IP Library Granted Patent US 8,734,750
Granted Patent B2
US 8,734,750 · App. 13/930,778 · Granted May 27, 2014

Sodium silicate solutions

Inventors: Fadi Mohammed Saeed Trabzuni (Jeddah, SA); Hassan Moenes El Dekki (Jeddah, SA); Chathangat Cheroolil Gopalkrishnan (Jeddah, SA)
Assignee: The National Titanium Dioxide Co. Ltd. (CRISTAL)
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Quick Facts
Patent No.
US 8,734,750
App. No.
13/930,778
Granted
May 27, 2014
Kind
B2
Abstract

Sodium silicate solutions of modulus 3.0 to 3.8 are provided. In some embodiments, the solution is made by a process that uses two specific principal reaction stages. A sodium silicate solution having a low SiO 2 :Na 2 O molar ratio, in the range from 2.0 to 2.8, is first produced by reaction of the SSS, as a cost-effective SiO 2 source, with aqueous caustic soda. The conversion of this intermediate sodium silicate solution of low modulus to a high SiO 2 :Na 2 O molar ratio is made possible by using a SiO 2 source that is prepared as precipitated amorphous silica from the intermediate sodium silicate solution produced above.

Claims (5)

1. A high modulus sodium silicate solution comprising a minimum content of 27.2% by weight of SiO 2 , a maximum content of 9.0% by weight of Na 2 O, a SiO 2 :Na 2 O molar ratio of from 3.0:1 to 3.8:1, and a presence of titanium, wherein the solution exhibits a physical form of a clear and colorless liquid.

2. The high modulus sodium silicate solution of claim 1 , wherein the solution exhibits

a density of from 1.35 kg/L to 1.45 kg/L.

3. The high modulus sodium silicate solution of claim 1 , wherein the SiO 2 :Na 2 O molar ratio is about 3.52:1.

4. The high modulus sodium silicate solution of claim 2 , wherein the SiO 2 :Na 2 O molar ratio is about 3.52:1.

Assignments (6)
SECURITY INTEREST Recorded Sep 26, 2025
From: TRONOX LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 072942/0255 →
RELEASE OF SECURITY INTEREST Recorded Apr 7, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TRONOX LLC
Reel/Frame 059629/0581 →
SECURITY INTEREST Recorded Mar 12, 2021
From: TRONOX LLC
To: HSBC BANK USA, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 055579/0619 →
SECURITY INTEREST Recorded May 1, 2020
From: TRONOX LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 052554/0529 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 25, 2019
From: THE NATIONAL TITANIUM DIOXIDE CO. LTD. (CRISTAL)
To: TRONOX LLC
Reel/Frame 049583/0638 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 20, 2019
From: TRABZUNI, FADI MOHAMMED SAEED; EL DEKKI, HASSAN MOENES; GOPALKRISHNAN, CHATHANGAT CHEROOLIL
To: THE NATIONAL TITANIUM DIOXIDE CO. LTD. (CRISTAL)
Reel/Frame 049539/0787 →
Continuity (5)
Division 13652952 · Oct 16, 2012
Division 13238271 · Sep 21, 2011
Continuation 12589736 · Oct 28, 2009
Division 11880334 · Jul 20, 2007
Related Publication 20130284974A1 · Oct 31, 2013