Process of making carbon fibers derived from lignin/carbon residue
A method of making a carbon fiber comprising esterification of a lignin precursor with an acid, acid anhydride, or acyl halide, thereby forming a reduced T g lignin. Mixing the reduced T g lignin with a carbon residue selected from the group of coal based raw material, petroleum based raw material and combinations thereof, thereby forming a fiber precursor mixture; and spinning the fiber precursor mixture into a fiber. A method of making a carbon fiber comprising esterification of a lignin with an acid derivative, thereby forming a reduced T g lignin. Mixing the reduced T g lignin with a pitch, thereby forming a fiber precursor mixture; and spinning the fiber precursor mixture into a fiber. A method of making a carbon fiber comprising lowering the T g of a lignin material, thereby forming a reduced T g lignin. Mixing the reduced T g lignin with a carbon residue, thereby forming a fiber precursor mixture and spinning the fiber precursor mixture into a fiber.
1. A method of making a carbon fiber comprising:
a. lowering the T g of a lignin material, thereby forming a reduced T g lignin;
b. mixing the reduced T g lignin with a carbon residue, thereby forming a fiber precursor mixture; and
c. spinning the fiber precursor mixture into a fiber.
2. The method of claim 1 , wherein the lowering comprises reacting the lignin with an alkylating agent.
3. The method of claim 1 , wherein the lowering comprises the esterification of the lignin.
4. The method of claim 1 , wherein the lowering comprises reacting the lignin with a compound having at least one of the following of a propyl group or longer alkyl chain, an aromatic group, and combinations thereof.
5. The method of claim 1 , wherein the lowering comprises reacting the lignin with a halogenated compound or an acid anhydride.
6. The method of claim 1 , wherein the carbon residue is selected from group comprising decant oil, decant oil based pitches, coal tar pitches, petroleum pitches, coal tar distillates and combinations thereof.
7. The method of claim 1 , wherein the T g of the reduced T g lignin is within 50° C. of the T g of the carbon residue.
8. The method of claim 1 , wherein the reduced T g lignin is formed by esterification of a lignin with an acid derivative and wherein the carbon residue is from a pitch.
9. The method of claim 8 , wherein the acid derivative includes at least one of the following of a propyl group or longer alkyl chain, an aromatic group, and combinations thereof.
10. The method of claim 8 , wherein the acid derivative comprises a halogenated compound, or an anhydride.
11. The method of any of claim 8 , wherein the T g of the reduced T g lignin is within 50° C. of the T g of the carbon residue.
12. The method of claim 1 , wherein the reduced T g lignin is formed by esterification of a lignin precursor with an acid, acid anhydride, alkyl halide, or acyl halide, and wherein the carbon residue is selected from the group of coal based raw material, petroleum based raw material and combinations thereof.
13. The method of claim 12 wherein the acid comprises an acid having a longer alkyl chain than acetic acid.
14. The method of claim 12 , wherein the acid includes an ethyl group or longer alkyl chain.
15. The method of claim 12 wherein the acid includes one or more selected from the group of compounds having 4 to 22 carbon atoms and a terminal carboxylic functional group.
16. The method of claim 12 , wherein the reduced T g lignin and the carbon residue have a similar polarity, whereby the carbon residue and lignin have a compatible viscoelastic state at a same point in time in the method.
17. The method of claim 12 , wherein the carbon residue comprises coal tar pitch or decant oil.
18. The method of claim 12 , wherein the carbon residue is selected from group comprising decant oil, decant oil based pitches, coal tar pitches, petroleum pitches, coal tar distillates and combinations thereof.
19. The method of claim 12 , wherein the T g of the reduced T g lignin is within 50° C. of the T g of the carbon residue.