Rare earth-containing compounds to enhance performance of downhole treatment compositions
View Patent ↗A downhole treatment composition comprises a rare earth-containing compound comprising one or more of the following: scandium; yttrium; lanthanum; cerium; praseodymium; neodymium; promethium; samarium; lutetium; europium; gadolinium; terbium; dysprosium; holmium; erbium; thulium; or ytterbium, wherein the downhole treatment composition is a cement slurry, a drilling fluid, or a spacer fluid. Also disclosed are methods of cementing a wellbore, methods of displacing a first fluid, and methods of drilling a wellbore in a subterranean formation using the cement slurry, the spacer fluid, or the drilling fluid.
1. A method of cementing a wellbore, the method comprising
injecting into the wellbore a cement slurry comprising greater than about 10 wt % to less than about 30 wt % of a rare earth-containing compound based on the total weight of the cement slurry, an aqueous carrier, and a cement component that sets and hardens by reaction with water; and
allowing the slurry to set,
wherein the rare earth-containing compound comprises one or more of the following: scandium; yttrium; lanthanum; cerium; praseodymium; neodymium; promethium; samarium; lutetium; europium; gadolinium; terbium; dysprosium; holmium; erbium; thulium; or ytterbium; and the rare earth-containing compound is a halide, carbonate, sulfate, nitrate, acetate, or a combination comprising at least one of the foregoing.
2. The method of claim 1 , wherein the rare earth-containing compound comprises at least one of a cerium-containing compound, and a lanthanum-containing compound.
3. The method of claim 2 , wherein the rare earth-containing compound comprises one or more of the following: cerium chloride; cerium bromide; cerium carbonate; cerium sulfate; cerium nitrate; cerium ammonium nitrate; or cerium acetate.
4. The method of claim 1 , wherein the rare earth-containing compound is present in the form of halides.
5. The method of claim 1 , wherein the rare earth-containing compound comprising both the cerium-containing compound and the lanthanum-containing compound.
6. The method of claim 5 , wherein the cerium-containing compound comprises one or more of the following: cerium chloride; cerium bromide; cerium carbonate; cerium sulfate; cerium nitrate; cerium ammonium nitrate; or cerium acetate.
7. The method of claim 1 , wherein the rare earth-containing compound has a specific gravity of about 5 to about 10.
8. The method of claim 1 , wherein the rare earth-containing compound has a specific gravity of about 5 to about 8.
9. The method of claim 1 , wherein the aqueous carrier is present in the cement slurry in an amount of about 10% to about 60% by weight, based on the total weight of the cement slurry.
10. The method of claim 2 , wherein the cerium-containing compound comprises cerium chloride.
11. The method of claim 2 , wherein the lanthanum-containing compound is present in the form of halides, hydroxides, or a combination comprising at least one of the foregoing.
12. The method of claim 5 , wherein the cerium-containing compound comprises or cerium chloride.
13. The method of claim 5 , wherein the lanthanum-containing compound is present in the form of halides, hydroxides, or a combination comprising at least one of the foregoing.
14. The method of claim 1 , wherein the cement component comprises Portland cements, pozzolan cements, gypsum cements, high alumina content cements, silica cements, high alkalinity cements, or a combination comprising at least one of the foregoing.