Photopolymerizable compositions for electroless plating methods

1. A photopolymerizable composition comprising:

(a) a photopolymerizable epoxy material,

(b) a photoacid generator,

(c) an electron donor photosensitizer having an oxidation potential of at least 0.4 V and up to and including 3 V vs. SCE, and

(d) metal particles, and

optionally

(e) one or more free-radically polymerizable materials, and

(f) one or more free radical photoinitiators.

2. The photopolymerizable composition of claim 1 , wherein the metal particles have a particle size of at least 0.01 μm and up to and including 25 μm.

3. The photopolymerizable composition of claim 1 , wherein the metal particles are silver or copper particles and have a particle size of at least 0.02 μm and up to and including 10 μm.

4. The photopolymerizable composition of claim 1 , further comprising a hydroxy-containing material.

5. The photopolymerizable composition of claim 1 , comprising all of components (a) through (f), and wherein:

the photopolymerizable epoxy material has at least two polymerizable epoxy groups per molecule and is present in an amount of at least 50 weight % and up to and including 75 weight %, based on the total weight of all six (a) through (f) components,

the photoacid generator is an iodonium or sulfonium that is present in an amount of at least 0.1 weight % and up to and including 10 weight %, based on the total weight of all six (a) through (f) components,

the electron donor photosensitizer is present in an amount of at least 0.05 weight % and up to and including 2 weight %, based on the total weight of all six (a) through (f) components,

the metal particles are silver or copper particles that are present in an amount of at least 1 weight % and up to and including 50 weight %, based on the total weight of all six (a) through (f) components,

the one or more free radically polymerizable compounds are present in an amount of at least 20 weight % and up to and including 75 weight %, based on all six (a) through (f) components, and

each of the one or more free radical photoinitiators is present in an amount of at least 0.1 weight % and up to and including 10 weight %, based on the total weight of all six (a) through (f) components.

6. The photopolymerizable composition of claim 1 , wherein the weight ratio of the sum of the weights of components (a), (b), (c), (e), and (f) to the weight of component (d) is from 1:1 to and including 3:1.

7. The photopolymerizable composition of claim 1 , wherein the electron donor photosensitizer is a pyrene, benzopyrene, perylene, or benzoperylene that is present in an amount of at least 0.05 weight % and up to and including 2 weight %, based on the total weight of components (a), (b), and (d).

8. An article comprising a substrate and having thereon either a uniform layer or a pattern of a photopolymerizable composition that comprises:

(a) a photopolymerizable epoxy material,

(b) a photoacid generator,

(c) an electron donor photosensitizer having an oxidation potential of at least 0.4 V and up to and including 3 V vs. SCE, and

(d) metal particles, and

optionally

(e) one or more free-radically polymerizable materials, and

(f) one or more free radical photoinitiators.

9. The article of claim 8 , wherein the substrate is a continuous polymeric web.

10. The article of claim 8 having either: a uniform layer of the photopolymerizable composition having an average dry thickness of at least 0.1 μm and up to and including 10 μm; or a pattern of the photopolymerizable composition comprising a grid of lines having an average dry thickness of at least 0.2 μm and up to and including 10 μm.

11. The article of claim 8 , wherein the substrate is a continuous polyester film.

12. A method for providing an electrically conductive article, the method comprising:

(i) providing a continuous web of a transparent substrate,

(ii) forming a photocurable pattern on at least a first portion of the continuous web using a photopolymerizable composition that comprises:

(a) a photopolymerizable epoxy material,

(b) a photoacid generator,

(c) an electron donor photosensitizer having an oxidation potential of at least 0.4 V and up to and including 3 V vs. SCE, and

(d) metal particles, and

optionally

(e) one or more free radically polymerizable compounds, and

(f) one or more free radical photoinitiators,

(iii) exposing the photocurable pattern to radiation to form a photocured pattern on the first portion, and

(iv) electrolessly plating the photocured pattern on the first portion with an electrically conductive metal.

13. The method of claim 12 , further comprising:

(v) repeating features (ii) through (iv) on one or more additional portions of the continuous web that are different from the first portion, using the same or different photopolymerizable composition.

14. The method of claim 12 , for providing a plurality of precursor articles, comprising:

(ii) forming the first photocurable pattern on a first portion of the continuous web by applying the photopolymerizable composition to the first portion using a flexographic printing member,

(iii′) advancing the continuous web comprising the first portion comprising the first photocurable pattern to be proximate exposing radiation, and thereby forming a first photocured pattern on the first portion,

(iv′) forming a second photocurable pattern on a second portion of the continuous web by applying the same or different photopolymerizable composition to the second portion using the flexographic printing member,

(v′) advancing the continuous web comprising the second portion comprising the second photocurable pattern to be proximate exposing radiation, and thereby forming a second photocured pattern on the second portion,

(vi′) optionally, carrying out features (iv′) and (v′) one or more times on additional respective portions of the continuous web using the same or different photopolymerizable composition and the same or different flexographic printing member to form additional photocured patterns on the additional respective portions, and

(vii′) winding up the continuous web comprising multiple photocured patterns.

15. The method of claim 14 , further comprising:

forming individual electrically conductive articles from the continuous web comprising multiple photocured patterns, and

assembling the individual electrically conductive articles into the same or different individual devices.