Graphite article
A graphite article which can be compressed by more three (3%) percent at a contact pressure of 100 KPa or less without damaging the graphite article reducing the thermal impedance exhibited by the article. Also a graphite article comprising graphitized polymer having a thickness of at least 75 microns. Preferably the graphite has a density of less than 1.50 g/cc and a compressibility of more than 3% at a contact pressure of 100 KPa. Also the article has a generally sheet like shape. These articles may be used in a thermal management system to dissipate heat from a heat source.
1. A graphite article comprising a single sheet of a graphitized polymer having a thickness of more than 150 microns, the graphite article having a density of less than 1.00 g/cc, a compressibility of more than 10% and up to 75% at a contact pressure of 100 kPa, and a thermal impedance of no more than 0.25 cm 2 ° C./W at a contact pressure of at least 700 kPa.
2. The graphite article of claim 1 wherein the thickness comprises up to 500 microns.
3. The graphite article of claim 2 further comprising a dopant in a concentration of at least 5 percent by weight.
4. The graphite article of claim 3 further comprising surface perforations.
5. The graphite article of claim 3 wherein the dopant comprises a conductive polymer.
6. The graphite article of claim 3 wherein the dopant comprises an EMI modifier.
7. The graphite article of claim 6 wherein the dopant comprises nickel, copper, mu-metals or combinations thereof.
8. The graphite article of claim 2 wherein the thickness comprises at least 200 microns.
9. The graphite article of claim 1 having a resistivity of less than 0.010 (° C./W) at a contact pressure of at least 200 KPa.
10. The graphite article of claim 1 further comprising a graphitized polymer having no dopant.
11. The graphite article of claim 1 having a resistivity of less than 0.019 (° C./W) at a contact pressure of at least 200 KPa.
12. The graphite article of claim 1 , wherein as the contact pressure of the graphite article increases, the in-plane thermal conductivity increases.
13. The graphite article of claim 12 , wherein as the contact pressure of the graphite article increases from 100 KPa to 700 KPa, the in-plane thermal conductivity increases by at least 1.25 times.
14. The graphite article of claim 13 , wherein as the contact pressure of the graphite article increases from 100 KPa to 700 KPa, the in-plane thermal conductivity increases up to 2 times.
15. The graphite article of claim 1 , wherein the graphite article has a compressibility of more than 20% and less than 65% at a contact pressure of 100 KPa.
16. A compressible graphite article comprising a graphitized polymer sheet having a thickness of at least 200 microns, a density of less than 1.00 g/cc, and a thermal impedance of no more than 0.25 cm 2 ° C./W at a contact pressure of at least 700 kPa.
17. The graphite article of claim 16 wherein the thickness comprises up to 300 microns.
18. The graphite article of claim 16 having a resistivity of less than 0.019 (° C./W) at a contact pressure of at least 200 KPa.
19. The graphite article of claim 16 , wherein as the contact pressure of the graphite article increases, the in-plane thermal conductivity increases.
20. The graphite article of claim 16 , wherein as the contact pressure of the graphite article increases from 100 KPa to 700 KPa, the in-plane thermal conductivity increases by at least 1.25 times.