Compositions comprising eutectic metal alloy nanoparticles
Provided herein is a composition for eutectic metal alloy nanoparticles having an average particle size ranging from about 0.5 nanometers to less than about 5000 nanometers and at least one organoamine stabilizer. Also provided herein is a process for preparing eutectic metal alloy nanoparticles comprising mixing at least one organic polar solvent, at least one organoamine stabilizer, and a eutectic metal alloy to create a mixture; sonicating the mixture at a temperature above the melting point of the eutectic metal alloy; and collecting a composition comprising a plurality of eutectic metal alloy nanoparticles having an average particle size ranging from about 0.5 nanometers to less than about 5000 nanometers. Further disclosed herein are hybrid conductive ink compositions comprising a component comprising a plurality of metal nanoparticles and a component comprising a plurality of eutectic metal alloy nanoparticles.
1. A process for preparing eutectic metal alloy nanoparticles comprising:
mixing at least one organic polar solvent, at least one organoamine stabilizer, and a eutectic metal alloy to create a mixture;
sonicating the mixture at a temperature above the melting point of the eutectic metal alloy; and
collecting from the mixture a composition comprising a plurality of eutectic metal alloy nanoparticles having an average particle size ranging from about 0.5 nanometers to less than about 5000 nanometers.
2. The process of claim 1 , wherein the eutectic metal alloy nanoparticles comprise Field's metal alloy.
3. The process of claim 1 , wherein the at least one organic polar solvent is heated to a temperature ranging from about 30° C. to about 200° C.
4. The process of claim 1 , wherein the at least one organic polar solvent is chosen from the group consisting of propylene glycol methyl ether acetate, di(propylene glycol) methyl ether acetate, (propylene glycol) methyl ether, di(propylene glycol) methyl ether, methyl isobutyl ketone, and diisobutyl ketone.
5. The process of claim 1 , wherein the at least one organic polar solvent is propylene glycol methyl ether acetate.
6. The process of claim 1 , wherein the at least one organoamine stabilizer is chosen from the group consisting of propylamine, butylamine, pentylamine, hexylamine, heptylamine, octylamine, 3-methoxypropylamine, pentaethylenehexamine, 2,2-(ethylenedioxy)diethylamine, tetraethylenepentamine, triethylenetetramine, diethylenetriamine, 1,11-Diamino-3,6, 9-trioxaundecane, 2,2′(Ethylenedioxy)bis(ethylamine), and 2-(2-aminoethoxy)ethylamine.
7. The process of claim 1 , wherein the mixture is sonicated for a period of time ranging from about 1 minute to about 1 hour at about 100% power.
8. The process of claim 1 , wherein the eutectic metal alloy nanoparticles have an average particle size ranging from about 50 nanometers to about 800 nanometers.