IP Library Granted Patent US 10,920,133
Granted Patent B2
US 10,920,133 · App. 16/003,191 · Granted Feb 16, 2021

Compositions for dust control and methods making and using same

Inventors: Sarkis Kakadjian (Houston, TX); Jose Garza (Houston, TX); Marvin Solomon (Houston, TX)
Assignee: NexTier Completion Solutions Inc.
C09K8/805C09K3/22C09K8/82C09K8/62E21B43/267
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Quick Facts
Patent No.
US 10,920,133
App. No.
16/003,191
Granted
Feb 16, 2021
Kind
B2
Abstract

Proppant dust suppression compositions including: (a) at least one sugar alcohol ester or a sugar alcohol esters or a plurality of sugar alcohol esters; or (b) a mixture of at least one glyceride or a glyceride or a plurality of glycerides and at least one sugar alcohol ester or a sugar alcohol esters or a plurality of sugar alcohol esters and methods for using the compositions, where the treated proppant composition has between about 30% and 100% proppant dust reduction and wherein the at least one sugar alcohol ester improves flowability of treated proppant so that the treated proppant has reduced screen out propensity.

Claims (79)

1. A treated dust-containing material composition comprising:

a dust-containing material, and

an effective amount of an oil based dust suppression composition comprising:

(a) at least one sugar alcohol ester, and

(b) at least one glyceride,

wherein the oil based dust suppression composition reduces dust of the dust-containing material from about 30% to about 100%,

wherein the oil based dust suppression composition is free or substantially free of water or an aqueous solution, and

wherein the at least one sugar alcohol ester improves flowability and reduces screen out propensity of the treated dust-containing material.

2. The composition of claim 1 , further comprising:

(c) at least one pour point depressant, wherein the at least one pour point depressant is selected from the group consisting of polymethacrylates, polyacrylates, acrylate-styrene copolymers, esterified olefin polymers or copolymers, styrene maleic anhydride copolymers, alkylated polystyrenes, and vinyl acetate-fumarate copolymers, poly alpha olefins, and mixtures thereof.

3. The composition of claim 1 , wherein the composition comprises:

between about 95 vol. % and about 50 vol. % of at least one glyceride and between 5 vol. % and 50 vol. % of at least one sugar alcohol ester, or

between about 90 vol. % and about 50 vol. % of at least one glyceride and between 10 vol. % and 50 vol. % of at least one sugar alcohol ester, or

between about 80 vol. % and about 50 vol. % of at least one glyceride and between 20 vol. % and 50 vol. % of at least one sugar alcohol ester, or

between about 70 vol. % and about 50 vol. % of at least one glyceride and between 30 vol. % and 50 vol. % of at least one sugar alcohol ester.

4. The composition of claim 3 , further comprising:

between about 0.1 wt. % and about 5 wt. % of at least one pour point depressant, wherein the at least one pour point depressant is selected from the group consisting of polymethacrylates, polyacrylates, acrylate-styrene copolymers, esterified olefin polymers or copolymers, styrene maleic anhydride copolymers, alkylated polystyrenes, and vinyl acetate-fumarate copolymers, poly alpha olefins, and mixtures thereof.

5. The composition of claim 1 , wherein:

the at least one glyceride comprises at least one compound of the general formula (I):

Z 1 , Z 2 , and Z 3 are hydroxyl groups or ester groups having the formula OC(═O)R, each R group is independently a C 4 -C 40 hydrocarbyl group, and

Z 1 , Z 2 , and Z 3 are not all hydroxyl groups; and

the at least one sugar alcohol ester comprises at least one compound of the general formula (III):

Z 4 OCH 2 (CHOZ 5 ) n CH 2 OZ 6   (III)

Z 4 , each Z 5 , and Z 6 are hydroxyl groups or ester groups having the formula OC(═O)R,

each R group is a C 4 -C 40 hydrocarbyl group,

Z 4 , Z 5 , and Z 6 are not all hydroxyl groups,

n is an integer having a value between 2 and 8, and

cyclic derivatives thereof.

