Membrane separation process for vinylamine-containing polymers
Provided is a method for the removal of salts and by-products from vinylamine-containing polymers. In particular, the method allows the removal of unwanted salts, by-products, spent initiators and short chain vinylamine-containing polymers while retaining the functional, higher molecular weight polymers that provide for desired product performance.
1 . A method of removing salts, by-products, and low molecular weight polymers from a solution of vinylamine-containing polymer comprising;
providing the solution of vinylamine-containing polymer, wherein the polymer comprises salts and by-products formed during vinylamine-containing polymer synthesis and/or modification of a vinylamine-containing polymer solution;
circulating the solution through a nanofiltration membrane and/or an ultrafiltration membrane having a molecular cutoff of from about 500 Dalton to 1,000 Dalton, thereby separating a low molecular weight from a high molecular weight retentate of the vinylamine-containing polymer and at least a portion of the salts and by-products; and
collecting a vinylamine-containing polymer retentate having a weight average molecular weight of from about 10,000 to about 1,000,000 Da. and a reduced amount of salts and by-products as compared to the solution prior to circulating through the nanofiltration membrane and/or an ultrafiltration membrane.
2 . The method according to claim 1 , wherein the salts and by-products are permeable molecules, unwanted reaction salts, small proteins, organic and/or inorganic solvents, residual monomers, monomeric impurities, monomer decomposition byproducts, monomer stabilizers, and byproducts from initiator decomposition, and/or impurities coming from cationizing and/or alkylating agent containing amine or amide functionality.
3 . The method according to claim 2 , wherein the salts and by-products are monomeric impurities.
4 . The method according to claim 1 , wherein the salts and by-products are impurities from reactions involving N-vinylformamide polymerization and copolymerization with other functional monomers, hydrolysis of polyvinylformamide by acid or caustic treatment, and post polymerization modification of vinylamine-containing polymers with functional monomers.
5 . The method of claim 1 , wherein collecting the vinylamine-containing polymer retentate comprises collecting the vinylamine-containing polymer retentate having a higher concentration of vinylamine-containing polymer than the solution prior to circulating through the nanofiltration membrane and/or an ultrafiltration membrane.
6 . The method according to claim 1 , wherein the nanofiltration membrane and/or an ultrafiltration membrane has a molecular weight cut-off of 800 Da.
7 . A method of improving drainage in a papermaking process comprising adding the retentate according to claim 1 , to a papermaking furnish.
8 . A method of preparing a solution of high molecular weight vinylamine-containing polymers comprising,
providing a solution of vinylamine-containing polymer wherein the polymer comprises one or more of a salt or a by-product formed during vinylamine-containing polymer synthesis and/or modification of vinylamine containing polymer comprising a low molecular weight vinylamine polymer component and a high molecular weight vinylamine polymer component;
circulating the solution through a nanofiltration and/or ultrafiltration membrane having a molecular weight cut-off of from about 500 Dalton to 1000 Dalton, thereby separating a fraction of low molecular weight vinylamine-containing polymer from a retentate having a weight average molecular weight of from about 10,000 to about 1,000,000 Da.; and
collecting the retentate of the higher molecular vinylamine containing polymer, wherein the weight average molecular weight of the collected fraction of the higher molecular vinylamine-containing polymer is from about 10,000 to about 1,000,000 Da.
9 . The method according to claim 8 , wherein the weight average molecular weight of the collected fraction of vinylamine-containing polymer retentate is from about 100,000 to about 250,000 Da.