Golf ball materials based on blends of polyamide and acid anhydride-modified polyolefins
View Patent ↗Multi-piece golf balls having at least one layer made from a polyamide non-ionomeric composition are provided. The polyamide composition consists essentially of about 40 to about 99% by weight polyamide; about 1 to about 60% by weight of an acid anhydride-modified polyolefin; and about 1 to about 60% of a fatty acid additive selected from the group consisting of fatty acid salts, fatty acid amides, and mixtures thereof. The ball includes a core, preferably a dual core construction; and a cover of at least one layer. In another preferred construction, a multi-layered core containing an inner, intermediate, and outer core layer is made. For example, the intermediate core layer may be made of a rubber composition; and each of the inner core and outer core layers may be made of the polyamide composition. The resulting ball has high resiliency along with a soft feel.
1. A golf ball, comprising:
a) a core, the core comprising an inner, intermediate, and outer core layer, the inner core having an outer surface and geometric center and the outer core layer having an outer surface and inner surface; wherein at least one core layer comprises a rubber composition and at least one core layer consists essentially of a polyamide non-ionomeric composition, the polyamide composition consisting essentially of:
i) about 40 to about 98% by weight polyamide;
ii) about 1 to about 60% by weight of an acid anhydride-modified polyolefin, wherein the acid anhydride-modified polyolefin is an ethylene-vinyl acetate copolymer; and
iii) about 1 to about 60% by weight of a fatty acid additive selected from the group consisting of fatty acid salts, fatty acid amides, and mixtures thereof, wherein the center of the inner core and surface of the outer core layer each has a hardness, and the surface hardness of the outer core layer is greater than the center hardness of the inner core; and
b) a cover having at least one layer disposed about the core.
2. The golf ball of claim 1 , wherein the intermediate core layer comprises the rubber composition; and each of the inner core and outer core layers consists essentially of the polyamide non-ionomeric composition.
3. The golf ball of claim 1 , wherein the intermediate core layer consists essentially of the polyamide non-ionomeric composition and each of the inner and outer core layers comprises the rubber composition.
4. The golf ball of claim 1 , wherein the polyamide is selected from the group consisting of polyamide 6; polyamide 6,6; polyamide 6,10; polyamide 6,12; polyamide 11; polyamide 12; polyamide 6,9; and polyamide 4,6, and copolymers and blends thereof.
5. The golf ball of claim 1 , wherein the rubber composition comprises a rubber selected from the group consisting of polybutadiene, ethylene-propylene rubber, ethylene-propylene-diene rubber, polyisoprene, styrene-butadiene rubber, polyalkenamers, butyl rubber, halobutyl rubber, or polystyrene elastomers.
6. The golf ball of claim 1 , wherein the acid anhydride used to modify the ethylene-based copolymer is selected from the group consisting of maleic, fumaric, nadic, itaconic, and clorendic acid anhydrides, and substituted derivatives thereof.
7. The golf ball of claim 1 , wherein the fatty acid additive is a fatty acid salt and the fatty acid is selected from the group consisting of stearic acid, behenic acid, erucic acid, linoleic acid, oleic acid, palmitic acid, and dimerized derivatives, and mixtures thereof.
8. The golf ball of claim 1 , wherein the fatty acid additive is a fatty acid amide selected from the group consisting of primary monoamides, substituted monoamides, and bisamides.
9. The golf ball of claim 1 , wherein the rubber composition has a flex modulus of 1,000 to 60,000 psi and the polyamide composition has a flex modulus of 20,000 psi to 150,000 psi, the flex modulus of the rubber composition being less than the flex modulus of the polyamide composition.