IP Library Granted Patent US 9,068,035
Granted Patent B2
US 9,068,035 · App. 13/577,271 · Granted Jun 30, 2015

Liquid coating composition containing a latent catalyst

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Quick Facts
Patent No.
US 9,068,035
App. No.
13/577,271
Granted
Jun 30, 2015
Kind
B2
Abstract

A liquid coating composition containing a crosslinkable binder A, as an optional component a crosslinker B for the binder A, and a latent catalyst C, wherein C is a carboxyl-functional resin which is present in the liquid coating composition as particles having a melting temperature of 40 to 180° C., measured by DSC at a heating rate of 10 K/min.

Claims (13)

1. A liquid coating composition containing a crosslinkable binder A, as an optional component a crosslinker B for the binder A, and a latent catalyst C, wherein C is a carboxyl-functional resin which is present in the liquid coating composition as particles having a melting temperature of 40 to 180° C., measured by DSC at a heating rate of 10 K/min, wherein the crosslinkable binder A is a hydroxyl-functional binder that has a hydroxyl value of from about 60 to about 300 mg of KOH/g, and wherein the crosslinkable binder A is a liquid at room temperature, wherein the liquid coating composition is free of an epoxy-functional component.

2. The coating composition of claim 1 containing organic solvent(s) and/or water and having a solids content of 35 to 75 wt. %, wherein the solids content consists of the resin solids content, the latent catalyst C and optional components: pigments, fillers and further non-volatile additives.

3. The coating composition of claim 1 , wherein the binder A is a self-crosslinkable binder.

4. The coating composition of claim 1 , wherein the crosslinker B is selected from the group consisting of aminoplast crosslinkers and free polyisocyanate crosslinkers.

5. The coating composition of claim 1 , wherein the catalyst C is contained in a proportion of 1 to 10 wt. %, relative to the resin solids of the coating composition.

6. The coating composition of claim 1 , wherein the catalyst C has an acid value originating from its carboxyl groups of 50 to 350 mg of KOH/g.

7. The coating composition of claim 1 , wherein the catalyst C is a polyester resin or a polyurethane resin.

8. The coating composition of claim 1 , wherein the melting temperature of the catalyst C is from about 60 to about 160° C.

9. The coating composition of claim 1 , wherein the solubility of the catalyst C is less than 10 g per liter of butyl acetate or water at 20° C.

10. The coating composition of claim 1 , wherein the average particle size of the catalyst C particles determined by means of laser diffraction is 1 to 100 μm.

11. A process for the production of a coating layer on a substrate, comprising the steps:

1) applying a coating layer of a liquid coating composition on a substrate, wherein the liquid coating composition contains a crosslinkable binder A, as an optional component a crosslinker B for the binder A, and a latent catalyst C, wherein C is a carboxyl-functional resin which is present in the liquid coating composition as particles having a melting temperature of 40 to 180° C., measured by DSC at a heating rate of 10 K/min, wherein the crosslinkable binder A is a hydroxyl-functional binder that has a hydroxyl value of from about 60 to about 300 mg of KOH/g, and wherein the crosslinkable binder A is a liquid at room temperature, wherein the liquid coating composition is free of an epoxy-functional component, and

2) thermally curing the coating layer at an object temperature at or above the melting temperature of the catalyst C.

Assignments (3)
IP SECURITY AGREEMENT SUPPLEMENT Recorded May 25, 2017
From: AXALTA COATING SYSTEMS IP CO. LLC
To: BARCLAYS BANK PLC, AS COLLATERAL AGENT
Reel/Frame 042583/0821 →
CHANGE OF NAME Recorded Jun 18, 2013
From: U.S. COATINGS IP CO., LLC
To: AXALTA COATING SYSTEMS IP CO., LLC
Reel/Frame 030639/0164 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 13, 2013
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: U.S. COATINGS IP CO. LLC
Reel/Frame 029803/0826 →