Method of applying fugitive hydrophobic treatment to tissue product
Cellulosic tissue sheets having temporary moisture barrier properties are prepared by applying a solution of reactive size in emollient at an elevated temperature to a previously formed tissue sheet.
1. A method of making a wet laid cellulosic tissue sheet having fugitive water barrier properties comprising:
forming a wet laid cellulosic tissue sheet comprising cellulose fibers and
applying to the wet laid cellulosic tissue sheet from about 5 to about 60 pounds of an emollient per ton of fiber and from about 0.5 to about 5 pounds of a reactive size per ton of fiber, admixed together in a substantially nonaqueous solution comprising less than about 5% water by weight of the solution, to form a wet laid cellulosic tissue sheet having fugitive water barrier properties,
wherein said reactive size is soluble in said emollient at a temperature of less than 110° C.
2. The method of claim 1 , wherein the wet laid cellulosic tissue sheet is not cured at an elevated temperature following the application of the substantially nonaqueous solution of emollient and reactive size.
3. The method of claim 2 , wherein the wet laid cellulosic tissue sheet is dried by application of elevated temperatures prior to application of the solution of emollient and reactive size, and is not further dried by application of elevated temperatures after application of the solution of emollient and reactive size.
4. The method of claim 2 , wherein the reactive size is chosen from at least one of:
i. ketene dimers having the general formula:
wherein R 1 and R 2 represent saturated or unsaturated hydrocarbon groups having from 8 to 36 carbon atoms; and
ii. acid anhydrides having the general formula:
wherein R 3 and R 4 can be identical or different and represent saturated or unsaturated hydrocarbon groups suitably containing from 8 to 30 carbon atoms, and R 3 and R 4 together with the —C—O—C—moiety can form a 5 to 6 membered ring, optionally being further substituted with hydrocarbon groups containing up to 30 carbon atoms;
and mixtures thereof.
5. The method of claim 2 , wherein the reactive size is at least one ketene dimer chosen from alkyl ketene dimers, alkenyl ketene dimers, aryl ketene dimers, alkaryl ketene dimers, and mixtures thereof.
6. The method of claim 5 , wherein the ketene dimer in the wet laid cellulosic tissue sheet having fugitive water barrier properties comprises an intact β-lactone structure.
7. The method of claim 2 , wherein the reactive size is chosen from at least one of alkenyl ketene dimers and alkenyl succinic anhydrides.
8. The method of claim 2 , wherein the reactive size is chosen from at least one of isoocta-decenyl succinic anhydride, 1,3-cyclobutadione, and an unsaturated β-lactone.
9. The method of claim 2 , wherein the emollient is chosen from at least one of a mineral oil, propylene glycol, acetylated monoglycerides, caprylic acid, pelargonic acid, capric acid, caprylic/capric triglyceride, caprylic/capric/oleic triglyceride, dimethicone copolyol, cyclomethicone, and mixtures thereof.
10. The method of claim 9 , wherein the emollient is chosen from at least one of a mineral oil or propylene glycol.
11. The method of claim 2 , wherein the reactive size is chosen from at least one of alkenyl ketene dimers and alkenyl succinic anhydrides and wherein the emollient is chosen from at least one of a mineral oil or propylene glycol.
12. The method of claim 2 , wherein the amount of reactive size admixed with the emollient is from about 1 to about 25% by weight of the total weight of the solution of emollient and reactive size.
13. The method of claim 2 , wherein the amount of reactive size admixed with the emollient is from about 2 to about 20% by weight of the total weight of the solution of emollient and reactive size.
14. The method of claim 2 , wherein the amount of reactive size admixed with the emollient is from about 5 to about 15% by weight of the total weight of the solution of emollient and reactive size.
15. The method of claim 2 , wherein the amount of reactive size admixed with the emollient is from about 8 to 12% by weight of the total weight of the solution of emollient and reactive size.
16. The method of claim 2 , wherein the emollient is heated to between about 55 to 110° C. before being admixed with the reactive size.
17. The method of claim 2 , wherein the temperature of the solution of emollient and reactive size is between about 55° C. to 80° C. when applied to the cellulosic tissue sheet.
18. The method of claim 2 , wherein the amount of reactive size is from about 1.0 to about 3.5 pounds per ton of fiber.
19. The method of claim 2 , wherein the amount of reactive size is from about 1.5 to about 2.5 pounds per ton of fiber.
20. The method of claim 2 , wherein at least about 99.9% by weight of the reactive size in the wet laid cellulosic tissue sheet having fugitive water barrier properties is extractible using THF.
21. The method of claim 2 , wherein the water contact angle on one side of the wet laid cellulosic tissue sheet having fugitive water barrier properties exceeds 90° at 10 seconds after contact with water but decreases to less than 85° within 5 minutes after contact with water.
22. A method of making a wet laid cellulosic tissue sheet having fugitive water barrier properties comprising:
forming a wet laid cellulosic tissue sheet comprising cellulose fibers and
applying to the wet laid cellulosic tissue sheet from about 5 to about 60 pounds per ton of fiber of an emollient chosen from at least one of a mineral oil or propylene glycol, and from about 0.5 to about 5 pounds of a reactive size per ton of fiber chosen from at least one of alkenyl ketene dimers and alkenyl succinic anhydrides, admixed together in a substantially nonaqueous solution comprising less than about 5% water by weight of the solution, to form a wet laid cellulosic tissue sheet having fugitive water barrier properties,
wherein the amount of reactive size admixed with the emollient is from about 2 to about 20% by weight of the total weight of the solution of emollient and reactive size,
wherein said reactive size is soluble in said emollient at a temperature of less than 110° C.,
wherein the temperature of the solution of emollient and reactive size is between about 55° C. to 80° C. when applied to the wet laid cellulosic tissue sheet,
wherein the wet laid cellulosic tissue sheet is not cured at an elevated temperature following the application of the substantially nonaqueous solution of emollient and reactive size, and
wherein the wet laid cellulosic tissue sheet is dried by application of elevated temperatures prior to application of the solution of emollient and reactive size, and is not further dried by application of elevated temperatures after application of the solution of emollient and reactive size.