Lignin nanoparticle synthesis
View Patent ↗A method including reducing a particle size of lignin particles to an average particle size less than 40 nanometers; after reducing the particle size, combining the lignin particles with a polymeric material; and forming a structure of the combination. A method including exposing lignin to a diazonium precursor including a functional group; modifying the lignin by introducing the functional group to the lignin; and combining the modified lignin with a polymeric material to form a composite. An apparatus including a composite of a polymer and lignin wherein the lignin has an average particle size less than 100 micrometers.
1. A method comprising:
mechanically reducing a particle size of lignin particles to an average particle size less than 40 nanometers;
after or during mechanically reducing the particle size, exposing lignin particles to a diazonium precursor comprising a functional group, thereby losing N 2 from the diazonium precursor and generating a radical form of the precursor, and then reacting the radical form with lignin particles; and
after mechanically reducing the particle size, combining the lignin particles with a polymeric material.
2. The method of claim 1 , wherein mechanically reducing lignin particles comprising mechanically reducing the particles to an average particle size of 10 nanometers or less.
3. The method of claim 1 , wherein mechanically reducing comprises ball milling.
4. The method of claim 1 , further comprising modifying the lignin particles to at least one of increase solubility in organic solvents and increase dispersion with rubber.
5. The method of claim 1 , wherein the functional group is selected from the group consisting of an olefin, an epoxide, an ester, an acrylate, a halide, a thiol, a carbonate, a nitrile, and a carboxylic acid.
6. The method of claim 1 , wherein combining comprises combining the lignin particles with the polymeric material and carbon black; and the method further comprises:
modifying the lignin particles to at least one of increase solubility in organic solvents and increase blend dispersion with rubber.
7. The method of claim 1 , wherein the polymeric material comprises rubber.
8. The method of claim 1 , wherein exposing comprises providing the diazonium precursor in solution with an electrolyte.
9. The method of claim 1 , wherein the polymeric material comprises rubber.
10. The method of claim 1 , wherein the diazonium precursor comprises an organic aryl diazonium.
11. The method of claim 10 , wherein the diazonium precursor further comprises a counterion.
12. The method of claim 11 , wherein the counterion is a cation.
13. The method of claim 1 , wherein reacting comprises reacting the radical form with an aryl group of the lignin particle.
14. The method of claim 1 , wherein the lignin particle comprises lignosulfate, lignin ester, or silylated lignin.
15. The method of claim 1 , wherein the polymeric material comprises a biocompatible polymer or a biopolymer.
16. The method of claim 1 , wherein exposing comprises addition of an acid solution.
17. The method of claim 1 , further comprising, after the combining, forming a structure of the combination.
18. The method of claim 17 , wherein the structure is a tire.
19. The method of claim 17 , wherein the structure comprises from 5 parts lignin per hundred rubber to 60 parts lignin per hundred rubber.