IP Library Granted Patent US 8,623,123
Granted Patent B2
US 8,623,123 · App. 13/910,014 · Granted Jan 7, 2014

CO

Inventors: Matthias Seiler (Griesheim, DE); Jöm Rolker (Alzenau, DE); Rolf Schneider (Gründau-Rothenbergen, DE); Bernd Glöckler (Rodenbach, DE); Axel Kobus (Langen, DE); Wolfgang Benesch (Bochum, DE); Thomas Riethmann (Essen, DE); Hermann Winkler (Recklinghausen, DE); Jens Reich (Mühlheim an der Ruhr, DE); Helmut Brüggemann (Moers, DE)
Assignee: Evonik Degussa GmbH
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Quick Facts
Patent No.
US 8,623,123
App. No.
13/910,014
Granted
Jan 7, 2014
Kind
B2
Abstract

CO 2 is absorbed from a gas mixture by bringing the gas mixture into contact with an absorbent that comprises water and at least one amine of the formula (I), wherein R 1 and R 2 , independently of each other, are hydrogen or an alkyl group. According to the invention, absorption media comprise sulfolane or an ionic liquid in addition to water and an amine of the formula (I). A device according to the invention for removing CO 2 from a gas mixture comprises an absorption unit, a desorption unit, and an absorption medium according to the invention that is conducted in the circuit.

Claims (16)

1. A device for separating CO 2 from a gas mixture, said device comprising an absorption unit, a desorption unit and a circulating absorption medium, wherein said absorption medium comprises water and one or more amines of formula (I)

wherein R 2 and R 2 independently of one another are hydrogen or an alkyl moiety with the proviso that R 2 and R 2 are not both hydrogen.

2. The device of claim 1 , wherein the absorption medium comprises water and amines of formula (I) in a weight ratio of from 10:1 to 1:10.

3. The device of claim 1 , wherein the absorption medium comprises water and amines of formula (I) in a weight ratio of from 5:1 to 1:1.

4. The device of claim 1 , wherein the absorption medium comprises water and amines of formula (I) in a weight ratio of from 4:1 to 2:1.

5. The device of claim 1 , wherein the absorption medium comprises at least 5% by weight of amines of formula (I).

6. The device of claim 1 , wherein the absorption medium comprises one or more ionic liquids.

7. The device of claim 6 , wherein the absorption medium comprises water and ionic liquids in a weight ratio of from 10:1 to 1:1.

8. The device of claim 7 , wherein the absorption medium comprises water and amines of formula (I) in a weight ratio of from 5:1 to 1:1.

9. The device of claim 7 , wherein the absorption medium comprises water and amines of formula (I) in a weight ratio of from 4:1 to 2:1.

10. The device of claim 7 , wherein the absorption medium comprises at least 5% by weight of amines of formula (I).

11. The device of claim 7 , wherein the absorption medium comprises ionic liquid and amines of formula (I) in a weight ratio of from 3:1 to 1:10.

12. The device of claim 7 , wherein the absorption medium comprises ionic liquid and amines of formula (I) in a weight ratio of from 2:1 to 1:5.

13. The device of claim 12 , wherein the absorption medium comprises water and amines of formula (I) in a weight ratio of from 5:1 to 1:1.

14. The device of claim 12 , wherein the absorption medium comprises water and amines of formula (I) in a weight ratio of from 4:1 to 2:1.

15. The device of claim 12 , wherein the absorption medium comprises at least 5% by weight of amines of formula (I).

Assignments (9)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 31, 2013
From: WINKLER, HERMANN
To: EVONIK STEAG GMBH
Reel/Frame 030913/0001 →
CHANGE OF NAME Recorded Jul 31, 2013
From: EVONIK STEAG GMBH
To: STEAG GMBH
Reel/Frame 030913/0126 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 31, 2013
From: STEAG GMBH
To: EVONIK DEGUSSA GMBH
Reel/Frame 030913/0479 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 31, 2013
From: BENESCH, WOLFGANG; RIETHMANN, THOMAS; REICH, JENS
To: EVONIK ENERGY SERVICES GMBH
Reel/Frame 030913/0927 →
CHANGE OF NAME Recorded Jul 31, 2013
From: EVONIK ENERGY SERVICES GMBH
To: STEAG ENERGY SERVICES GMBH
Reel/Frame 030914/0503 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 31, 2013
From: STEAG ENERGY SERVICES GMBH
To: EVONIK DEGUSSA GMBH
Reel/Frame 030914/0677 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 31, 2013
From: SEILER, MATTHIAS; ROLKER, JORN; SCHNEIDER, ROLF; GLOCKLER, BERND; KOBUS, AXEL; BRUGGEMANN, HELMUT
To: EVONIK DEGUSSA GMBH
Reel/Frame 030915/0665 →
CHANGE OF ADDRESS Recorded Jul 31, 2013
From: STEAG GMBH
To: STEAG GMBH
Reel/Frame 030923/0063 →
CHANGE OF ADDRESS Recorded Jul 31, 2013
From: EVONIK ENERGY SERVICES GMBH
To: EVONIK ENERGY SERVICES GMBH
Reel/Frame 030923/0800 →
Priority Claims (1)
DE 10 2009 000 543 · Feb 2, 2009 · national
Continuity (3)
Division 13589169 · Aug 19, 2012
Division 13147198
Related Publication 20130263743A1 · Oct 10, 2013