Spray Drying Microcapsules
Spray drying microcapsules with particulates, the microcapsules that result from such spray drying, and compositions and methods of making said compositions including the spray-dried microcapsules.
1 . Microcapsules comprising:
a core material and a shell encapsulating the core material;
wherein the microcapsules have a median volume-weighted average particle size of from 3 micrometers to 25 micrometers;
wherein the shell of the microcapsules are coated with particulates.
2 . The microcapsules of claim 1 , wherein the shell comprises a polyacrylate material.
3 . The microcapsules of claim 1 , wherein the shell comprises a polyacrylate material having a total polyacrylate mass and including material selected from the group consisting of: amine content of from 0.2% to 2.0% of the total polyacrylate mass; carboxylic acid of from 0.6% to 6.0% of the total polyacrylate mass; and a combination of amine content of from 0.1% to 1.0% and carboxylic acid of from 0.3% to 3.0% of the total polyacrylate mass.
4 . The microcapsules of claim 1 , wherein the shell has a thickness of from 1 nanometer to 300 nanometers.
5 . The microcapsules of claim 1 , wherein the particulates have a median volume-weighted particle size of from 1 nanometer to 1000 nanometers.
6 . The microcapsules of claim 1 , wherein the particulates comprise inorganic particulates.
7 . The microcapsules of claim 1 , wherein the particulates comprise silica particulates.
8 . The microcapsules of claim 1 , wherein the particulates are selected from the group consisting of precipitated silicas, colloidal silicas, fumed silicas, and mixtures thereof.
9 . The microcapsules of claim 1 , wherein the particulates comprise material selected from the group consisting of citric acid, sodium carbonate, sodium sulfate, magnesium chloride, potassium chloride, sodium chloride, sodium silicate, modified cellulose, zeolite, silicon dioxide, and combinations thereof.
10 . The microcapsules of claim 1 , wherein the core material has a first mass and the shell has a second mass, wherein the ratio of the first mass to the second mass is 80% to 20%
11 . The microcapsules of claims 1 , wherein from 15% to 85% of the shell of the microcapsules is coated with the particulates.
12 . The microcapsules of claim 1 , wherein the microcapsules have a bulk flow energy of from 1 milliJoule to 800 milliJoules, according to the Bulk Flow Energy Test Method.
13 . The microcapsules of claim 1 , wherein the shell of the microcapsules is coated with the particulates using a spray-drying process.
14 . The microcapsules of claim 1 , wherein the microcapsules have a fracture strength of from 0.2 mega Pascals to 10.0 mega Pascals, according to the Fracture Strength Test Method.
15 . A method of spray-drying microcapsules comprising:
spray-drying a plurality of microcapsules with a plurality of particulates to form a plurality of spray-dried microcapsules;
wherein the microcapsules comprise a core material and a shell encapsulating the core material; wherein the spray-dried microcapsules comprise the core material and the shell encapsulating the core material; wherein the spray-dried microcapsules are coated with the particulates.
16 . The method of claim 15 , wherein the method further comprises:
providing an aqueous slurry comprising the microcapsules; and
providing a colloidal suspension comprising the particulates;
wherein the spray-drying includes spraying-drying the aqueous slurry and the colloidal suspension.
17 . The method of claim 15 , wherein:
the shell has a glass transition temperature that is less than or equal to a first temperature;
and the spray-drying includes spray-drying the microcapsules with a working fluid;
wherein the working fluid is at a temperature that is greater than the first temperature;
wherein the first temperature is from 75 degrees Celsius to 150 degrees Celsius;
wherein the working fluid is heated to a temperature that is from 25 degrees Celsius to 175 degrees Celsius greater than the first temperature.
18 . The method of claim 15 , wherein from 15% to 85%, of the shell of the spray-dried microcapsules is coated with the particulates.
19 . The method of claim 15 , wherein the spray-dried microcapsules have a bulk flow energy of from 1 milliJoule to 800 milliJoules, according to the Bulk Flow Energy Test Method.
20 . The method of claim 15 , wherein the method produces a process yield of greater than 60% but less than or equal to 95% of the spray-dried microcapsules, according to the Process Yield Test Method.