Hydroprocessing light cycle oil in liquid-full reactors
View Patent ↗A process for the hydroprocessing of a low value light cycle oil (LCO) hydrocarbon feed to provide a high-value diesel-range product. The process comprises a hydrotreatment stage followed by a hydrocracking stage, each of which is conducted under liquid-full reaction conditions wherein substantially all the hydrogen supplied to the hydrotreating and hydrocracking reactions is dissolved in the liquid-phase hydrocarbon feed. Ammonia and other gases formed during hydrotreatment are removed in a separation step prior to hydrocracking. The LCO feed is advantageously converted to diesel in high yield with little loss of hydrocarbon to naphtha.
1. A process for hydroprocessing a hydrocarbon feed, comprising:
(a) contacting the hydrocarbon feed with hydrogen and a first diluent to form a first liquid feed, wherein hydrogen is dissolved in said first liquid feed, and wherein the hydrocarbon feed is a light cycle oil (LCO) having a polyaromatic content greater than 25% by weight, a nitrogen content greater than 300 parts per million by weight (wppm), and a density greater than 890 kg/m 3 ;
(b) contacting the first liquid feed mixture with a first catalyst in a first liquid-full reaction zone to produce a first effluent;
(c) recycling a portion of the first effluent for use as all or part of the first diluent in step (a);
(d) separating ammonia and optionally other gases from the portion of first effluent not recycled, to produce a second effluent having a nitrogen content less than 100 wppm;
(e) contacting the second effluent with hydrogen and a second diluent to produce a second liquid feed, wherein hydrogen is dissolved in said second liquid feed;
(f) contacting the second liquid feed with a second catalyst in a second liquid-full reaction zone to produce a third effluent having a density less than 865 kg/m 3 at 15.6° C. and a polyaromatic content less than 11% by weight;
(g) recycling a portion of the third effluent for use as all or part of the second diluent in step (e); and
(h) taking the portion of the third effluent not recycled as a product stream;
wherein the first catalyst is a hydrotreating catalyst and the second catalyst is a ring opening catalyst, wherein the second catalyst comprises a non-precious metal and an oxide support, and wherein the product stream has a cetane index greater than 35.
2. The process of claim 1 further comprising: fractionating the product stream to recover at least a diesel fraction.
3. The process of claim 1 wherein the total amount of hydrogen fed to the process is 200-530 N l/l (1125-3000 scf/bbl).
4. The process of claim 1 wherein the total amount of hydrogen fed to the process is 250-450 N l/l (1400-2500 scf/bbl).
5. The process of claim 1 wherein the second effluent produced in step (d) has a nitrogen content less than 10 wppm.
6. The process of claim 1 wherein both the first liquid-full reaction zone and the second liquid-full reaction zone have, independently, a temperature in the range of about 300° C. to about 450° C., a pressure in the range of about 3.45 MPa (34.5 bar) to about 17.3 MPa (173 bar), and a liquid hourly space velocity (LHSV) of from about 0.1 hr −1 to about 10 hr −1 .
7. The process of claim 1 wherein both the first liquid-full reaction zone and the second liquid-full reaction zone have, independently, a temperature in the range of about 340° C. to about 400° C., a pressure in the range of about 6.9 MPa (69 bar) to about 13.9 MPa (138 bar), and a LHSV in the range of about 0.4 hr −1 to about 4 hr −1 .
8. The process of claim 1 wherein the product stream comprises at least 75% by volume diesel based on the total volume of diesel fraction and naphtha fraction.
9. The process of claim 1 wherein the product stream comprises at least 88% by volume diesel, based on the total volume of diesel fraction and naphtha fraction.
10. The process of claim 1 wherein the LCO in step (a) has a sulfur content of more than 500 wppm and the product stream in step (h) has a sulfur content of less than 50 wppm.
11. The process of claim 10 wherein the product stream in step (h) has a sulfur content of less than 10 wppm.
12. The process of claim 1 wherein the LCO in step (a) has a cetane index less than 30.
13. The process of claim 12 wherein the product stream in step (h) has a cetane index greater than 40.
14. The process of claim 1 wherein the non-precious metal is selected from the group consisting of nickel and cobalt, and combinations thereof.
15. The process of claim 1 wherein the non-precious metal is a combination of metals selected from the group consisting of nickel-molybdenum (NiMo), cobalt-molybdenum (CoMo), nickel-tungsten (NiW) and cobalt-tungsten (CoW).