Multifilament fiber and method of making same
View Patent ↗A multipolymer fiber comprising a polyester phase formed from at least one polyester resin, present at between about 50 to about 95 percent by weight and a polyamide phase formed from at least one polyamide resin, present at between about 5 to about 50 percent by weight, wherein the polyamide phase is distinct from the polyester phase and comprises a plurality of polyamide fibrils dispersed in the polyester phase, and wherein the polyamide fibrils are separately distinguishable from each other.
1. A multipolymer fiber comprising:
a) A polyester phase formed from at least one polyester resin, present at between about 75 to about 95 percent by weight; and
b) A polyamide phase formed from at least one polyamide resin with an amine end group content of about 40 meq/kg or less, present at between about 5 to about 25 percent by weight, wherein the polyamide phase is distinct from the polyester phase and comprises a plurality of polyamide fibrils dispersed in the polyester phase, wherein the polyamide fibrils are separately distinguishable from each other, and wherein the polyamide fibrils have an average diameter size in the range from about 100 nm to about 400 nm.
2. The multipolymer fiber of claim 1 wherein a majority of the polyamide fibrils are continuous fibrils that span the length of the multipolymer fiber.
3. The multipolymer fiber of claim 1 wherein a majority of the polyamide fibrils have an average length that is at least 10 times the average diameter of the polyamide fibrils.
4. The multipolymer fiber of claim 1 wherein a majority of the polyamide fibrils have an average length that is at least about 10,000 nm.
5. The multipolymer fiber of claim 1 wherein the multipolymer fiber is a bulk continuous filament fiber.
6. The multipolymer fiber of claim 1 wherein the at least one polyester resin is selected from the group consisting of polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate and blends or copolymers thereof.
7. The multipolymer fiber of claim 1 wherein the at least one polyamide resin is selected from the group consisting of nylon 6,6, nylon 6, nylon 7, nylon 11, nylon 12, nylon 6,10, nylon 6,12, nylon DT, nylon 6T, nylon 61 and blends or copolymers thereof.
8. The multipolymer fiber of claim 1 wherein the polyester resin is polyethylene terephthalate.
9. The multipolymer fiber of claim 1 wherein the polyamide resin is nylon 6,6.
10. The multipolymer fiber of claim 1 wherein the polyamide phase is formed from at least one polyamide resin with an RV in the range of about 20 to about 60, and amine end groups in the range of about 20 to about 40 meq/kg.
11. The multipolymer fiber of claim 1 wherein the polyamide phase is formed from at least one polyamide resin with sulfonated isophthalic acid content of about 0.01 to about 8 percent by weight.
12. The multipolymer fiber of claim 1 wherein the polyester phase is formed from at least one polyester resin with isophthalic acid content of about 0.01 to about 8 percent by weight.
13. The multipolymer fiber of claim 1 wherein there is sufficient interfacial bonding between the polyester phase and the polyamide phase to maintain fibril stability of the plurality of polyamide fibrils dispersed within the polyester phase.
14. The multipolymer fiber of claim 13 wherein more than about 25% of the polyamide fibrils will break on the same cross-sectional plane as the polyester phase when the multipolymer fiber is subject to a freeze fracture test.
15. The multipolymer fiber of claim 13 wherein more than about 50% the polyamide fibrils will break on the same cross-sectional plane as the polyester phase when the multipolymer fiber is subject to a freeze fracture test.
16. The multipolymer fiber of claim 1 further comprising a component selected from the group consisting of colorants, delustrants, catalysts, spin assists, dye level modifiers, anti-microbial agents, stabilizers, flame-retardants, anti-oxidants, acidic moieties conducive to cationic dyeing, and combinations thereof.
17. The multipolymer fiber of claim 1 wherein the polyamide phase is present at between about 10 to about 25 percent by weight of the multipolymer fiber.
