Thermoplastic elastomer composition and molded body
View Patent ↗The thermoplastic elastomer composition of the present invention is a thermoplastic elastomer composition including a hydrogenated block copolymer (A) and a softening agent (B), the hydrogenated block copolymer (A) being a hydrogenated product of a block copolymer including a polymer block (a) composed of a constitutional unit derived from an aromatic vinyl compound and a polymer block (b) containing 1 to 100% by mass of a constitutional unit (b1) derived from farnesene and 99 to 0% by mass of a constitutional unit (b2) derived from a conjugated diene other than farnesene; a mass ratio of the polymer block (a) and the polymer block (b) [(a)/(b)] being 1/99 to 70/30; 50 mol % or more of carbon-carbon double bonds in the polymer block (b) being hydrogenated; and a content of the softening agent (B) being 20 to 2,000 parts by mass on the basis of 100 parts by mass of the hydrogenated block copolymer (A).
1. A thermoplastic elastomer composition comprising a hydrogenated block copolymer (A) and a softening agent (B),
the hydrogenated block copolymer (A) being a hydrogenated product of a block copolymer including a polymer block (a) composed of a constitutional unit derived from an aromatic vinyl compound and a polymer block (b) containing 30 to 100% by mass of a constitutional unit (b1) derived from farnesene and 70 to 0% by mass of a constitutional unit (b2) derived from a conjugated diene other than farnesene,
a mass ratio of the polymer block (a) and the polymer block (b) [(a)/(b)] being 10/90 to 60/40,
70 to 100 mol % of carbon-carbon double bonds in the polymer block (b) being hydrogenated, and
a content of the softening agent (B) being 20 to 200 parts by mass on the basis of 100 parts by mass of the hydrogenated block copolymer (A),
wherein
the aromatic vinyl compound comprises at least one selected from the group consisting of styrene, α-methylstyrene and 4-methylstyrene,
the conjugated diene other than farnesene comprises at least one selected from the group consisting of butadiene, isoprene and myrcene, and
the softening agent (B) comprises at least one selected from the group consisting of paraffin-based process oils, naphthene-based process oils and aromatic process oils, phthalic acid derivatives, white oils, liquid co-oligomers of ethylene and an α-olefin, liquid paraffins, low-molecular weight polyisobutylene, liquid polydienes, and hydrogenated products thereof.
2. The thermoplastic elastomer composition according to claim 1 , wherein the thermoplastic elastomer composition further comprises a polyolefin-based resin (C), and a content of the polyolefin-based resin (C) is 5 to 200 parts by mass on the basis of 100 parts by mass of the hydrogenated block copolymer (A).
3. The thermoplastic elastomer according to claim 1 , wherein a total content of the hydrogenated block copolymer (A) and the softening agent (B) in the thermoplastic elastomer composition is 90% by mass or more.
4. The thermoplastic elastomer composition according to claim 1 , wherein the farnesene is β-farnesene.
5. The thermoplastic elastomer composition according to claim 1 , wherein a peak top molecular weight (Mp) of the hydrogenated block copolymer (A) is 4,000 to 1,500,000.
6. The thermoplastic elastomer composition according to claim 1 , wherein a molecular weight distribution (Mw/Mn) of the hydrogenated block copolymer (A) is 1 to 4.
7. The thermoplastic elastomer composition according to claim 1 , wherein the aromatic vinyl compound is styrene.
8. The thermoplastic elastomer composition according to claim 1 , wherein the hydrogenated block copolymer (A) is a hydrogenated product of a block copolymer including at least two of the polymer blocks (a) and at least one of the polymer blocks (b).
9. A molded body comprising the thermoplastic elastomer composition according to claim 1 .
10. The thermoplastic elastomer composition according to claim 1 , wherein the content of the softening agent (B) is 50 to 200 parts by mass on the basis of 100 parts by mass of the hydrogenated block copolymer (A).