IP Library Granted Patent US 11,279,842
Granted Patent B2
US 11,279,842 · App. 16/882,825 · Granted Mar 22, 2022

Aqueous fluid sets for inkjet printing methods

Inventors: Wayne Lee Cook (Xenia, OH); Allan Francis Sowinski (Rochester, NY)
Assignee: EASTMAN KODAK COMPANY
C09D11/54C09D11/033C09D11/102C09D11/107C09D11/38
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Quick Facts
Patent No.
US 11,279,842
App. No.
16/882,825
Granted
Mar 22, 2022
Kind
B2
Abstract

Aqueous particle-free fluids can be used in inkjet printing methods including continuous inkjet printing processes. Each of these fluids has a dynamic viscosity of less than or equal to 5 centipoise (5 mPa-sec) at 25° C., and each consists essentially of: a composition consisting of one or more compounds represented by the following Structure (I): HO—CH 2 —CH 2 —R   (I) wherein R is a substituted or unsubstituted phenyl group or a substituted or unsubstituted phenoxy group, in a total amount of at least 0.5 weight % and up to and including 2 weight %, based on the total weight of the aqueous inkjet ink composition. Such aqueous particle-free fluids can be used as replenishment or printhead maintenance fluids. Two or more of such aqueous particle-free fluids can be packaged, sold, and use as part of fluid sets.

Claims (19)

1. A fluid set comprising two or more aqueous particle-free fluids, each of which two or more aqueous particle-free fluids independently has a dynamic viscosity of less than or equal to 5 centipoise (5 mPa-sec) at 25° C., and each of which two or more aqueous particle-free fluids independently consists essentially of:

(b) a composition consisting of one or more compounds represented by the following structure (1):

HO—CH 2 —CH 2 —R   (I)

wherein R is a substituted or unsubstituted phenyl group or a substituted or unsubstituted phenoxy group, in a total amount of at least 0.5 weight % and up to and including 2 weight %, based on the total weight of each of the two or more aqueous [inkjet ink composition] particle-free fluids.

2. The fluid set of claim 1 , wherein each of the two or more aqueous particle-free fluids further contains one or more promoters for the one or more structure (I) compounds of the (b) composition, each of which promoters is an alkane diol having a least 7 carbon atoms and up to and including 12 carbon atoms, in an amount of less than or equal to 1.5 weight %, based on the total weight of each of the two or more aqueous [inkjet ink composition] particle-free fluids.

3. The fluid set of claim 2 wherein the one or more promoters comprises 1,2-octanediol.

4. The fluid set of claim 1 , wherein R is either an unsubstituted phenyl group or an unsubstituted phenoxy group.

5. The fluid set of claim 1 , wherein at least one of the two or more aqueous particle-free fluids further comprises at least one water-soluble or water-dispersible polymeric component in an amount of up to and including 20 weight %, based on the total weight of the at least one aqueous particle-free fluid, which at least one water-soluble or water-dispersible polymeric component is an acrylic polymer, a styrene-acrylic polymer, water-soluble polymer having poly(ethylene oxide) segments, water-dispersible polyurethane, or two or more of such materials.

6. The fluid set of claim 1 , wherein at least one of the two or more aqueous particle-free fluids has a pH of at least 8 and up to and including 11.

7. The fluid set of claim 1 , wherein at least one of the two or more aqueous particle-free fluids comprises an anionic, nonionic, cationic, or amphoteric surfactant in an amount of least 0.01 weight % and up to and including 5 weight %, based on the total weight of the at least one aqueous particle-free fluid.

8. The fluid set of claim 1 , wherein at least one of the two or more aqueous particle-free fluids comprises a (d) supplemental antimicrobial agent that is different from the (b) composition.

9. The fluid set of claim 8 , wherein the (d) supplemental antimicrobial agent is iodopropynyl butyl carbamate, piroctone olamine, 2,4-dichlorobenzyl alcohol, boric acid or a metal ion salt derived from boric acid, or a combination of these compounds.

10. The fluid set of claim 1 , wherein at least one of the two or more of the aqueous particle-free fluids further comprises a solvo-surfactant in an amount of at least 0.1 weight % and up to and including 20 weight %, based on the total weight of the at least one aqueous particle-free fluid.

11. The fluid set of claim 10 , wherein the solvo-surfactant is an asymmetric polyhydric alcohol or mono-alkyl ether derived from a polyhydric alcohol.

12. The fluid set of claim 10 , wherein the solvo-surfactant is a C 1 to C 4 mono-alkyl ethyl derived from a polyhydric alcohol.

13. The fluid set of claim 10 , wherein the solvo-surfactant is present in an amount of at least 3 weight % and up to and including 6 weight %, based on the total weight of the at least one aqueous particle-free fluid.

14. The fluid set of claim 10 , wherein the at least one of the two or more aqueous particle-free fluids further comprises a surfactant different from the solvo-surfactant, which surfactant is present in an amount of at least 0.01 weight % and up to 10 weight %, based on the total weight of the at least one aqueous particle-free fluid.

15. The fluid set of claim 1 , wherein at least one of the two or more aqueous particle-free fluids has a pH of at least 10 and up to and including 11, and further comprises an organic base.

16. The fluid set of claim 15 , wherein the organic base is an alkanolamine.

Assignments (6)
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: ALTER DOMUS (US) LLC
Reel/Frame 056733/0681 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: ALTER DOMUS (US) LLC
Reel/Frame 056734/0001 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: ALTER DOMUS (US) LLC
Reel/Frame 056734/0233 →
NOTICE OF SECURITY INTERESTS Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: BANK OF AMERICA, N.A., AS AGENT
Reel/Frame 056984/0001 →
SECURITY INTEREST Recorded Aug 25, 2020
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST) INC.; KODAK AMERICAS LTD.; LASER-PACIFIC MEDIA CORPORATION; KODAK PHILIPPINES LTD.; NPEC, INC.
To: BANK OF AMERICA, AS AGENT
Reel/Frame 053596/0518 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 28, 2020
From: COOK, WAYNE LEE; SOWINSKI, ALLAN FRANCIS
To: EASTMAN KODAK COMPANY
Reel/Frame 053324/0442 →
Continuity (2)
Division 16171446 · Oct 26, 2018
Related Publication 20200283654A1 · Sep 10, 2020