IP Library Granted Patent US 12,000,015
Granted Patent B2
US 12,000,015 · App. 17/216,789 · Granted Jun 4, 2024

Method of improving gold recovery in a cyanide leaching circuit

Inventor: Kirill N. Bakeev (Newark, DE)
Assignee: Solenis Technologies, L.P.
C22B3/06C22B11/04
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Quick Facts
Patent No.
US 12,000,015
App. No.
17/216,789
Granted
Jun 4, 2024
Kind
B2
Abstract

This disclosure provides a method of improving gold recovery in a cyanide leaching circuit comprising a gold ore slurry. The method includes the step of providing a gold recovery additive chosen from polyacrylic acid, copolymers of acrylic acid and a sulfonated co-monomer, and combinations thereof, wherein the additive has a weight average molecular weight of from about 500 to about 10,000 g/mol. The method also includes the step of combining the gold recovery additive with the gold ore slurry in the cyanide leaching circuit, wherein the gold recovery additive is present in an amount of from about 10 to about 1000 g per ton of dry gold ore to improve the recovery of gold from the gold ore slurry.

Claims (22)

1. A method of improving gold recovery in a cyanide leaching circuit comprising a gold ore slurry, said method comprising the steps of:

providing a gold recovery additive that is polyacrylic acid, wherein the additive has a weight average molecular weight of from about 500 to about 10,000 g/mol;

combining the gold recovery additive with the gold ore slurry in the cyanide leaching circuit, wherein the gold recovery additive is present in an amount of from about 10 to about 1000 g per ton of dry gold ore to improve the recovery of gold from the gold ore slurry.

2. The method of claim 1 wherein the polyacrylic acid has a weight average molecular weight of about 1,000 to about 6,000 g/mol.

3. The method of claim 1 wherein the polyacrylic acid has a weight average molecular weight of about 2,000 to about 4,000 g/mol.

4. The method of claim 1 wherein the gold ore slurry has a grind density of from about 50 to about 80 percent of solids based on a total weight of the slurry.

5. The method of claim 4 wherein the gold ore slurry has a leach density of from about 25 to about 50 percent of solids based on a total weight of the slurry.

6. The method of claim 5 wherein the gold recovery additive is present in an amount of from about 100 to about 700 g per ton of dry gold ore.

7. The method of claim 1 wherein the gold ore slurry has a grind density of from about 50 to about 80 percent of solids based on a total weight of the slurry.

8. The method of claim 7 wherein the gold ore slurry has a leach density of from about 25 to about 50 percent of solids based on a total weight of the slurry.

9. The method of claim 1 wherein the gold ore slurry has a leach density of from about 25 to about 50 percent of solids based on a total weight of the slurry.

10. The method of claim 1 wherein the gold recovery additive is present in an amount of from about 100 to about 700 g per ton of dry gold ore.

11. The method of claim 1 wherein the gold recovery additive is present in an amount of from about 60 to about 650 g per ton of dry gold ore.

12. The method of claim 1 wherein the step of combining occurs in a leaching tank of a carbon-in-leach or carbon-in-pulp process.

13. The method of claim 1 wherein the step of combining occurs during a step of slurry pumping in the cyanide leaching circuit of a carbon-in-leach or carbon-in-pulp process.

14. The method of claim 1 wherein the gold recovery additive and the gold ore slurry are free of an oil.

15. The method of claim 1 wherein the gold recovery additive and the gold ore slurry are free of a cationic surfactant.

16. The method of claim 1 wherein the step of combining occurs in a leaching tank of a carbon-in-leach or carbon-in-pulp process, wherein the gold ore slurry has a leach density of from about 25 to about 50 percent based on a total weight of the slurry, wherein the gold slurry has a grind density of about 60 percent based on a total weight of the slurry, and wherein the gold recovery additive and the gold ore slurry are free of an oil and a cationic surfactant.

17. The method of claim 1 wherein the step of combining occurs in a leaching tank of a carbon-in-leach or carbon-in-pulp process, wherein the gold ore slurry has a leach density of from about 25 to about 50 percent based on a total weight of the slurry, wherein the gold slurry has a grind density of about 60 percent based on a total weight of the slurry, wherein the polyacrylic acid has a weight average molecular weight of about 2,000 to about 4,000 g/mol, and wherein the gold recovery additive and the gold ore slurry are free of an oil and a cationic surfactant.

18. The method of claim 1 wherein the step of combining occurs in a leaching tank of a carbon-in-leach or carbon-in-pulp process, wherein the gold ore slurry has a leach density of from about 25 to about 50 percent based on a total weight of the slurry, wherein the gold slurry has a grind density of about 60 percent based on a total weight of the slurry, wherein the polyacrylic acid has a weight average molecular weight of about 2,000 to about 4,000 g/mol, wherein the gold recovery additive is present in an amount of from about 600 to about 650 g per ton of dry ore, and wherein the gold recovery additive and the gold ore slurry are free of an oil and a cationic surfactant.

19. The method of claim 18 wherein the slurry has a pH of from about 10 to about 12, a cyanide concentration of not less than about 0.015 wt. %, and a slurry concentration of from about 40 to about 45 wt % solids dry ore and wherein the slurry further comprises activated carbon having a particle size of from about 1.0 to about 3.35 mm and coconut shell activated carbon.

20. The method of claim 1 wherein the slurry has a pH of from about 10 to about 12, a cyanide concentration of not less than about 0.015 wt. %, and a slurry concentration of from about 40 to about 45 wt % solids dry ore and wherein the slurry further comprises activated carbon having a particle size of from about 1.0 to about 3.35 mm and coconut shell activated carbon.

Assignments (10)
SECURITY INTEREST Recorded Nov 14, 2025
From: CHEM-AQUA, INC.; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; NCH CORPORATION; NCH LIFE SCIENCES LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 073570/0838 →
RELEASE OF SECURITY INTEREST Recorded Nov 14, 2025
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
To: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 073564/0864 →
RELEASE OF 2023 NOTES PATENT SECURITY INTERESTS Recorded Oct 10, 2025
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
To: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 073074/0198 →
SECURITY AGREEMENT (NOTES) Recorded Oct 10, 2025
From: DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 073061/0885 →
SECURITY AGREEMENT (2024 NOTES) Recorded Jun 24, 2024
From: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 067824/0278 →
2023 NOTES PATENT SECURITY AGREEMENT Recorded Jul 7, 2023
From: BIRKO CORPORATION; SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE GLOBAL CORPORATION
To: BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
Reel/Frame 064225/0170 →
SECURITY AGREEMENT (ABL) Recorded Sep 14, 2022
From: SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC
To: BANK OF AMERICA, N.A, AS COLLATERAL AGENT
Reel/Frame 061432/0958 →
SECURITY AGREEMENT (NOTES) Recorded Sep 14, 2022
From: SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A. AS COLLATERAL AGENT
Reel/Frame 061432/0821 →
SECURITY AGREEMENT (TERM) Recorded Sep 13, 2022
From: SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC
To: GOLDMAN SACHS BANK USA, AS COLLATERAL AGENT
Reel/Frame 061431/0851 →
SECURITY AGREEMENT (NOTES) Recorded Sep 13, 2022
From: SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A. AS COLLATERAL AGENT
Reel/Frame 061431/0865 →
Continuity (2)
Provisional Application 63001615 · Mar 30, 2020
Related Publication 20210301371A1 · Sep 30, 2021