hydrolysis reaction is carried out by stirring the reaction mixture for more than two minutes up to 24 hours at a temperature of from 30° C. to 90° C.;
B) a film-forming binder that is different from the pre-formed organosilane condensate, wherein the pre-formed organosilane condensate is present in an amount of from 1% to 30% by total weight of the film-forming binder;
C) optionally one or more of moisture scavengers, UV stabilizers or screeners present in an amount of about 0.1% to 10% by total weight of the film-forming binder, pigments, and rheology control agents; and
D) at least one organic solvent in addition to the optional one or more solvents of component A(1).
2. The coating composition of claim 1 wherein the film-forming binder comprises a crosslinkable component and a crosslinking component;
wherein the crosslinkable component is a compound, oligomer and/or polymer comprising one or more functional groups selected from the group consisting of hydroxyl groups, amine groups, epoxy groups, carboxylic acid groups, anhydride groups, aspartate groups, acetoacetate groups, orthoester groups, thiol groups and a combination thereof; and
wherein the crosslinking component is a compound, oligomer and/or polymer comprising one or more of carboxylic acid groups, anhydride groups, isocyanate groups, blocked isocyanate groups or wherein the crosslinking component is a melamine resin or wherein the crosslinking component comprises combinations thereof.
3. The coating composition of claim 1 wherein the coating composition is a clearcoat composition.
4. The coating composition of claim 1 , wherein the pre-formed organosilane condensate has a number average molecular weight (M n ) of about 800 to 2946.
5. The coating composition of claim 1 , wherein the pre-formed organosilane condensate comprises particles with an average particle size of 1 nanometer to 6 microns.
6. The coating composition of claim 1 , wherein the pre-formed organosilane condensate has a polydispersity of 1.81 to 5.01.