Negative-working lithographic printing plate precursor and use
View Patent ↗A negative-working, infrared radiation-sensitive lithographic printing plate precursor is exposed and processed on-press to provide a lithographic printing plate. This precursor has an infrared radiation-sensitive imageable layer comprises free radical imaging chemistry; an infrared radiation absorber; a particulate primary polymeric binder comprising polyalkylene oxide segments having an average particle size (D 1 ) of at least 50 nm and up to and including 1000 nm; and a particulate secondary resin having an average particle size (D 2 ) of at least 3 μm and up to and including 10 μm. The imageable layer has an average dry thickness (t) of at least 1 μm and up to and including 4 μm and satisfies Equation (1): D 2 /1.4> t>D 1 (1) and the average dry thickness (t) is defined by Equation (2): t=w/r (2) wherein w is the dry coverage of the imageable layer in g/m 2 and r is 1 g/cm 3 .
1. A negative-working, infrared radiation-sensitive lithographic printing plate precursor comprising:
a substrate having a hydrophilic surface, and
an infrared radiation-sensitive imageable layer that is disposed over the hydrophilic surface of the substrate, and that comprises:
a free radically polymerizable compound;
an initiator composition that provides free radicals upon exposure to infrared radiation;
an infrared radiation absorber;
a primary polymeric binder comprising polyalkylene oxide segments and is present in the form of particles having an average particle size (D 1 ) of at least 50 nm and up to and including 1000 nm; and
a secondary resin that is present as particles having an average particle size (D 2 ) of at least 3 μm and up to and including 10 μm,
wherein:
the infrared radiation-sensitive imageable layer has an average dry thickness (t) of at least 1 μm and up to and including 4 μm and satisfies the following Equation (1):
D 2 /1.4> t>D 1 (1)
and the average dry thickness (t) is defined by the following Equation (2):
t=w/r (2)
wherein w is the dry coverage of the infrared radiation-sensitive imageable layer in g/m 2 and r is 1 g/cm 3 .
2. The negative-working, infrared radiation-sensitive lithographic printing plate precursor of claim 1 , wherein the primary polymeric binder comprises recurring units comprising polyalkylene oxide segments and recurring units comprising pendant cyano groups.
3. The negative-working, infrared radiation-sensitive lithographic printing plate precursor of claim 1 , wherein the infrared radiation-sensitive imageable layer further satisfies the following Equation (3):
D 2 /2> t>D 1 .
4. The negative-working, infrared radiation-sensitive lithographic printing plate precursor of claim 1 , wherein the infrared radiation-sensitive imageable layer further satisfies the following Equation (IV):
D 2 /2> t> 2 D 1 .
5. The negative-working, infrared radiation-sensitive lithographic printing plate precursor of claim 1 , wherein the initiator composition comprises a compound comprising a tetraaryl borate anion.
6. The negative-working, infrared radiation-sensitive lithographic printing plate precursor of claim 1 , wherein the initiator composition comprises an iodonium cation and a tetraphenyl borate anion.
7. The negative-working, infrared radiation-sensitive lithographic printing plate precursor of claim 1 , wherein the secondary resin particles comprise a crosslinked polymer.
8. The negative-working, infrared radiation-sensitive lithographic printing plate precursor of claim 7 , wherein the secondary resin particles are composed of recurring units derived from one or more ethylenically unsaturated polymerizable monomers selected from the group consisting of an alkyl acrylate, alkyl methacrylate, and a styrene monomer.
9. The negative-working, infrared radiation-sensitive lithographic printing plate precursor of claim 1 , wherein the secondary resin particle is present in the infrared radiation-sensitive imageable layer in an amount of at least 1 weight % and up to and including 15 weight %, based on the total solids of the infrared radiation-sensitive imageable layer.
10. The negative-working, infrared radiation-sensitive lithographic printing plate precursor of claim 1 , wherein the primary polymeric binder is present in the infrared radiation-sensitive imageable layer in an amount of at least 25 weight % and up to and including 70 weight %, based on the total solids of the infrared radiation-sensitive imageable layer.
11. A method for providing a lithographic printing plate, the method comprising:
imagewise exposing the negative-working, infrared radiation-sensitive lithographic printing plate precursor of claim 1 to infrared radiation to provide exposed regions and non-exposed regions in the infrared radiation-sensitive imageable layer, and
removing the non-exposed regions in the infrared radiation-sensitive imageable layer from the substrate on-press using a fountain solution, lithographic printing ink, or both fountain solution and lithographic printing ink, to provide a lithographic printing plate.