Cellulose Ethers With Improved Thermal Gel Strength
Aqueous cellulose ether blend with improved thermal gel strength are formed by combining nanocrystalline cellulose with thermal gelling cellulose ethers. This blend can be used as a binder in a variety of different applications, such as food products and ceramic green bodies. It can also be used to form capsule shells for pharmaceuticals.
1 . A thermal gelling composition having improved high-temperature gel strength comprising:
water soluble thermal gelling cellulose ether;
nanocrystalline cellulose; and
water,
wherein said composition has a ratio of said water soluble thermal gelling cellulose ether to said nanocrystalline cellulose effective to improve the gel strength of said composition at temperatures above 25° C. when dispersed in water.
2 . The composition of claim 1 wherein said thermal gelling cellulose ether is selected from the group consisting of methyl cellulose, methylhydroxypropyl cellulose, methylhydroxyethyl cellulose, and combinations thereof.
3 . The composition of claim 1 wherein said ratio is from about 10:1 to about 1:2 by weight.
4 . The composition of claim 1 wherein said composition is substantially free of alkylene glycols.
5 . A green ceramic body comprising:
a ceramic precursor powder effective to form a ceramic upon heating; and
a binder,
wherein said binder comprises a blend of water soluble thermal gelling cellulose ether and nanocrystalline cellulose.
6 . The green ceramic body of claim 5 wherein said ceramic precursor powder comprises compounds selected from the group consisting of clay, talc, silica alumina, magnesium oxide, silicon nitride, silicon carbide, aluminum silicate, aluminum titrate, cordierite, and combinations thereof.
7 . The material of claim 6 wherein said binder is from about 2 to about 15 weight percent.
8 . The material of claim 5 wherein said thermal gelling cellulose ether is selected from the group consisting of methyl cellulose, methylhydroxypropyl cellulose, methylhydroxyethyl cellulose, and combinations thereof.
9 . The material of claim 5 wherein a ratio of said cellulose ether to said nanocrystalline cellulose is from about 10:1 to about 1:2 by weight.
10 . The material of claim 5 further comprising an amount of water effective to dissolve at least a portion of said binder.
11 . A method of forming a green ceramic body comprising:
blending a ceramic precursor powder with a binder and water to form a blend; and
extruding said blend under pressure to form the green ceramic body,
wherein said binder comprises water soluble thermal gelling cellulose ether, and nanocrystalline cellulose.
12 . The method of claim 11 further comprising adding at least one of a lubricant, a dispersant and a flocculant into said blend.
13 . The method of claim 11 wherein said thermal gelling cellulose ether is selected from the group consisting of methyl cellulose, methylhydroxypropyl cellulose, methylhydroxyethyl cellulose, and combinations thereof.
14 . A food product comprising:
a food stuff; and
a binder,
wherein said binder comprises a blend of water soluble thermal gelling cellulose ether and nanocrystalline cellulose.
15 . The food product of claim 14 wherein said food stuff is selected from the group consisting of vegetable, meat, soy, seafood, cheese, cream, and combinations thereof.
16 . The food product of claim 14 wherein said binder comprises from about 0.1 to about 5 weight percent.
17 . A drug capsule comprising:
a first portion; and
a second portion,
wherein said first portion interfits with said second portion to form a complete capsule, and said first portion and said second portion both comprise a blend of thermal gelling cellulose ether and nanocrystalline cellulose.
18 . The drug capsule of claim 17 wherein said thermal gelling cellulose ether is selected from the group consisting of methyl cellulose, methylhydroxypropyl cellulose, methylhydroxyethyl cellulose, and combinations thereof.
19 . A method of forming a drug capsule comprising:
dipping a pin into an aqueous dispersion of thermal gelling cellulose ether and nanocrystalline cellulose to form a film on said pin; and
removing said pin from said dispersion,
wherein said film solidifies to form a half of a capsule.
20 . The method of claim 19 wherein said dispersion comprises at least about 15% by weight of said thermal gelling cellulose ether and said nanocrystalline cellulose combined.