Golf ball layers including a fatty acid (meth)acrylic acid salt
The present invention relates to the use of a fatty acid (meth)acrylic acid salt in a golf ball layer. The fatty acid (meth)acrylic acid salt may be added to one or more portions of a golf ball including a core, intermediate, or cover layer. For example, in one embodiment, the fatty acid (meth)acrylic acid salt may be blended with a polybutadiene rubber material. In another embodiment, the fatty acid (meth)acrylic acid salt of the present invention may be blended with an ionomer. In some embodiments, the fatty acid (meth)acrylic acid salt may be blended with a formulation including both a polybutadiene rubber component and an ionomer.
1. A golf ball comprising a cover, a core, and an intermediate layer disposed between the cover and the core, wherein the core comprises:
a blend of a polybutadiene rubber and a fatty acid (meth)acrylic acid salt, wherein the fatty acid (meth) acrylic acid salt comprises the reaction product of a fatty acid, a (meth)acrylic acid monomer, and M(OH) x or M x O y , where M is a metal cation and x and y independently range from about 1 to about 7, and wherein the fatty acid (meth)acrylic acid salt is present in the blend in an amount of about 1 phr to about 70 phr.
2. The golf ball of claim 1 , wherein the fatty acid (meth)acrylic acid salt comprises stearic acid or oleic acid.
3. The golf ball of claim 1 , wherein the blend further comprises a coagent selected from zinc diacrylate, zinc oxide, a fatty acid, a fatty acid salt, or combinations thereof.
4. The golf ball of claim 1 , wherein the fatty acid (meth)acrylic acid salt is present in the blend in an amount of about 10 phr to about 50 phr.
5. The golf ball of claim 1 , wherein the core has a hardness of about 70 Shore C to about 85 Shore C.
6. The golf ball of claim 1 , wherein the fatty acid comprises at least 4 carbon atoms.
7. A golf ball comprising a core, a cover, and an intermediate layer disposed between the core and the cover, wherein the core comprises:
a blend of a polybutadiene rubber and a fatty acid (meth)acrylic acid salt, wherein the fatty acid (meth)acrylic acid salt comprises the reaction product of a fatty acid having the following formula:
where R is a straight or branched, saturated or unsaturated, carbon chain having at least 3 carbon atoms, a (meth)acrylic acid monomer, and a metal component having the formula M(OH) x or M x O y , where M is a metal cation and x and y independently range from about 1 to about 7, and wherein the fatty acid (meth)acrylic acid salt is present in the blend in an amount of about 10 phr to about 50 phr.
8. The golf ball of claim 7 , wherein the fatty acid is saturated.
9. The golf ball of claim 7 , wherein the (meth)acrylic acid monomer comprises acrylic acid or methacrylic acid.
10. The golf ball of claim 7 , wherein M comprises zinc, magnesium, or cadmium.
11. The golf ball of claim 7 , wherein the metal component is selected from the group consisting of magnesium oxide (MgO), zinc oxide (ZnO), cadmium oxide (CdO), and combinations thereof.
12. The golf ball of claim 7 , wherein the blend further comprises a crosslinking initiator selected from the group consisting of peroxides, high energy radiation sources capable of generating free radicals, or combinations thereof.
13. The golf ball of claim 7 , wherein the fatty acid comprises stearic acid or oleic acid.
14. The golf ball of claim 7 , wherein the blend further comprises a coagent selected from the group consisting of zinc salts of acrylates, diacrylates, methacrylates, and dimethacrylates.
15. A golf ball comprising a core, an intermediate layer disposed about the core, and a cover disposed about the intermediate layer, wherein the core comprises:
a blend of a polybutadiene rubber, a fatty acid (meth)acrylic acid salt in an amount of about 1 phr to about 70 phr, and a crosslinking initiator, wherein the fatty acid (meth)acrylic acid salt comprises the reaction product of a fatty acid, a (meth)acrylic acid monomer, and a metal oxide or metal hydroxide.
16. The golf ball of claim 15 , wherein the fatty acid (meth)acrylic acid salt is present in the blend in an amount of about 10 phr to about 50 phr.
17. The golf ball of claim 15 , wherein the crosslinking initiator is selected from the group consisting of peroxides, high energy radiation sources capable of generating free radicals, and combinations thereof.
18. The golf ball of claim 15 , wherein the blend further comprises a coagent selected from the group consisting of zinc diacrylate, zinc oxide, a fatty acid, a fatty acid salt, and combinations thereof, wherein the coagent is present in an amount of about 5 phr to about 55 phr.
19. The golf ball of claim 15 , wherein the (meth)acrylic acid monomer comprises acrylic acid or methacrylic acid.
20. The golf ball of claim 15 , wherein the blend comprises a metal oxide selected from the group consisting of magnesium oxide (MgO), zinc oxide (ZnO), cadmium oxide (CdO), and combinations thereof.