LITHOGRAPHIC PRINTING PLATE PRECURSOR AND COLOR-FORMING COMPOSITION
A color-forming composition is useful to provide a printout image in an imaged lithographic printing plate precursor. This color-forming composition includes (a) an acid generator; (b) a tetraaryl borate; (c) an acid-sensitive dye precursor; and (d) a compound having the following Structure (I): wherein n is 1, 2, 3, or 4; R independently represents a monovalent substituent or the atoms necessary to form a fused ring if n is at least 2, and at least one R substituent is an electron-withdrawing group. The color-forming composition is included within a negative-working radiation-sensitive imageable layer along with a free radically polymerizable component and a radiation absorber such as an infrared radiation absorber.
1 . A color-forming composition comprising:
(a) an acid generator;
(b) a tetraaryl borate;
(c) an acid-sensitive dye precursor; and
(d) a compound having the following Structure (I):
wherein n is 1, 2, 3, or 4; R independently represents a monovalent substituent or the atoms necessary to form a fused ring if n is at least 2, and at least one R substituent is an electron-withdrawing group.
2 . The color-forming composition of claim 1 , wherein the sum of para Hammett-Sigma values for the at least one R substituent is greater than 0.
3 . The color-forming composition of claim 1 , wherein the (a) acid generator is an onium salt.
4 . The color-forming composition of claim 1 , wherein the (a) acid generator and the (b) tetraaryl borate are present in the color-forming composition as one molecule comprising an acid-generating cation and a tetraaryl borate anion.
5 . The color-forming composition of claim 1 , wherein the (a) acid generator is an onium salt having an iodonium cation.
6 . The color-forming composition of claim 1 , wherein the (d) compound of Structure (I) is selected from the group consisting of an alkyl 3,4-dihydroxybenzoate, an alkyl gallate, 4-chlorocatechol, 4-nitrocatechol, and 3,4-dihydroxybenzonitrile.
7 . The color-forming composition of claim 1 , wherein the molar ratio of the (d) compound of Structure (I) to the (b) tetraaryl borate is at least 0.25:1 and to and including 3:1.
8 . A lithographic printing plate precursor comprising:
a substrate comprising a hydrophilic surface;
a radiation-sensitive imageable layer that is disposed on the hydrophilic surface of the substrate, the radiation-sensitive imageable layer comprising:
one or more free radically polymerizable components,
one or more radiation absorbers,
a color-forming composition consisting of:
(a) an acid generator;
(b) a tetraaryl borate;
(c) an acid-sensitive dye precursor; and
(d) a compound having the following Structure (I):
wherein n is 1, 2, 3, or 4; and R independently represents a monovalent substituent or the atoms necessary to form a fused ring if n is at least 2, and at least one R substituent is an electron-withdrawing group, and
optionally, a polymeric material different from the one or more free radically polymerizable components, and
the lithographic printing plate precursor optionally comprising a protective layer disposed over the radiation-sensitive imageable layer.
9 . The lithographic printing plate precursor of claim 8 that is on-press developable using a lithographic printing ink, a fountain solution, or a combination of a lithographic printing ink and a fountain solution.
10 . The lithographic printing plate precursor of claim 8 , wherein the radiation-sensitive imageable layer comprises two or more free radically polymerizable components.
11 . The lithographic printing plate precursor of claim 8 , wherein the radiation-sensitive imageable layer comprises one or more polymeric binders, at least one of which polymeric binders is present as particles having an average particle size of at least 50 nm and up to and including 400 nm.
12 . The lithographic printing plate precursor of claim 8 , wherein the radiation-sensitive imageable layer is an infrared radiation-sensitive imageable layer, and the one or more radiation absorbers are one or more infrared radiation absorbers.
13 . The lithographic printing plate precursor of claim 8 , wherein the sum of para Hammett-Sigma values for the at least one R substituent is greater than 0.
14 . The lithographic printing plate precursor of claim 8 , wherein the (a) acid generator is an onium salt.
15 . The lithographic printing plate precursor of claim 8 , wherein the (a) acid generator and the (b) tetraaryl borate are present in the color-forming composition as one molecule comprising an acid-generating cation and a tetraaryl borate anion.
16 . The lithographic printing plate precursor of claim 8 , wherein the (a) acid generator comprises an iodonium cation.
17 . The lithographic printing plate precursor of claim 8 , wherein the (d) compound of Structure (I) is selected from the group consisting of an alkyl 3,4-dihydroxybenzoate, an alkyl gallate, 4-chlorocatechol, 4-nitrocatechol, and 3,4-dihydroxybenzonitrile.
18 . The lithographic printing plate precursor of claim 8 , wherein the molar ratio of the (b) tetraaryl borate to the (d) compound of Structure (I) is at least 0.25:1 and to and including 3:1
19 . A method for forming a lithographic printing plate, comprising:
A) imagewise exposing a lithographic printing plate precursor according to claim 8 with radiation, to provide exposed regions and non-exposed regions in the radiation-sensitive imageable layer; and
B) removing the non-exposed regions of the radiation-sensitive imageable layer.
20 . The method of claim 19 , comprising
B) removing the non-exposed regions of the radiation-sensitive imageable layer on-press using a lithographic printing ink, a fountain solution, or a combination of a lithographic printing ink and a fountain solution.
21 . The method of claim 19 , wherein the radiation-sensitive imageable layer comprises an infrared radiation absorber, and the imagewise exposing is carried out using infrared radiation.
22 . The method of claim 19 , wherein the radiation-sensitive imageable layer comprises one or more polymeric binders, at least one of which polymeric binders is present as particles having an average particle size of at least 50 nm and up to and including 400 nm.