Coating compositions for packaging articles such as food and beverage containers
View Patent ↗A method of forming a coating on a food or beverage container, which includes spraying a coating composition onto an interior surface of the food or beverage container, where the coating composition includes an emulsion-polymerized latex copolymer having copolymer chains of one or more mono-unsaturated monomers that are cross-linked with one or more multi-unsaturated monomers. The method also includes heating the sprayed coating composition to cure the coating composition, thereby providing the coating on the interior surface of the food or beverage container.
1. An article comprising a food or beverage container, or a portion thereof, including:
a metal substrate; and
an inside spray coating disposed on at least a portion of the metal substrate, wherein the coating is produced from an inside-spray coating composition having an emulsion-polymerized latex copolymer that is a reaction product of monomers comprising:
one or more mono-unsaturated monomers each having a single ethylenically-unsaturated group; and
one or more multi-unsaturated monomers each having two or more ethylenically-unsaturated groups, wherein the multi-unsaturated monomer(s) each have a divalent chain length with at least two carbon atoms between at least two of the ethylenically-unsaturated groups, and have a concentration from 8% by weight to 25% by weight, based on a total weight of the monomers used to produce the emulsion-polymerized latex copolymer;
wherein the monomers used to produce the emulsion-polymerized latex copolymer are substantially free of oxirane groups.
2. The article of claim 1 , wherein the multi-unsaturated monomer comprises 1,4-butanediol di(meth)acrylate, and wherein 1,4-butanediol di(meth)acrylate constitutes from 8% by weight to 25% by weight of the emulsion-polymerized latex copolymer, based on the total weight of the monomers used to produce the emulsion-polymerized latex copolymer.
3. The article of claim 1 , wherein the concentration of the one or more multi-unsaturated monomers ranges from 10% by weight to 20% by weight, based on the total weight of the monomers used to produce the emulsion-polymerized latex, and wherein the glass transition temperature of the coating ranges from about 60° C. to about 120° C.
4. The article of claim 1 , wherein the coating exhibits a metal exposure less than 2 milliamps, pursuant to the Initial Metal Exposure test.
5. The article of claim 1 , wherein the multi-unsaturated monomer(s) constitute greater than 10% by weight and less than 25% by weight of the monomers used to produce the emulsion-polymerized latex copolymer, the coating is substantially free of monomeric or polymerized styrene, and the cured coating has a glass transition temperature greater than 50° C.
6. The article of claim 1 , wherein the one or more mono-unsaturated monomers comprise one or more ethylenically-unsaturated, acid-functional monomers whose concentration ranges from 3% by weight to 30% by weight, based on the total weight of the monomers used to produce the emulsion-polymerized latex copolymer.
7. The article of claim 6 , wherein the concentration of the one or more ethylenically-unsaturated, acid-functional monomers ranges from 5% by weight to 20% by weight, based on the total weight of the monomers used to produce the emulsion-polymerized latex copolymer.
8. An inside spray coating composition comprising:
an aqueous carrier; and
an emulsion-polymerized latex copolymer dispersed in the aqueous carrier, and comprising:
one or more mono-unsaturated monomers each having a single ethylenically-unsaturated group; and
one or more multi-unsaturated monomers each having two or more ethylenically-unsaturated groups, wherein the multi-unsaturated monomer(s) each have a divalent chain length with at least two carbon atoms between at least two of the ethylenically-unsaturated groups, and constitute from 8% by weight to 25% by weight of the monomers used to produce the emulsion-polymerized latex copolymer;
wherein the coating composition has an average viscosity ranging from about 5 seconds to about 40 seconds, pursuant to the Viscosity Test; and
wherein the coating composition has a resin solids content ranging from about 10% by weight to about 30% by weight, based on a total weight of the coating composition.
9. The coating composition of claim 8 , wherein the one or more mono-unsaturated monomers comprise one or more ethylenically-unsaturated, acid-functional monomers whose concentration ranges from 3% by weight to 30% by weight, based on the total weight of the monomers used to produce the emulsion-polymerized latex copolymer.
10. The coating composition of claim 8 , wherein the one or more mono-unsaturated monomers further comprise one or more polymerizable surfactants.
11. The coating composition of claim 8 , wherein the multi-unsaturated monomer comprises 1,4-butanediol di(meth)acrylate, and wherein 1,4-butanediol di(meth)acrylate constitutes from 8% by weight to 25% by weight of the emulsion-polymerized latex copolymer, based on the total weight of the monomers used to produce the emulsion-polymerized latex copolymer.
12. The coating composition of claim 8 , wherein the concentration of the one or more multi-unsaturated monomers ranges from 10% by weight to 20% by weight, based on the total weight of the monomers used to produce the emulsion-polymerized latex, and wherein the coating composition is substantially free of halogenated compounds.
13. The coating composition of claim 8 , wherein the coating composition exhibits a change in viscosity, if any, of less than about 25% pursuant to the Pot Life Stability test.
14. The coating composition of claim 8 , wherein the coating composition includes less than 1 weight percent, if any, of vegetable oils.
15. The coating composition of claim 8 , wherein the multi-unsaturated monomer(s) constitute greater than 10% by weight and less than 25% by weight of the monomers used to produce the emulsion-polymerized latex copolymer.
16. The coating composition of claim 8 , wherein the multi-unsaturated monomer(s) constitute greater than 12% by weight and less than 20% by weight of the monomers used to produce the emulsion-polymerized latex copolymer.
17. The coating composition of claim 8 , wherein the coating composition is substantially free of monomeric or polymerized styrene.
18. The coating composition of claim 8 , wherein a cured coating of the coating composition has a glass transition temperature greater than 50° C.
19. The coating composition of claim 8 , wherein the multi-unsaturated monomer(s) constitute greater than 10% by weight and less than 25% by weight of the monomers used to produce the emulsion-polymerized latex copolymer, the coating composition is substantially free of monomeric or polymerized styrene, and a cured coating of the coating composition has a glass transition temperature greater than 50° C.
20. The coating composition of claim 8 , wherein the average viscosity of the coating composition ranges from about 15 seconds to about 25 seconds.
21. The coating composition of claim 20 , wherein the concentration of the one or more ethylenically-unsaturated, acid-functional monomers ranges from 5% by weight to 20% by weight, based on the total weight of the monomers used to produce the emulsion-polymerized latex copolymer.