6. The composition of claim 5 , wherein the at least one glyceride comprises a monoglyceride of formula (IA), a diglyceride of formula (IB), a triglyceride of formula (IC), or mixtures thereof:

R 1 , R 2 , and R 3 are independently C 4 -C 40 hydrocarbyl groups.

7. The composition of claim 6 , wherein:

the —C(═O)—R 1 , —C(═O)—R 2 , and —C(═O)—R 3 moieties are derived from C 4 -C 40 fatty acids.

8. The composition of claim 1 , wherein:

the at least one glyceride comprises at least one vegetable oil selected from the group consisting of coconut oil, corn oil, cottonseed oil, olive oil, palm oil, peanut oil, rapeseed oil, safflower oil, sesame oil, soybean oil, sunflower oil, almond oil, beech nut oil, brazil nut oil, cashew oil, hazelnut oil, macadamia oil, mongongo nut oil, pecan oil, pine nut oil, pistachio oil, walnut oil, grapefruit seed oil, bitter gourd oil, bottle gourd oil, buffalo gourd oil, butternut squash seed oil, egusi seed oil, pumpkin seed oil, watermelon seed oil, açai oil, black seed oil, blackcurrant seed oil, borage seed oil, evening primrose oil, flaxseed oil, amaranth oil, apricot oil, apple seed oil, argan oil, avocado oil, babassu oil, ben oil, borneo tallow nut oil, cape chestnut oil, carob pod oil, algaroba oil, cocoa butter, cocklebur oil, cohune oil, coriander seed oil, date seed oil, dika oil, grape seed oil, hemp oil, kapok seed oil, kenaf seed oil, lallemantia oil, mafura oil, marula oil, meadowfoam seed oil, mustard oil, niger seed oil, poppyseed oil, nutmeg butter, okra seed oil, papaya seed oil, perilla seed oil, persimmon seed oil, pequi oil, pili nut oil, pomegranate seed oil, poppyseed oil, pracaxi oil, virgin pracaxi oil, prune kernel oil, quinoa oil, ramtil oil, rice bran oil, royle oil, shea butter, sacha inchi oil, sapote oil, seje oil, taramira oil, tea seed oil, camellia oil, thistle oil, tigernut oil, tigernut-sedge oil, tobacco seed oil, tomato seed oil, wheat germ oil, and mixtures thereof, and

the at least one sugar alcohol ester is selected from the group consisting of erythritol esters, threitol esters, arabitol esters, xylitol esters, ribitol esters, mannitol esters, sorbitol esters, galactitol esters, fucitol esters, iditol esters, inositol esters, volemitol esters, isomalt esters, maltitol esters, lactitol esters, maltotriitol esters, maltotetraitol esters, cyclic derivatives thereof, and mixtures thereof.

9. The composition of claim 8 , wherein:

the at least one vegetable oil is selected from the group consisting of coconut oil, corn oil, cottonseed oil, olive oil, palm oil, peanut oil, rapeseed oil, safflower oil, sesame oil, soybean oil, sunflower oil, almond oil, grapefruit seed oil, avocado oil, grape seed oil, hemp oil, and mixtures thereof.

10. The composition of claim 9 , wherein:

the at least one vegetable oil is selected from the group consisting of coconut oil, corn oil, cottonseed oil, olive oil, palm oil, peanut oil, rapeseed oil, safflower oil, sesame oil, soybean oil, sunflower oil, almond oil, avocado oil, and mixtures thereof, and

the at least one sugar alcohol fatty acid ester comprises at least one sorbitol and/or sorbitan fatty acid ester.

11. A method comprising:

applying an effective amount of an oil based proppant dust suppression composition to a proppant to form a reduced dust forming or treated proppant,

wherein the oil based proppant dust suppression composition comprises:

a mixture of at least one sugar alcohol ester and at least one glyceride,

wherein the oil based proppant dust suppression composition reduces proppant dust from about 30% to about 100%,

wherein the oil based dust suppression composition is free or substantially free of water or an aqueous solution, and

wherein the at least one sugar alcohol ester improves flowability and reduces screen out propensity of the treated proppant.

