Light blocking articles having opacifying layers

1. An article comprising a dry opacifying layer that comprises:

(a) porous particles comprising a continuous polymeric binder and pores within the continuous polymeric binder, the porous particles having a glass transition temperature of at least 25° C., a porosity of at least 10% and up to and including 70%, and a mode particle size of at least 3 μm and up to and including 40 μm, the porous particles being present in an amount of at least 40 weight % based on the total dry weight of the dry opacifying layer,

(b) an opacifying colorant that absorbs predetermined electromagnetic radiation within at least 380 nm and up to and including 780 nm, the opacifying colorant being a neutral or black pigment that is present in an amount of at least 0.001 weight % and up to and including 0.3 weight %, based on the total dry weight of the dry opacifying layer, wherein the opacifying colorant is present in the dry opacifying layer within the pores of the porous particles or within the continuous polymeric binder of the porous particles, or within both the pores and continuous polymeric binder of the porous particles, and

(c) a matrix polymer in which the porous particles and opacifying colorant are dispersed, the matrix polymer being water-soluble or water-dispersible and having a glass transition temperature that is less than 25° C., and is present in an amount of at least 10 weight % and up to and including 60 weight %, based on the total weight of the dry opacifying layer,

wherein the weight ratio of the matrix polymer to the opacifying colorant in the dry opacifying layer is from 33.3:1 to 60,000:1, and

the dry opacifying layer has an interstitial void volume of at least 5 volume % and less than 30 volume %;

provided that:

the article is capable of blocking at least 85% of the predetermined electromagnetic radiation compared to a control article from which the porous particles have been omitted, and

the article has a CIELAB L* greater than 70.

2. The article of claim 1 wherein at least 95 weight % and up to and including 100 weight % of the total opacifying colorant is within the porous particles.

3. The article of claim 1 , further comprising a substrate on which the opacifying layer is disposed.

4. The article of claim 3 , further comprising an underlying layer that has a glass transition temperature below 25° C. and that is disposed between the substrate and the dry opacifying layer.

5. The article of claim 1 , wherein the opacifying colorant is a carbon black.

6. The article of claim 1 , wherein the opacifying colorant comprises a combination of two or more component pigment colorants.

7. The article of claim 1 , wherein the dry opacifying layer is disposed on a substrate that comprises a textile web, polymer, cellulosic material, glass, or ceramic.

8. The article of claim 1 , wherein the opacifying colorant is present in the dry opacifying layer in an amount of at least 0.003 weight % and up to and including 0.1 weight % based on the total dry weight of the dry opacifying layer.

9. The article of claim 1 , wherein the porous particles comprise a plurality of discrete pores having an average pore size of at least 100 nm and up to and including 4,000 nm.

10. The article of claim 1 , wherein the dry opacifying layer has an average dry thickness of at least 50 μm.

11. The article of claim 1 , selected from one of the following embodiments:

the opacifying colorant is present in either or both of the pores and continuous polymeric binder of the porous particles, and the article further comprises a second set of porous particles that contain no colorants; and

the opacifying colorant is present in either or both of the pores and continuous polymeric binder of the porous particles, wherein the porous particles further comprise a second set of discrete pores that contain no colorants.