Thermal image receiver elements having release agents
A thermal image receiver element dry image receiving layer has a T g of at least 25° C. and is the outermost layer. The dry image receiving layer has a dry thickness of at least 0.5 μm and up to and including 5 μm. It comprises a water-dispersible release agent and a polymer binder matrix that consists essentially of: (1) a water-dispersible acrylic polymer comprising chemically reacted or chemically non-reacted hydroxyl, phospho, phosphonate, sulfo, sulfonate, carboxy, or carboxylate groups, and (2) a water-dispersible polyester that has a T g of 30° C. or less. The water-dispersible acrylic polymer is present in an amount of at least 55 weight % and at a dry ratio to the water-dispersible polyester of at least 1:1. The thermal image receiver element can be used to prepare thermal dye images after thermal transfer from a thermal donor element.
1. A thermal image receiver element comprising a support, and having on at least one side of the support:
a dry image receiving layer having a T g of at least 25° C., which dry image receiving layer is the outermost layer of the thermal image receiver element, has a dry thickness of at least 0.5 μm and up to and including 5 μm, and comprises a water-dispersible release agent, and a polymer binder matrix that consists essentially of:
(1) a water-dispersible acrylic polymer comprising chemically reacted or chemically non-reacted hydroxyl, phospho, phosphonate, sulfo, sulfonate, carboxyl, or carboxylate groups, and
(2) a water-dispersible polyester that has a T g of 30° C. or less,
wherein the water-dispersible acrylic polymer is present in an amount of at least 55 weight % of the total dry image receiving layer weight;
wherein the water dispersible release agent is selected from the group consisting of a water-dispersible fluorine-based surfactant, a silicone-based surfactant, a modified silicone oil, a polysiloxane, a modified polysiloxane and a cross-linked amino modified polydimethyl siloxane.
2. The thermal image receiver element of claim 1 , wherein the water-dispersible release agent is a polysilicone that is modified with amino side chains and/or terminal groups, in an amount of at least 0.5 weight % based on the total dry image receiving layer weight.
3. The thermal image receiver element of claim 1 , wherein the water-dispersible release agent is a polysilicone that is modified with amino side chains or terminal groups, and is present in an amount of at least 1 weight %, 2 weight %, or 3 weight %, based on the total dry image receiving layer weight.
4. The thermal image receiver element of claim 1 , wherein the water-dispersible release agent is present in an amount of at least 1.0 weight % and up to and including 5 weight %, based on the total dry image receiving layer weight.
5. The thermal image receiver element of claim 1 wherein the image receiving layer comprises the water-dispersible acrylic polymer and the water-dispersible polyester at a ratio of 2:3 to 1 and comprises 3 weight % release agent.
6. The thermal image receiver element of claim 1 wherein the image receiving layer comprises the water-dispersible acrylic polymer and the water-dispersible polyester at a ratio of 2:1 to 1 and comprises 2 weight % release agent.
7. The thermal image receiver element of claim 1 wherein the image receiving layer comprises the water-dispersible acrylic polymer and the water-dispersible polyester at a ratio of 2:1 to 1 and comprises 1 weight % release agent.
8. The thermal image receiver element of claim 1 , wherein the water-dispersible release agent is a water-dispersible polyoxyalkylene-modified dimethylsiloxane graft copolymer having at least one alkylene oxide pendant chain having more than 45 alkoxide units.
9. The thermal image receiver element of claim 1 , further comprising a residual crosslinking agent.
10. The thermal image receiver element of claim 1 , wherein the residual crosslinking agent is a carbodiimide or an aziridine derivative compound.
11. The thermal image receiver element of claim 1 , wherein the residual crosslinking agent is an individual compound or mixture of compounds chosen from the group consisting of melamine formaldehyde resins, glycoluril formaldehyde resins, plycarboxylic acids and anhydrides, plyamines, epihalohydrins, diepoxides, dialdehydes, diols, carboxylic acid halides, ketenes, aziridines, carbodiimides, and isocyanates.
12. A thermal image receiver element comprising a support, and having one or both of opposing sides of the support:
a dry image receiving layer having a T g of at least 35° C. and up to and including 60° C., which dry image receiving layer is the outermost layer of the thermal image receiver element, has a dry thickness of at least 1 μm and up to and including 3 μm, comprising:
a water-dispersible release agent, wherein the water dispersible release agent is a crosslinked amino modified polysiloxane present in an amount of at least 1 weight % and up to and including 5 weight %, based on the total dry image receiving layer weight;
a residual crosslinking agent, wherein the residual crosslinking agent is a carbodiimide or an aziridine derivative compound; and
a polymer binder matrix that consists essentially of:
(1) a water-dispersible acrylic polymer comprising chemically reacted or chemically non-reacted carboxy or carboxylate groups, wherein the water-dispersible acrylic polymer further comprises recurring ethylenically unsaturated polymerizable monomer units derived from styrene or a styrene derivative; and
(2) a water-dispersible, film-forming polyester that has a T g of at least 0° C. and up to and including 20° C., which water-dispersible, film-forming polyester having water-dispersibility groups, wherein the polyester is a VYLONAL® MD-1480.
13. A method for making the thermal image receiver element of claim 1 , comprising:
applying an aqueous image receiving layer formulation to one or both of the opposing sides of a support, the aqueous image receiving layer formulation comprising a water-dispersible release agent, a residual crosslinking agent, and a polymer binder composition consisting essentially of:
(1) a water-dispersible acrylic polymer comprising chemically reacted or chemically non-reacted hydroxyl, phospho, phosphonate, sulfo, sulfonate, carboxy, or carboxylate groups, and
(2) a water-dispersible polyester that has a T g of 30° C. or less, wherein the water-dispersible acrylic polymer is present in an amount of at least 55 weight % of the resulting total dry image receiving layer weight, and is present in the polymeric binder matrix at a dry ratio to the water-dispersible polyester of at least 1:1 to and including 6:1, and
drying the aqueous image receiving layer formulation to form a dry image receiving layer on one or both opposing sides of the support.
14. A method for making a thermal image, comprising:
imagewise transferring a clear polymeric film, one or more a dye images, or both a clear polymeric film and one or more dye images, from a thermal donor element to the image receiving layer of the dry thermal image receiving element of claim 1 .