12. The method of claim 11 , further comprising:

(c) at least one pour point depressant, wherein the at least one pour point depressant is selected from the group consisting of polymethacrylates, polyacrylates, acrylate-styrene copolymers, esterified olefin polymers or copolymers, styrene maleic anhydride copolymers, alkylated polystyrenes, and vinyl acetate-fumarate copolymers, poly alpha olefins, and mixtures thereof.

13. The method of claim 11 , wherein the composition comprises:

between about 95 vol. % and about 50 vol. % of at least one glyceride and between 5 vol. % and 50 vol. % of at least one sugar alcohol ester, or

between about 90 vol. % and about 50 vol. % of at least one glyceride and between 10 vol. % and 50 vol. % of at least one sugar alcohol ester, or

between about 80 vol. % and about 50 vol. % of at least one glyceride and between 20 vol. % and 50 vol. % of at least one sugar alcohol ester, or

between about 70 vol. % and about 50 vol. % of at least one glyceride and between 30 vol. % and 50 vol. % of at least one sugar alcohol ester.

14. The method of claim 13 , further comprising:

between about 0.1 wt. % and about 5 wt. % of at least one pour point depressant, wherein the at least one pour point depressant is selected from the group consisting of polymethacrylates, polyacrylates, acrylate-styrene copolymers, esterified olefin polymers or copolymers, styrene maleic anhydride copolymers, alkylated polystyrenes, and vinyl acetate-fumarate copolymers, poly alpha olefins, and mixtures thereof.

15. The method of claim 11 , wherein:

the at least one glyceride comprises at least one compound of the general formula (I):

Z 1 , Z 2 , and Z 3 are hydroxyl groups or ester groups having the formula —OC(═O)R, each R group is independently a C 4 -C 40 hydrocarbyl group, and

Z 1 , Z 2 , and Z 3 are not all hydroxyl groups; and

the at least one sugar alcohol ester comprises at least one compound of the general formula (III):

Z 4 OCH 2 (CHOZ 5 ) n CH 2 OZ 6   (III)

Z 4 , each Z 5 , and Z 6 are hydroxyl groups or ester groups having the formula —OC(═O)R,

each R group is a C 4 -C 40 hydrocarbyl group,

Z 4 , Z 5 , and Z 6 are not all hydroxyl groups,

n is an integer having a value between 2 and 8, and

cyclic derivatives thereof.

16. The method of claim 15 , wherein the at least one glyceride comprises a monoglyceride of formula (IA), a diglyceride of formula (IB), a triglyceride of formula (IC), or mixtures thereof:

R 1 , R 2 , and R 3 are independently C 4 -C 40 hydrocarbyl groups.

17. The method of claim 16 , wherein:

the —C(═O)—R 1 , —C(═O)—R 2 , and —C(═O)—R 3 moieties are derived from C 4 -C 40 fatty acids.

18. The method of claim 11 , wherein:

the at least one glyceride comprises at least one vegetable oil selected from the group consisting of coconut oil, corn oil, cottonseed oil, olive oil, palm oil, peanut oil, rapeseed oil, safflower oil, sesame oil, soybean oil, sunflower oil, almond oil, beech nut oil, brazil nut oil, cashew oil, hazelnut oil, macadamia oil, mongongo nut oil, pecan oil, pine nut oil, pistachio oil, walnut oil, grapefruit seed oil, bitter gourd oil, bottle gourd oil, buffalo gourd oil, butternut squash seed oil, egusi seed oil, pumpkin seed oil, watermelon seed oil, açai oil, black seed oil, blackcurrant seed oil, borage seed oil, evening primrose oil, flaxseed oil, amaranth oil, apricot oil, apple seed oil, argan oil, avocado oil, babassu oil, ben oil, borneo tallow nut oil, cape chestnut oil, carob pod oil, algaroba oil, cocoa butter, cocklebur oil, cohune oil, coriander seed oil, date seed oil, dika oil, grape seed oil, hemp oil, kapok seed oil, kenaf seed oil, lallemantia oil, mafura oil, marula oil, meadowfoam seed oil, mustard oil, niger seed oil, poppyseed oil, nutmeg butter, okra seed oil, papaya seed oil, perilla seed oil, persimmon seed oil, pequi oil, pili nut oil, pomegranate seed oil, poppyseed oil, pracaxi oil, virgin pracaxi oil, prune kernel oil, quinoa oil, ramtil oil, rice bran oil, royle oil, shea butter, sacha inchi oil, sapote oil, seje oil, taramira oil, tea seed oil, camellia oil, thistle oil, tigernut oil, tigernut-sedge oil, tobacco seed oil, tomato seed oil, wheat germ oil, and mixtures thereof, and

