Dual core golf ball having positive-hardness-gradient thermoplastic inner core and positive-hardness-gradient thermoset outer core layer
A golf ball comprising an inner core layer including a thermoplastic material and having a geometric center hardness less than the surface hardness to define a positive hardness gradient. An outer core layer is formed over the inner core. The outer core includes a thermoset rubber composition and has an inner surface hardness less than an outer surface hardness to define a positive hardness gradient. A cover layer is formed over the outer core layer. The cover layer includes an inner cover layer and an outer cover layer. The thermoplastic material of the core includes an acid copolymer of ethylene and an α,β-unsaturated carboxylic acid, optionally a softening monomer comprising alkyl acrylate or methacrylate; a plasticizer; an organic acid or salt thereof; and a cation source present in an amount sufficient to neutralize from about 70 to about 100% of all acid groups present in the material.
1. A golf ball comprising:
an inner core layer comprising a thermoplastic material and having a geometric center hardness less than a surface hardness to define a positive hardness gradient;
an outer core layer disposed about the inner core, the outer core comprising a thermoset rubber composition and having an inner surface hardness less than an outer surface hardness to define a positive hardness gradient; and
a cover layer disposed about the outer core layer, the cover layer comprising an inner cover layer and an outer cover layer;
wherein the thermoplastic material comprises:
an acid copolymer of ethylene and an α,β-unsaturated carboxylic acid, optionally including a softening monomer comprising alkyl acrylate or methacrylate;
a plasticizer comprising an alkyl oleate comprising methyl oleate, ethyl oleate, propyl oleate, butyl oleate, octyl oleate, 2-ethylhexyl oleate, or mixtures thereof;
an organic acid or salt thereof; and
a cation source present in an amount sufficient to neutralize from about 70 to about 100% of all acid groups present in the material.
2. The golf ball of claim 1 , wherein the plasticizer is present in an amount of about 3 to 50% by weight.
3. The golf ball of claim 1 , wherein the plasticizer comprises a fatty acid ester.
4. The golf ball of claim 1 , wherein the thermoplastic material comprises an ethylene acid copolymer containing acid groups such that greater than 80% of the acid groups are neutralized.
5. The golf ball of claim 4 , wherein 90% or greater of the acid groups are neutralized.
6. The golf ball of claim 5 , wherein 100% of the acid groups are neutralized.
7. The golf ball of claim 1 , wherein the thermoplastic material further comprises a non-acid polymer.
8. The golf ball of claim 7 , wherein the non-acid polymer comprises polyolefins, polyamides, polyesters, polyethers, polyurethanes, metallocene-catalyzed polymers, single-site catalyst polymerized polymers, ethylene propylene rubber, ethylene propylene diene rubber, styrenic block copolymer rubbers, alkyl acrylate rubbers, or functionalized derivatives thereof.
9. The golf ball of claim 1 , wherein the organic acid or salt thereof comprises barium, lithium, sodium, zinc, bismuth, chromium, cobalt, copper, potassium, strontium, titanium, tungsten, magnesium, cesium, iron, nickel, silver, aluminum, tin, or calcium salts, or salts of fatty acids.
10. The golf ball of claim 9 , wherein the fatty acid salt comprises stearic acid, behenic acid, erucic acid, oleic acid, linoelic acid or dimerized derivatives thereof.
11. The golf ball of claim 1 , wherein the thermoplastic inner core further comprises an ethylene/acid copolymer or ionomer.
12. The golf ball of claim 1 , wherein the inner core layer has a diameter of about 1.0 inches to about 1.30 inches.
13. A golf ball comprising:
an inner core layer comprising a thermoplastic material and having a geometric center hardness less than a surface hardness to define a positive hardness gradient;
an outer core layer disposed about the inner core, the outer core comprising a thermoset rubber composition and having an inner surface hardness less than an outer surface hardness to define a positive hardness gradient; and
a cover layer disposed about the outer core layer, the cover layer comprising an inner cover layer and an outer cover layer;
wherein the thermoplastic material comprises:
an acid copolymer of ethylene and an α,β-unsaturated carboxylic acid, optionally including a softening monomer comprising alkyl acrylate or methacrylate;
a plasticizer comprising butyl oleate or glycerol trioleate;
an organic acid or salt thereof; and
a cation source present in an amount sufficient to neutralize from about 70 to about 100% of all acid groups present in the material.