Lubricant composition and use thereof
A lubricant composition comprising an oil-soluble polyalkylene glycol; an ester compound selected from the group of natural esters and synthetic esters, and combinations thereof; and an additive mixture comprising an antioxidant and an anticorrosive, wherein the anticorrosive is selected from neutral alkali metal and alkaline earth metal salts of sulfonic acids, carboxylic acids, naphthoic acids, naphthenic acids, benzoic acids and phosphoric acids, and derivatives and combinations thereof.
1 . A lubricant composition comprising
an oil-soluble polyalkylene glycol, as a base oil component;
an ester compound selected from the group of natural esters and synthetic esters, and combinations thereof, as another base oil component; and
an additive mixture comprising an antioxidant and an anticorrosive,
wherein the anticorrosive is selected from neutral alkali metal and alkaline earth metal salts of sulfonic acids and derivatives and combinations thereof, wherein the neutral alkali metal and alkaline earth metal salts are Na, Ca, K and Mg salts,
wherein the anticorrosive has a total acid number (TAN) of 30 mg KOH/g or less,
wherein the oil-soluble polyalkylene glycol has a molecular weight M n of 500 g/mol or more to 1400 g/mol or less,
wherein the oil-soluble polyalkylene glycol and the ester compound are the only base oil components comprised in the lubricant composition,
wherein the weight ratio of oil-soluble polyalkylene glycol to the ester compound based on the total weight of those two base oil components in the lubricant composition is in the range from 15:85 to 70:30,
wherein the lubricant composition does not comprise an overbased alkali metal or alkaline earth metal salt,
wherein the oil-soluble polyalkylene glycol is a copolymer selected from polybutylene oxide-polypropylene oxide copolymers, polybutylene oxide-polyethylene oxide copolymers and polybutylene oxide-polypropylene oxide-polyethylene oxide copolymers, and combinations thereof,
wherein the amount of oil-soluble polyalkylene glycol is 5-70% by weight,
wherein the amount of the antioxidant is in the range of 0.05-3.5% by weight, and
wherein the amount of the anticorrosive is in the range of 0.05-3.5% by weight.
2 . The lubricant composition as claimed in claim 1 , wherein the antioxidant is selected from phenolic antioxidants, aminic antioxidants, phosphites and sulfur-containing compounds, and combinations thereof.
3 . The lubricant composition as claimed in claim 1 , wherein the antioxidant is selected from phenolic antioxidants, aminic antioxidants, thiocarbamates and dithiocarbamates, and combinations thereof.
4 . The lubricant composition as claimed in claim 1 , wherein the antioxidant is selected from aminic antioxidants.
5 . The lubricant composition as claimed in claim 1 , wherein the additive mixture further comprises a nonferrous metal deactivator selected from triazoles, mercaptothiadiazoles and salicylates, and combinations thereof.
6 . The lubricant composition as claimed in claim 5 , wherein the nonferrous metal deactivator is selected from triazoles.
7 . The lubricant composition as claimed in claim 1 , wherein the ester compound is selected from natural glyceride esters, optionally from the group of sunflower oil, rapeseed oil or colza oil, linseed oil, corn oil, safflower oil, soybean oil, linseed oil, peanut oil, “ lesquerella ” oil, palm oil, olive oil, in monomeric, oligomeric and/or polymerized form; and synthetic esters from the group of polyol esters, polyol complex esters, complex esters of dimer acids, dimer acid esters, aliphatic carboxylic acid and dicarboxylic esters, phosphate esters and trimellitic and pyromellitic esters and estolides; and combinations thereof.
8 . The lubricant composition as claimed in claim 1 , wherein the ester compound is selected from polyol esters and polyol complex esters, and combinations thereof.
9 . The lubricant composition as claimed in claim 1 , wherein the ester compound is selected from neopentyl glycol esters, trimethylolpropane esters and pentaerythritol esters that have been esterified with saturated and/or mono- or polyunsaturated, linear and/or branched monocarboxylic acids of chain length C4-C36; and neopentyl glycol complex esters, trimethylolpropane complex esters and pentaerythritol complex esters that have been fully esterified with saturated and/or mono- or polyunsaturated, linear and/or branched monocarboxylic acids of chain length C4-C36 and with saturated and/or mono- or polyunsaturated, linear and/or branched dicarboxylic acids of chain length C4-C36 in any mixture; and combinations thereof.
10 . The lubricant composition as claimed in claim 9 , wherein the neopentyl glycol esters, trimethylolpropane esters and pentaerythritol esters have each been esterified with saturated and/or mono- or polyunsaturated, linear and/or branched monocarboxylic acids of chain length C18-C36; and the neopentyl glycol complex esters, trimethylolpropane complex esters and pentaerythritol esters have each been fully esterified or partly esterified with saturated and/or mono- or polyunsaturated, linear and/or branched monocarboxylic acids of chain length C18-C36 and with saturated and/or mono- or polyunsaturated, linear and/or branched dicarboxylic acids of chain length C4-C36 in any mixture.
11 . The lubricant composition as claimed in claim 1 , wherein the oil-soluble polyalkylene glycol is a copolymer selected from polyisobutylene oxide-polyisopropylene oxide copolymers, polyisobutylene oxide-polyethylene oxide copolymers and polyisobutylene oxide-polyisopropylene oxide-polyethylene oxide copolymers, and combinations thereof.
12 . The lubricant composition as claimed in claim 1 , wherein the oil-soluble polyalkylene glycol is an alcohol-initiated copolymer, optionally wherein the alcohol-initiated copolymer is a copolymer having a C10-C20-alkyl radical bonded to at least one terminal end thereof.
13 . The lubricant composition as claimed in claim 1 , wherein the ester compound is present in an amount of 0.1-85% by weight, based on the overall lubricant composition.
14 . The lubricant composition as claimed in claim 1 , wherein the additive mixture is present in an amount of 0.1-20% by weight, based on the overall lubricant composition.
15 . The lubricant composition as claimed in claim 1 , wherein the additive mixture further comprises one or more additives selected from antiwear agents, friction modifiers, high-pressure additives, ion complex formers, solid lubricants, dispersants, pour point and viscosity improvers, UV stabilizers, emulsifiers, color indicators, lubricity improvers and defoamers.
16 . A system comprising the lubricant composition as claimed in claim 1 , wherein the system is selected from a gear, hydraulics, a propeller rudder, a propeller shaft, a linear guide, a pneumatic component, an instrument, a bearing, a chain, a cable, a spring, a valve, and a machine component, optionally wherein the system is configured to come into contact with water and/or aqueous media in a marine sector, in inland waterways, or on land.
17 . The lubricant composition as claimed in claim 1 , wherein the anticorrosive has a total acid number (TAN) of 10 mg KOH/g or less.
18 . The lubricant composition as claimed in claim 1 , wherein the neutral alkali metal and alkaline earth metal salts are Ca salts.