the at least one sugar alcohol ester is selected from the group consisting of erythritol esters, threitol esters, arabitol esters, xylitol esters, ribitol esters, mannitol esters, sorbitol esters, galactitol esters, fucitol esters, iditol esters, inositol esters, volemitol esters, isomalt esters, maltitol esters, lactitol esters, maltotriitol esters, maltotetraitol esters, cyclic derivatives thereof, and mixtures thereof.

19. The method of claim 18 , wherein:

the at least one vegetable oil is selected from the group consisting of coconut oil, corn oil, cottonseed oil, olive oil, palm oil, peanut oil, rapeseed oil, safflower oil, sesame oil, soybean oil, sunflower oil, almond oil, grapefruit seed oil, avocado oil, grape seed oil, hemp oil, and mixtures thereof.

20. The method of claim 19 , wherein:

the at least one vegetable oil is selected from the group consisting of coconut oil, corn oil, cottonseed oil, olive oil, palm oil, peanut oil, rapeseed oil, safflower oil, sesame oil, soybean oil, sunflower oil, almond oil, avocado oil, and mixtures thereof, and

the at least one sugar alcohol fatty acid ester comprises at least one sorbitol and/or sorbitan fatty acid ester.

Assignments (5)
RELEASE OF SECURITY INTEREST FILED OCTOBER 31, 2019 AT REEL/FRAME 050897/0314 Recorded Sep 1, 2023
From: BARCLAYS BANK PLC
To: KEANE FRAC, LP; C&J SPEC-RENT SERVICES, INC. N/K/A NEXTIER COMPLETION SOLUTIONS INC.; KING MERGER SUB II LLC; C&L WELL SERVICES, INC.; KEANE GROUP HOLDINGS, LLC
Reel/Frame 064802/0830 →
RELEASE OF SECURITY INTEREST FILED OCTOBER 31, 2019 AT REEL/FRAME 050897/0470 Recorded Sep 1, 2023
From: BANK OF AMERICA, N.A.
To: KEANE FRAC, LP; C&J SPEC-RENT SERVICES, INC. N/K/A NEXTIER COMPLETION SOLUTIONS INC.; KING MERGER SUB II LLC; C&J WELL SERVICES, INC.; KEANE GROUP HOLDINGS, LLC
Reel/Frame 064803/0057 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 8, 2021
From: KEANE GROUP HOLDINGS, LLC
To: NEXTIER COMPLETION SOLUTIONS INC.
Reel/Frame 058332/0367 →
TL SECURITY AGREEMENT Recorded Oct 31, 2019
From: C&J SPEC-RENT SERVICES, INC.; C&J WELL SERVICES, INC.; KING MERGER SUB II LLC (F/K/A C&J ENERGY SERVICES, INC.); KEANE FRAC, LP; KEANE GROUP HOLDINGS, LLC
To: BARCLAYS BANK PLC
Reel/Frame 050897/0314 →
ABL SECURITY AGREEMENT Recorded Oct 31, 2019
From: C&J SPEC-RENT SERVICES, INC.; C&J WELL SERVICES, INC.; KING MERGER SUB II LLC (F/K/A C&J ENERGY SERVICES, INC.); KEANE FRAC, LP; KEANE GROUP HOLDINGS, LLC
To: BANK OF AMERICA, N.A.
Reel/Frame 050897/0470 →