Multi-layer golf ball with thermo-reversible covalent adaptable network
Compositions including a base polymer and diene functional groups and/or dienophile functional groups attached to and crosslinking the base polymer, and golf balls made from such compositions are disclosed. The type and concentration of the components in the compositions, including the base polymer, the diene functional groups, and the dienophile functional groups, affect the hardness and resiliency of golf ball components made from such compositions, and thus, can be used to produce a golf ball having desirable performance characteristics. The compositions of the present disclosure may also be used in adjacent golf ball components to create crosslinks between such components that affect the adhesion between such golf balls components and, thus, can be used to produce a golf ball having increased durability. Golf ball components made from the compositions of the present disclosure may also have increased recyclability.
1 . A golf ball, comprising:
a core;
a casing layer disposed on the core and formed from a composition comprising a base polymer, diene functional groups, and dienophile functional groups, wherein the diene functional groups and dienophile functional groups are linked to the base polymer via ester groups, and wherein the diene and dienophile functional groups are crosslinked; and
a cover disposed on the casing layer.
2 . The golf ball of claim 1 , wherein the composition comprises a covalent adaptable network.
3 . The golf ball of claim 2 , wherein the composition comprises a thermo-reversible covalent adaptable network.
4 . The golf ball of claim 1 , wherein the diene and dienophile functional groups are crosslinked via a Diels-Alder reaction and form dynamic covalent bonds.
5 . The golf ball of claim 1 , wherein the diene functional groups are formed from a dual reactive diene crosslinking agent and the dienophile functional groups are formed from a dual reactive dienophile crosslinking agent.
6 . The golf ball of claim 5 , wherein the base polymer is selected from the group consisting of polyethylene, polyacrylate, and hybrids, copolymers, and blends thereof.
7 . The golf ball of claim 5 , wherein the base polymer comprises an ionomer.
8 . The golf ball of claim 1 , wherein the diene functional groups are formed from a furan derivative.
9 . The golf ball of claim 1 , wherein the dienophile functional groups are formed from a maleimide derivative.
10 . The golf ball of claim 1 , wherein the diene functional groups are selected from the group consisting of furfuryl alcohol, furfuryl alcohol resin, furaldehyde, furoic acid, 5-hydroxymethyl-2-furaldehyde, and mixtures thereof, and wherein the dienophile functional groups are selected from the group consisting of maleimide alcohol, maleimide ether, N-hydroxymaleimide, maleic acid, 3-maleimidopropionic acid, N-[2-(2-bromoisobutyryloxy) ethyl] maleimide (BiBEMI), and mixtures thereof.
11 . A golf ball, comprising:
a core;
a casing layer disposed on the core and formed from a composition comprising a base polymer, diene functional groups, and dienophile functional groups, wherein the diene functional groups and dienophile functional groups are attached to the base polymer via ester groups, and wherein a ratio of the diene functional groups concentration (in mole) to the dienophile functional groups concentration (in mole) may be about 2.5:1 to about 1:2.5; and
a cover disposed on the casing layer,
wherein the base polymer includes the following linkage:
12 . The golf ball of claim 11 , wherein the linkage is a dynamic covalent bond.
13 . The golf ball of claim 11 , wherein the base polymer is selected from the group consisting of polyethylene, polyacrylate, and hybrids, copolymers, and blends thereof.
14 . The golf ball of claim 11 , wherein the diene functional groups are formed from a furan derivative.
15 . The golf ball of claim 11 , wherein the dienophile functional groups are formed from a maleimide derivative.