IP Library Granted Patent US 10,947,474
Granted Patent B2
US 10,947,474 · App. 16/767,691 · Granted Mar 16, 2021

Friction modifier for motor oil

Inventors: Shibaji Kumar Ghosh (Kolkata, IN); Jesse Dambacher (Lexington, KY)
Assignee: VALVOLINE LICENSING AND INTELLECTUAL PROPERTY LLC
C10M133/16C07C233/91C10M2215/082C10N2030/02C10N2030/04C10N2030/06C10N2030/10C10N2030/12C10N2030/18C10N2030/36C10N2040/255
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Quick Facts
Patent No.
US 10,947,474
App. No.
16/767,691
Granted
Mar 16, 2021
Kind
B2
Abstract

Novel friction reducing additives provide friction modification at a lower effective concentration when added to a motor oil base. A friction reducing motor oil composition may include motor oil base and a friction reducing additive having the structure of the general formula (I): wherein: R 1 is a straight or branched C 5 -C 30 alkyl or alkenyl; R 2 is H, or a straight or branched alkyl of C 1 -C 10 ; R 3 is H, or a straight or branched alkyl of C 1 -C 10 ; P is 0 or C 1 ; n is C 1 -C 5 ; and m is C 0 -C 5 .

Claims (24)

1. A friction reducing motor oil additive, wherein the additive has the structure of the general formula (I):

wherein, R 1 is straight or branched C 5 -C 30 alkyl, or alkenyl; R 2 is H, or a straight or branched alkyl of C 1 -C 10 ; R 3 is H, or a straight or branched alkyl of C 1 -C 10 ; P is 0 or C 1 ; n is C 1 -C 5 ; and m is C 0 -C 5 and wherein the additive is present in an amount between about 0.001 wt % and about 5 wt %.

2. The friction reducing motor oil additive of claim 1 , wherein R 1 is straight chain C 16 -C 18 alkyl.

3. The friction reducing motor oil additive of claim 1 , wherein: R 1 is a C 16 straight alkenyl; R 2 is H; R 3 is C 1 ; P is C 1 ; n is C 1 ; and m is 0.

4. The friction reducing motor oil additive of claim 3 , wherein R 1 is unsaturated between C 9 and C 10 .

5. The friction reducing motor oil additive of claim 1 , wherein: R 1 is C 16 straight alkenyl; R 2 is C 4 ; R 3 is H; P is C 1 ; n is C 1 ; and m is C 1 .

6. The friction reducing motor oil additive of claim 5 , wherein R 1 is unsaturated between C 9 and C 10 .

7. The friction reducing motor oil additive of claim 1 , wherein the additive has the structure of the formula (II):

8. The friction reducing motor oil additive of claim 1 , wherein the additive has the structure of the formula (III):

9. The friction reducing motor oil additive of claim 1 , wherein the additive is a combination of additives having the general Formula I, II or III.

10. A friction reducing motor oil composition comprising:

a) motor oil base; and

b) a friction reducing additive having the structure of the general formula (I):

wherein: R 1 is a straight or branched C 5 -C 30 alkyl or alkenyl; R 2 is H, or a straight or branched alkyl of C 1 -C 10 ; R 3 is H, or a straight or branched alkyl of C 1 -C 10 ; P is 0 or C 1 ; n is C 1 -C 5 ; and m is C 0 -C 5 .

11. The friction reducing motor oil composition of claim 10 , wherein R 1 is straight chain C 16 -C 18 alkyl.

12. The friction reducing motor oil composition of claim 10 , wherein: R 1 is a C 16 straight alkenyl; R 2 is H; R 3 is C 1 ; P is C 1 ; n is C 1 ; and m is 0.

13. The friction reducing motor oil composition of claim 12 , wherein R 1 is unsaturated between C 9 and C 10 .

14. The friction reducing motor oil composition of claim 10 , wherein: R 1 is C 16 straight alkenyl; R 2 is C 4 ; R 3 is H; P is C 1 ; n is C 1 ; and m is C 1 .

15. The friction reducing motor oil composition of claim 14 , wherein R 1 is unsaturated between C 9 and C 10 .

16. The friction reducing motor oil composition of claim 10 , wherein the friction reducing additive has the structure of the formula (II):

17. The friction reducing motor oil composition of claim 10 , wherein the friction reducing additive has the structure of the formula (III):

18. The friction reducing motor oil composition of claim 10 , wherein the friction reducing additive is a combination of additives having the general Formula I, II or III.

19. The friction reducing motor oil composition of claim 10 , wherein the composition further comprises one or more additional additives selected from the group consisting of: dispersants, detergents, antioxidants, anti-wear agents, viscosity modifiers, pour point depressants, other friction modifiers, corrosion inhibitors, anti-foamants, demulsifiers, and seal swell agents.

20. The friction reducing motor oil composition of claim 10 , wherein the motor oil base is present in an amount from about 50% to about 99.9 wt % and the friction reducing additive is present in an amount from about 0.001 wt % to about 5.0 wt % of the total composition of the friction reducing motor oil.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 21, 2023
From: VALVOLINE LICENSING AND INTELLECTUAL PROPERTY LLC
To: VGP IPCO LLC
Reel/Frame 063411/0655 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 28, 2023
From: VALVOLINE LICENSING AND INTELLECTUAL PROPERTY LLC
To: VGP IPCO LLC
Reel/Frame 063174/0450 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 28, 2020
From: GHOSH, SHIBAJI KUMAR; DAMBACHER, JESSE
To: VALVOLINE LICENSING AND INTELLECTUAL PROPERTY LLC
Reel/Frame 052777/0389 →
Continuity (2)
Provisional Application 62592645 · Nov 30, 2017
Related Publication 20200385647A1 · Dec 10, 2020