IP Library Granted Patent US 9,901,018
Granted Patent B1
US 9,901,018 · App. 15/490,249 · Granted Feb 20, 2018

Electrically conductive hybrid polymer material

Inventors: Zachary J. Richmond (Warren, OH); Evangelia Rubino (Warren, OH); Anshuman Shrivastava (Twinsburg, OH)
Assignee: Delphi Technologies, Inc.
H05K9/0083C08L101/12H01B1/124H01B1/24H01B3/004H01B7/17H01B13/24H01R13/6599C08L2203/202
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Quick Facts
Patent No.
US 9,901,018
App. No.
15/490,249
Granted
Feb 20, 2018
Kind
B1
Abstract

An electrically conductive hybrid polymer material is described herein. The hybrid polymer material includes 0.01% to 1% by weight of carbon nanoparticles, 1% to 10% by weight of a conductive polymeric material, 1% to 20% of electrically conductive fibers having a metallic surface and 69% or more by weight of a nonconductive polymeric base material. The carbon nanoparticles may be carbon nanotubes, graphite nanoparticles, graphene nanoparticles, and/or fullerene nanoparticles. The conductive polymeric material may be an inherently conductive polymer, a radical polymers, or an electroactive polymer. The electrically conductive fibers may be stainless steel fibers, metal plated carbon fibers, or metal nanowires. The nonconductive polymeric base material may be selected from materials that are pliable at temperatures between −40° C. and 125° C. or materials that are rigid in this temperature range. The hybrid polymer material may be used to provide EMI shielding for wire cables of housings of electrical assemblies.

Claims (32)

1. An electrically conductive hybrid polymer material, comprising:

0.01% to 0.2% by weight of carbon nanoparticles;

1% to 10% by weight of a conductive polymeric material;

11% to 20% by weight of electrically conductive fibers having a metallic surface; and

69% or more by weight of a nonconductive polymeric material.

2. The hybrid polymer material according to claim 1 , wherein the carbon nanoparticles are selected from the group consisting of carbon nanotubes, graphite nanoparticles, graphene nanoparticles, and fullerene nanoparticles.

3. The hybrid polymer material according to claim 1 , wherein the conductive polymeric material is selected from the group consisting of inherently conductive polymers, radical polymers, and electroactive polymers.

4. The hybrid polymer material according to claim 3 , wherein the inherently conductive polymers are selected from the group consisting of: polylanine, 3,4-ethylenedioxythiophene, 3,4-ethylenedioxythiophene polystyrene sulfonate, and 4,4-cyclopentadithiophene.

5. The hybrid polymer material according to claim 1 , wherein the electrically conductive fibers having a metallic surface are selected from the group consisting of stainless steel fibers, metal plated carbon fibers, and metal nanowires.

6. The hybrid polymer material according to claim 1 , wherein the nonconductive polymeric material is selected from the group consisting of: polyethylene, polypropylene, and polyvinyl chloride.

7. The hybrid polymer material according to claim 6 , wherein the hybrid polymer material is substantially pliable at temperatures between −40° C. and 125° C.

8. A wire cable assembly, comprising:

a wire cable; and

the hybrid polymer material according to claim 6 surrounding the wire cable.

9. The hybrid polymer material according to claim 1 , wherein the nonconductive polymeric material is selected from the group consisting of: acrylic, polyester, polybutylene terephthalate, acrylonitrile butadiene styrene, and polyamide.

10. The hybrid polymer material according to claim 9 , wherein the hybrid polymer material is substantially rigid at temperatures between −40° C. and 125° C.

11. An electrical assembly comprising a housing formed of the hybrid polymer material according to claim 9 .

12. An electrically conductive hybrid polymer material, essentially consisting of:

0.01% to 0.2% by weight of carbon nanoparticles;

1% to 10% by weight of a conductive polymeric material;

11% to 20% by weight of electrically conductive fibers having a metallic surface; and

a remaining percentage by weight of a nonconductive polymeric material.

13. The hybrid polymer material according to claim 12 , wherein the carbon nanoparticles are selected from the group consisting of carbon nanotubes, graphite nanoparticles, graphene nanoparticles, and fullerene nanoparticles.

14. The hybrid polymer material according to claim 12 , wherein the conductive polymeric material is selected from the group consisting of inherently conductive polymers, radical polymers, and electroactive polymers.

15. The hybrid polymer material according to claim 14 , wherein the inherently conductive polymers are selected from the group consisting of: polylanine, 3,4-ethylenedioxythiophene, 3,4-ethylenedioxythiophene polystyrene sulfonate, and 4,4-cyclopentadithiophene.

16. The hybrid polymer material according to claim 12 , wherein the electrically conductive fibers having a metallic surface are selected from the group consisting of stainless steel fibers, metal plated carbon fibers, and metal nanowires.

17. The hybrid polymer material according to claim 12 , wherein the nonconductive polymeric material is selected from the group consisting of: polyethylene, polypropylene, and polyvinyl chloride.

18. A wire cable assembly, comprising:

a wire cable; and

the hybrid polymer material according to claim 17 surrounding the wire cable.

19. The hybrid polymer material according to claim 12 , wherein the nonconductive polymeric material is selected from the group consisting of: acrylic, polyester, polybutylene terephthalate, acrylonitrile butadiene styrene, and polyamide.

20. An electrical assembly comprising a housing formed of the hybrid polymer material according to claim 19 .

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 25, 2018
From: DELPHI TECHNOLOGIES INC.
To: APTIV TECHNOLOGIES LIMITED
Reel/Frame 047143/0874 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 18, 2017
From: RICHMOND, ZACHARY J.; RUBINO, EVANGELIA; SHRIVASTAVA, ANSHUMAN
To: DELPHI TECHNOLOGIES, INC.
Reel/Frame 042044/0401 →