18. The multipolymer fiber of claim 1 further comprising about 1% or less by weight of a compatibilizing agent.
19. A yarn comprising the multipolymer fiber of claim 1 .
20. A textile comprising the yarn of claim 19 .
21. A carpet comprising the yarn of claim 19 .
22. A carpet of claim 21 wherein the vetterman-5K rating is 3 or greater when evaluated according to ASTM D5417.
23. A carpet of claim 21 wherein the pile compression is less than about 10%.
24. A method of making a multipolymer fiber, comprising:
a) combining at least one polyester resin and at least one polyamide resin with an amine end group content of about 40 meq/kg or less to form a polymer melt, wherein the at least one polyester resin is present from about 75 to about 95 percent by weight of the polymer melt and the at least one polyamide resin is present from about 5 to about 25 percent by weight of the polymer melt; and
b) forming a multipolymer fiber from the polymer melt comprising a polyester phase and a polyamide phase, wherein the polyamide phase is distinct from the polyester phase and comprises a plurality of polyamide fibrils dispersed in the polyester phase, wherein the polyamide fibrils are separately distinguishable from each other and wherein the polyamide fibrils have an average diameter size in the range from about 100 nm to about 400 nm.
25. The method of claim 24 wherein the at least one polyester resin has a moisture content below about 100 ppm and the at least one polyamide resin has a moisture content below 500 ppm.
26. The method of claim 24 wherein the polymer melt is dried to a moisture content below about 100 ppm prior to step (b).
27. The method of claim 24 wherein step (b) further comprises forming the multipolymer fiber at a spin draw ratio of about 90 or lower.
28. The method of claim 24 wherein step (b) further comprises advancing the polymer melt through a spinneret capillary at an exit velocity of about 30 feet per minute or greater.
29. The method of claim 24 wherein step (b) further comprises advancing the polymer melt through a spinneret capillary at an exit velocity of about 40 feet per minute or greater.
30. The method of claim 24 wherein a majority of the polyamide fibrils are continuous fibrils that span the length of the multipolymer fiber.
31. The method of claim 24 wherein a majority of the polyamide fibrils have an average length that is at least 10 times the average diameter of the polyamide fibrils.
32. The method of claim 24 wherein a majority of the polyamide fibrils have an average length that is at least about 10,000 nm.
33. The method of claim 24 wherein the multipolymer fiber is a bulk continuous filament fiber.
34. The method of claim 24 wherein the at least one polyester resin is selected from the group consisting of polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate and blends or copolymers thereof.
35. The method of claim 24 wherein the at least one polyamide resin is selected from the group consisting of nylon 6,6, nylon 6, nylon 7, nylon 11, nylon 12, nylon 6,10, nylon 6,12, nylon DT, nylon 6T, nylon 61 and blends or copolymers thereof.
36. The method of claim 24 wherein the polyester resin is polyethylene terephthalate.
37. The method of claim 24 wherein the polyamide resin is nylon 6,6.
38. The method of claim 24 wherein the at least one polyamide resin has an RV in the range of about 20 to about 60, and amine end groups in the range of about 20 to about 40 meq/kg.
39. The method of claim 24 wherein at least one polyamide resin has a sulfonated isophthalic acid content of about 0.01 to about 8 percent by weight.
40. The method of claim 24 wherein the at least one polyester resin has an isophthalic acid content of about 0.01 to about 8 percent by weight.
41. The method of claim 24 wherein there is sufficient interfacial bonding between the polyester phase and the polyamide phase to maintain fibril stability of the plurality of polyamide fibrils dispersed within the polyester phase.
42. The method of claim 24 wherein more than about 25% of the polyamide fibrils will break on the same cross-sectional plane as the polyester phase when the multipolymer fiber is subject to a freeze fracture test.
43. The method of claim 24 wherein more than about 50% the polyamide fibrils will break on the same cross-sectional plane as the polyester phase when the multipolymer fiber is subject to a freeze fracture test.
44. The method of claim 24 the polymer melt further comprises a component selected from the group consisting of colorants, delustrants, catalysts, spin assists, dye level modifiers, anti-microbial agents, stabilizers, flame-retardants, antioxidants, acidic moieties conducive to cationic dyeing, and combinations thereof.
45. The method of claim 24 wherein the polyamide phase is present at between about 10 to about 25 percent by weight of the multipolymer fiber.
46. The method of claim 24 wherein the polymer melt further comprises about 1% or less by weight of a compatibilizing agent.
47. A yarn comprising the multipolymer fiber formed from the method of claim 24 .
48. A textile comprising the yarn of claim 47 .
49. A carpet comprising the yarn of claim 47 .
50. A carpet of claim 49 wherein the vetterman-5K rating is 3 or greater when evaluated according to ASTM D5417.
51. A carpet of claim 50 wherein the pile compression is less than about 10%.
52. The method of claim 24 wherein the multipolymer fiber is formed by melt spinning.