METHOD OF DEWATERING SLUDGE
Provided is a method of dewatering aqueous sludge that is produced by waste water or sewage treatment facilities, such as from industrial and municipal processes. The method includes treating an aqueous sludge with an associative and branching or cross-linked inverse emulsion cationic polymer, wherein the associative properties of the cationic polymer are provided by an emulsification surfactant(s) chosen from diblock and triblock polymeric surfactants and/or cross-linking agents.
1 . A method of dewatering aqueous sludge comprising:
a. treating the aqueous sludge with an associative and branching or cross-linked polymer composition comprising:
at least one associative and branching or cross-linked cationic polymer, wherein the associative properties of the cationic polymer are provided by an emulsification surfactant chosen from diblock and triblock polymeric surfactants;
wherein the at least one associative and branching or cross-linked cationic polymer comprises one or more polymer segment “A” comprised of ethylenically unsaturated nonionic monomers; and one or more cationic polymer segment “B” comprised of ethylenically unsaturated cationic monomers; and a cross-linking agent;
wherein the molar ratio of the emulsification surfactant to a combination of the one or more ethylenically unsaturated nonionic monomers and the one or more ethylenically unsaturated cationic monomers is from about 3:100 to about 6:100; and
wherein the at least one associative and branching or cross-linked cationic polymer is formed from a polymerization reaction that is initiated by an initiator; and
b. dewatering the treated aqueous sludge obtained from step a).
2 . The method according to claim 1 , wherein the initial temperature of the polymerization reaction is between 55° C. and 65° C. and a pH of from about 2 to less than 7.
3 . The method according to claim 1 , wherein the one or more ethylenically unsaturated nonionic monomers is chosen from acrylamides, methacrylamides, N-dialkylacrylamides, N-alkylacrylamides, and mixtures thereof.
4 . The method according to claim 1 , wherein the one or more ethylenically unsaturated cationic monomers is chosen from acryloyloxy)ethyl)trimethylammonium chloride, 2-acryloxyethyltrimethylammonium chloride, dimethylaminoethyl acrylate, dimethylaminoethyl acrylate methyl chloride quat., 2-((1-oxo-2-propenyl)oxy)-N,N,N-trimethylethanaminium chloride, (2-(dimethylamino)ethyl acrylate methochloride), N,N,N-trimethyl-2-((1-oxo-2-propenyl)oxy)chloride, (2-(acryloyloxy)ethyl)trimethylammonium chloride, (2-((1-oxo-2-propenyl)oxy)-N,N,N-trimethylchloride, N,N,N-trimethyl-2-((1-oxo-2-propenyl)oxy) chloride, (2-acryloyloxyethyl)-N,N,N-trimethylammonium chloride, 2-(acryloyloxy)-N,N,N-trimethylethanaminium chloride and combinations thereof.
5 . The method according to claim 1 , wherein the cross-linking agent is chosen from N,N-methylene bis acrylamide (MBA) or tetraallyl ammonium chloride (TAAC).
6 . The method according to claim 1 , wherein the cross-linking agent is present in an amount of about 0.5 ppm to about 25 ppm by weight of the total weight of the associative and branching or cross-linked polymer composition.
7 . The method according to claim 1 , wherein the diblock and triblock copolymers are chosen from copolymers based polyester derivatives of fatty acids and poly(ethylene oxide); copolymers based on polyisobutylene succinic anhydride and poly(ethylene oxide); reaction products of ethylene oxide and propylene oxide with ethylenediamine; and mixtures thereof.
8 . The method according to claim 1 , wherein the amount of the emulsification surfactant comprises about 1.0 wt. % to about 3.0 wt. % of the total weight of the associative and branching or cross-linked polymer composition.
9 . The method according to claim 1 , wherein the amount of diblock or triblock copolymers to monomer is about 4:100 to 5:100.
10 . The method according to claim 1 , wherein the emulsification surfactant is a triblock emulsifier comprising a polyester derivative of fatty acids and poly[ethyleneoxide].
11 . The method according to claim 1 , wherein the initiator is an organic peroxide initiator.
12 . The method according to claim 11 , wherein the organic peroxide initiator is lauroyl peroxide.
13 . The method according to claim 1 , wherein the one or more ethylenically unsaturated nonionic monomers is acrylamide; the one or more ethylenically unsaturated cationic monomers is acryloyloxyethyltrimethyl ammonium chloride; and the initiator is lauroyl peroxide.
14 . The method claimed in claim 1 , wherein the initiator is in an amount of not more than 250 ppm based on the total weight of the associative and branching or cross-linked polymer composition.
15 . The method according to claim 1 , wherein an initiator is optionally added as a burn-out charge.
16 . A method of increasing cake dryness in sludge dewatering processes comprising:
a) treating the aqueous sludge with an associative and branching or cross-linked polymer composition comprising:
at least one associative and branching or cross-linked inverse emulsion cationic polymer, wherein the associative properties of the cationic polymer are provided by an emulsification surfactant chosen from diblock and triblock polymeric surfactants;
wherein the at least one associative and branching or cross-linked inverse emulsion cationic polymer comprises one or more polymer segment “A” comprised of ethylenically unsaturated nonionic monomers; and one or more cationic polymer segment “B” comprised of ethylenically unsaturated cationic monomers; and a cross-linking agent; and
wherein the molar ratio of the emulsification surfactant to a combination of the one or more ethylenically unsaturated nonionic monomers and the one or more ethylenically unsaturated cationic monomers is from about 3:100 to about 6:100; and
wherein the at least one associative and branching or cross-linked inverse emulsion cationic polymer is formed from a polymerization reaction that is initiated by an initiator; and
dewatering the treated aqueous sludge obtained from step a) producing a filter cake.
17 . The method according to claim 16 , wherein the amount of the emulsification surfactant comprises about 1.0 wt. % to about 3.0 wt. % of the total copolymer composition.
18 . The method claimed in claim 16 , wherein the initiator is in an amount of not more than 250 ppm by weight based on the total weight of the associative and branching or cross-linked inverse emulsion cationic polymer composition.
19 . The method according to claim 16 , wherein an initiator chosen from a persulfate, a bisulfate, or a combination thereof, is optionally added as a burn-out charge.
20 . The method according to claim 16 , wherein the filter cake dryness is increased by at least 10% when compared with filter cakes made using standard polymer compositions.