Metal nanoparticle ink dispersion
View Patent ↗A metal nanoparticle ink dispersion is made by mixing ingredients comprising: a first solvent being nonpolar and having a boiling point above 160° C. at 1 atmosphere pressure; a second solvent having a boiling point above 230° C. at 1 atmosphere pressure, the second organic solvent being an aromatic hydrocarbon and having a higher boiling point than the first hydrocarbon solvent; and a plurality of metal nanoparticles. A method of printing the metal nanoparticle ink dispersion is also disclosed.
1. A metal nanoparticle inkjet ink dispersion made by mixing ingredients comprising:
a first solvent being nonpolar and having a boiling point above 160° C. at 1 atmosphere pressure;
a second solvent having a boiling point above 230° C. at 1 atmosphere pressure, the second solvent being a C 10 to C 18 arylcycloalkane and having a higher boiling point than the first solvent; and
a plurality of metal nanoparticles,
wherein a weight percent of the first solvent is greater than the weight percent of the second solvent in the inkjet ink dispersion.
2. The dispersion of claim 1 , wherein the first solvent is a saturated or unsaturated C 10 to C 20 hydrocarbon having at least one cyclic group.
3. The dispersion of claim 1 , wherein the first solvent is a compound selected from the group consisting of bicyclohexane, decalin, naphthalene and combinations thereof.
4. The dispersion of claim 1 , wherein the second solvent is phenylcyclohexane.
5. The dispersion of claim 1 , wherein a total amount of the first solvent and second solvent is at least 10 wt. %, based on the total weight of the composition.
6. The dispersion of claim 1 , wherein the metal nanoparticles comprise at least one metal selected from the group consisting of Al, Ag, Au, Pt, Pd, Cu, Co, Cr, In and Ni.
7. The dispersion of claim 1 , wherein the metal nanoparticles comprise Ag.
8. The dispersion of claim 1 , wherein the metal nanoparticles are in a concentration ranging from about 10 wt. % to about 90 wt. %.
9. The dispersion of claim 1 , wherein the metal nanoparticles include an organic stabilizing group attached thereto.
10. The dispersion of claim 1 , further comprising a polymeric adhesion promoter.
11. A method comprising:
providing a metal nanoparticle ink dispersion made by mixing ingredients comprising (a) a first organic solvent with a boiling point above 160° C. at 1 atmosphere pressure; (b) a second organic solvent with a boiling point above 230° C. at 1 atmosphere pressure, the second organic solvent having a higher boiling point than the first organic solvent, the second organic solvent being a C 10 to C 18 arylcycloalkane; and (c) a plurality of metal nanoparticles; and
inkjet printing the ink dispersion onto a substrate.
12. The method of claim 11 , wherein the printing comprises:
selectively depositing the metal nanoparticle dispersion to form a nanoparticle ink pattern on the substrate; and
heating the deposited nanoparticle ink pattern to form a conductive metal pattern.
13. The method of claim 12 , wherein the metal pattern has a conductivity that is greater than 1.0×10 4 S/cm.
14. The method of claim 12 , wherein the heating is performed at a temperature ranging from about 80° C. to about 250° C.
15. The method of claim 11 , wherein the metal nanoparticles comprise at least one metal selected from the group consisting of Al, Ag, Au, Pt, Pd, Cu, Co, Cr, In and Ni.
16. The method of claim 11 , wherein the metal nanoparticles comprise Ag.
17. The method of claim 11 , wherein the first solvent is a saturated or unsaturated C 10 to C 20 hydrocarbon having at least one cyclic group.
18. The method of claim 11 , wherein the first solvent is a compound selected from the group consisting of bicyclohexane, decalin and combinations thereof.
19. The method of claim 11 , wherein the second solvent is phenylcyclohexane.