IP Library Granted Patent US 12,187,635
Granted Patent B2
US 12,187,635 · App. 17/398,225 · Granted Jan 7, 2025

Mineral fiber compositions having enhanced biopersistent properties and methods for making and using the same

Inventors: Marsha S. Bischel (Lancaster, PA); Peter J. Oleske (Lancaster, PA)
Assignee: AWI LICENSING LLC
C03C13/06C03C3/062C03C3/087E04B9/04
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Quick Facts
Patent No.
US 12,187,635
App. No.
17/398,225
Granted
Jan 7, 2025
Kind
B2
Abstract

Described herein are mineral fiber compositions having enhanced characteristics, such as biopersistence and resistance to heat induced shrinkage. Also described are methods for making and using the same. Such compositions may comprise manganese oxide and aluminum oxide.

Claims (48)

1. A composition comprising:

mineral fibers comprising:

silicon dioxide;

manganese oxide in an amount ranging from about 7.5 wt. % to about 9.5 wt. % based on the total weight of the mineral fibers;

aluminum oxide in an amount ranging from 17 wt. % to 21 wt. % based on the total weight of the mineral fibers;

iron oxide in an amount ranging from about 0.2 wt. % to 2.0 wt. %, based on the total weight of the mineral fibers;

CaO;

MgO;

K 2 O; and

Na 2 O;

wherein the sum of (aluminum oxide+CaO+MgO+K 2 O+Na 2 O) within the mineral fibers is at least 50 wt. % based on the total weight of the mineral fibers; and

wherein a ratio of (silicon dioxide+aluminum oxide)/manganese oxide within the mineral fibers is between 7 to 8.

2. The composition according to claim 1 , wherein the aluminum oxide is present in an amount ranging from 18 wt. % to 20 wt. %, based on the total weight of the mineral fibers.

3. The composition according to claim 1 , wherein the mineral fibers comprises silicon dioxide present in an amount ranging from about 35.0 wt. % to about 45.0 wt. %, based on the total weight of the mineral fibers.

4. The composition according to claim 1 , wherein the mineral fibers comprises MgO present in an amount ranging from about 8 wt. % to about 9 wt. %, based on the total weight of the mineral fibers.

5. The composition according to claim 1 , wherein the mineral fibers comprises K 2 O present in an amount ranging from about 1.0 wt. % to about 2.0 wt. %, based on the total weight of the mineral fibers.

6. The composition according to claim 1 , wherein the mineral fibers comprises about 40 wt. % of silicon dioxide and about 18.9 wt. % of aluminum oxide.

7. The composition according to claim 6 , wherein the mineral fibers further comprises about 8.65 wt. % of MgO.

8. The composition according to claim 1 , wherein a ratio of (silicon dioxide+aluminum oxide)/(manganese oxide+iron oxide) within the mineral fibers is between 6 to 8.

9. The composition according to claim 1 , a ratio of (silicon dioxide+manganese oxide)/(aluminum oxide+CaO+MgO+K 2 O+Na 2 O) within the mineral fibers is less than 1.

10. The composition according to claim 1 , wherein the mineral fibers comprise fibers having a diameter of less than 3 microns and are more than 20 microns in length.

11. A composition comprising:

mineral fibers comprising:

silicon dioxide in an amount of about 40.0 wt. % of based on the total weight of the mineral fibers;

aluminum oxide in an amount ranging from about 18.0 wt. % to about 20.0 wt. % of based on the total weight of the mineral fibers;

manganese oxide in an amount ranging from about 8.0 wt. % to about 9.0 wt. % based on the total weight of the mineral fibers;

iron oxide in an amount between 0.2 wt. % to 1.0 wt. %, based on the total weight of the mineral fiber;

CaO;

MgO;

K 2 O; and

Na 2 O.

12. The composition according to claim 11 , wherein a ratio of (silicon dioxide+manganese oxide)/(aluminum oxide+CaO+MgO+K 2 O+Na 2 O) within the mineral fibers is less than 1.

13. A composition comprising:

mineral fibers comprising;

silicon dioxide in an amount ranging from about 35 wt. % to about 45 wt. % based on the total weight of the mineral fibers;

aluminum oxide in an amount of about 18.9 wt. % based on the total weight of the mineral fibers;

manganese oxide;

iron oxide;

CaO;

MgO;

K 2 O; and

Na 2 O;

wherein a combined amount of (silicon dioxide+aluminum oxide)/manganese oxide ranges from about 7.1 to about 7.9.

14. The composition according to claim 13 , wherein the MgO is present in an amount ranging from about 8 wt. % to about 9 wt. %, based on the total weight of the mineral fibers.

15. The composition according to claim 13 , wherein the CaO is present in an amount ranging from about 18 wt. % to about 22 wt. %, based on the total weight of the mineral fibers.

16. The composition according to claim 13 , wherein the K 2 O is present in an amount ranging from about 1.0 wt. % to about 2.0 wt. %, based on the total weight of the mineral fibers.

17. The composition according to claim 13 , wherein the iron oxide is present in an amount between 0.2 wt. % to 1.0 wt. %, based on the total weight of the mineral fibers.

18. The composition according to claim 13 , wherein the mineral fibers comprise fibers having a diameter of less than 3 microns and are more than 20 microns in length.

Assignments (5)
SECURITY INTEREST Recorded Dec 11, 2025
From: AWI LICENSING LLC
To: BANK OF AMERICA, N.A., AS THE COLLATERAL AGENT
Reel/Frame 073939/0866 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 15, 2025
From: ARMSTRONG WORLD INDUSTRIES, INC.
To: AWI LICENSING LLC
Reel/Frame 071131/0030 →
CORRECTIVE NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS TO REMOVE APPL. NO. 17894024 PREVIOUSLY RECORDED ON REEL 062081 FRAME 0523. ASSIGNOR HEREBY CONFIRMS THE SECURITY INTEREST. Recorded Jul 31, 2023
From: ARMSTRONG WORLD INDUSTRIES, INC.
To: BANK OF AMERICA, N.A., AS THE COLLATERAL AGENT
Reel/Frame 064655/0563 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Dec 7, 2022
From: ARMSTRONG WORLD INDUSTRIES, INC.
To: BANK OF AMERICA, N.A., AS THE COLLATERAL AGENT
Reel/Frame 062081/0523 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 10, 2021
From: BISCHEL, MARSHA S.; OLESKE, PETER J.
To: ARMSTRONG WORLD INDUSTRIES, INC.
Reel/Frame 057132/0554 →
Continuity (2)
Provisional Application 63063512 · Aug 10, 2020
Related Publication 20220041494A1 · Feb 10, 2022
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