IP Library Granted Patent US 9,267,239
Granted Patent B2
US 9,267,239 · App. 14/640,654 · Granted Feb 23, 2016

Creping release agents

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Quick Facts
Patent No.
US 9,267,239
App. No.
14/640,654
Granted
Feb 23, 2016
Kind
B2
Abstract

Disclosed is a method of reducing adhesion to the surface of equipment used in paper manufacture or in paper converting processes, comprising applying to the surface the a composition. comprising (a) 50-98 parts of hydrocarbon oil, (b) 1-40 parts of emulsifier, and (c) 1-10 parts of a non-curing hydrocarbon polymer.

Claims (26)

1. A method of reducing adhesion to a surface of equipment used in paper manufacture or in paper converting process comprising the steps of :

a) applying a composition comprising:

(i) 50-98 weight percent of hydrocarbon oil,

(ii) 1-40 weight percent of emulsifier, and

(iii) 1-10 weight percent of a non-curing hydrocarbon polymer, to the surface of a creping cylinder,

b) pressing the paper web against the drying surface to adhere the web to the drying surface, and

c) dislodging the web from the drying surface with a creping device to crepe the paper web.

2. The method of claim 1 wherein at least one hydrocarbon oil is selected from the group consisting of white oils, mineral oils, petroleum distillates or combinations thereof.

3. The method of claim 1 wherein the non-curing hydrocarbon polymer comprises isobutylene/butene copolymers or hydrogenates thereof.

4. The method of claim 1 wherein the non-curing hydrocarbon polymer comprises polyethylene or polypropylene based copolymers.

5. The method of claim 1 wherein the non-curing hydrocarbon polymer has the formula

or hydrogenates thereof, wherein R 1 through R 5 are hydrogen or —CH 3 , with at least one of R 1 through R 4 being —CH 3 , and n is a number such that the number average molecular weight of the hydrocarbon polymer is from 50 to 3000.

6. The method of claim 5 wherein the non-curing hydrocarbon polymer comprises a polybutene resulting from isobutylene/butene copolymerization or hydrogenates thereof.

7. The method of claim 6 wherein the composition contains less than about 8% polybutene.

8. The method of claim 1 wherein the non-curing hydrocarbon polymer comprises a polybutene resulting from isobutylene/butene copolymerization or hydrogenates thereof.

9. The method of claim 6 wherein the composition contains less than about 8% polybutene.

10. The method of claim 1 wherein the emulsifier is selected from the group consisting of polyethylene glycol mono- and diesters of fatty acids; alcohol ethoxylates; alkyl phenol ethoxylates; phosphate esters of alcohol ethoxylates; and quaternary ammonium surfactants.

11. The method of claim 1 wherein the weight percent of hydrocarbon oil is from 62 to 97 percent.

12. The method of claim 1 wherein the weight percent of emulsifiers is from 2 to 30 percent.

13. The method of claim 1 wherein the weight percent of non-curing hydrocarbon polymer is from 1 to 8 percent.

14. The method of claim 1 wherein the weight percent of non-curing hydrocarbon polymer is from 1 to 5.5 percent.

15. The method of claim 11 wherein the weight percent of emulsifiers is from 2 to 30 percent and wherein the weight percent of non-curing hydrocarbon polymer is from 1 to 8 percent.

16. The method of claim 3 wherein the weight percent of hydrocarbon oil is from 62 to 97 percent.

17. The method of claim 3 wherein the weight percent of emulsifiers is from 2 to 30 percent.

18. The method of claim 3 wherein the weight percent of non-curing hydrocarbon polymer is from 1 to 8 percent.

19. The method of claim 1 wherein the composition is applied by splaying the composition onto the surface of the equipment used in paper manufacture or in paper converting process.

Assignments (14)
SECURITY INTEREST Recorded Nov 14, 2025
From: CHEM-AQUA, INC.; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; NCH CORPORATION; NCH LIFE SCIENCES LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 073570/0838 →
RELEASE OF SECURITY INTEREST Recorded Nov 14, 2025
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
To: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 073564/0864 →
SECURITY AGREEMENT (NOTES) Recorded Oct 10, 2025
From: DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 073061/0885 →
RELEASE OF 2023 NOTES PATENT SECURITY INTERESTS Recorded Oct 10, 2025
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
To: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 073074/0198 →
SECURITY AGREEMENT (2024 NOTES) Recorded Jun 24, 2024
From: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 067824/0278 →
2023 NOTES PATENT SECURITY AGREEMENT Recorded Jul 7, 2023
From: BIRKO CORPORATION; SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE GLOBAL CORPORATION
To: BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
Reel/Frame 064225/0170 →
SECURITY AGREEMENT (NOTES) Recorded Sep 14, 2022
From: SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A. AS COLLATERAL AGENT
Reel/Frame 061432/0821 →
RELEASE OF SECURITY INTEREST Recorded Nov 10, 2021
From: CITIBANK, N.A.
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 058848/0636 →
TERM LOAN PATENT SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: GOLDMAN SACHS BANK USA
Reel/Frame 058102/0407 →
ABL PATENT SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: BANK OF AMERICA, N.A.
Reel/Frame 058102/0122 →
RELEASE OF SECURITY INTEREST Recorded Nov 10, 2021
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 058856/0724 →
NOTES SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
Reel/Frame 058103/0066 →
FIRST LIEN NOTICE AND CONFIRMATION OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Jul 20, 2018
From: SOLENIS TECHNOLOGIES, L.P.
To: CITIBANK, N.A., COLLATERAL AGENT
Reel/Frame 046595/0241 →
SECOND LIEN NOTICE AND CONFIRMATION OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Jul 20, 2018
From: SOLENIS TECHNOLOGIES, L.P.
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 046629/0213 →