Aluminum substrates and lithographic printing plate precursors
View Patent ↗Electrochemically grained and anodized aluminum supports are treated with a post-treatment coating solution containing a polymer derived at least in part from vinyl phosphonic acid and phosphoric acid. This post-treated support is useful as substrates in the preparation of lithographic printing plate precursors. The post-treatment substrate treatment enables wide latitude in manufacturing and compatibility with silicate-free developers to achieve negligible background staining and oxide attack.
1. A method for providing a lithographic printing plate comprising:
imagewise exposing a positive-working lithographic printing plate precursor to infrared radiation, the positive-working lithographic printing plate precursor comprising a substrate having thereon one or more imageable layers, each imageable layer comprising a polymeric binder, and the positive-working lithographic printing plate precursor further comprising an infrared radiation absorber,
the substrate being an electrochemically grained, anodized aluminum substrate comprising an oxide layer from anodization, and a post-treatment coating that has been applied directly to the oxide layer using a post-treatment coating solution comprising a polymer derived at least in part from vinyl phosphonic acid, and phosphoric acid in an amount of at least 0.01 weight %,
to provide an exposed positive-working lithographic printing plate precursor comprising exposed and non-exposed regions in the one or more imageable layers, and
processing the exposed positive-working lithographic printing plate precursor with a silicate-free developer having a pH of at least 12, to remove the exposed regions from the one or more imageable layers.
2. The method of claim 1 , wherein the silicate-free developer comprises a salt of a compound comprising both a carboxylic acid and a phosphonic acid.
3. The method of claim 1 , wherein the post-treatment coating on the oxide layer of the substrate is present at a coverage of at least 0.2 mg/m 2 and up to and including 50 mg/m 2 , and comprises a polymer in which at least 10 mol % of the recurring units is derived from the vinyl phosphonic acid.
4. The method of claim 1 , wherein the post-treatment coating comprises a polymer in which at least 15 mol % and up to and including 100 mol % of the total recurring units are derived from the vinyl phosphonic acid, and the polymer also comprises recurring units derived from one or more (meth)acrylates, (meth)acrylamides, (meth)acrylic acid, and vinyl phosphonic acid dimethylester.
5. The method of claim 1 , wherein the polymer in the post-treatment coating is a homopolymer derived from vinyl phosphonic acid.
6. The method of claim 1 , wherein the positive-working lithographic printing plate precursor comprises a single imageable layer comprising the polymeric binder and the infrared radiation absorber.
7. The method of claim 1 , wherein the positive-working lithographic printing plate precursor comprises:
an inner layer disposed over the post-treatment coating of the substrate, the inner layer comprising a first polymeric binder, and
an outer layer disposed over the inner layer, the outer layer comprising a second polymeric binder.
8. The method of claim 1 , wherein the silicate-free developer comprises one or more multivalent cations selected from the group consisting of barium cations, calcium cations, strontium cations, and zinc cations.
9. The method of claim 1 , wherein the post-treatment coating solution comprises phosphoric acid in an amount of at least 0.05 weight %.
10. The method of claim 1 , wherein the substrate has been sulfuric acid-anodized.