IP Library Granted Patent US 12,655,304
Granted Patent B2
US 12,655,304 · App. 18/314,575 · Granted Jun 16, 2026

Coating to cool a surface by passive radiative cooling

Inventors: Sepehr Tehrani (Toronto, CA); Quentin Van Overmeere (Mountain View, CA); Scott Alan Elrod (Palo Alto, CA); Scott E. Solberg (San Jose, CA); Gabriel Iftime (Dublin, CA); Ravi Neelakantan (Redwood City, CA); Bernard D. Casse (Saratoga, CA)
Assignee: Genesee Valley Innovations, LLC
C09D5/004C09D5/024C09D7/69C09D129/14C09D133/10C08K2003/2241C08K2003/3045C08K2201/005
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,655,304
App. No.
18/314,575
Granted
Jun 16, 2026
Kind
B2
Abstract

Disclosed herein in is a radiative cooling formulation including a solvent for providing a viscosity of a radiative cooling material for application onto a surface to be passively cooled. The radiative cooling formulation includes a binder for the radiative cooling material's integrity and bonding to the surface to be passively cooled. The radiative cooling formulation includes a polymer, which, in combination with the binder, provides one or more properties in the radiative cooling material, including a reflectance of or greater than 55% in a wavelengths range of 0.3 to 2.5 microns and a first thermal emissivity peak value greater than 0.85 at a first wavelength in a range of 8 to 13 microns (μm). For example, the polymer is a latex material including a styrene based copolymer.

Claims (35)

1 . An apparatus comprising:

a substrate;

a radiative cooling material on the substrate, the radiative cooling material comprising:

a medium for providing a viscosity for application of the radiative cooling material onto a surface to be passively cooled;

a binder for the radiative cooling material's integrity and bonding to the surface to be passively cooled, wherein the binder comprises a latex;

a solar reflector material embedded in the binder, the solar reflector material comprising particles of barium sulfate (BaSO 4 ) wherein at least half of the particles of BaSO 4 are smaller than 2 microns (μm); and

a polymer in combination with the binder for providing properties including a first thermal emissivity peak value greater than 0.85 at a first wavelength in a range of 8 to 13 microns (μm).

2 . The apparatus of claim 1 , wherein the polymer is formed from a non-styrene material.

3 . The apparatus of claim 1 , wherein the binder comprises a dispersion of one or more polymers in the medium.

4 . The apparatus of claim 3 , wherein the binder comprises nanoparticles having a particle size from about 10 nm to 500 nm dispersed in the medium, and wherein the dispersion is about 80% by weight of the radiative cooling material.

5 . The apparatus of claim 1 , wherein the polymer comprises a styrene based copolymer being about 15% by weight of the radiative cooling material.

6 . The apparatus of claim 5 , wherein the styrene based copolymer is a latex material formed by:

a surfactant;

a medium (or media);

a plurality of monomers; and

an initiator.

7 . The apparatus of claim 6 , wherein the plurality of monomers comprises at least one of:

an acrylate; or

a methacrylic acid.

8 . A method of manufacturing the apparatus of claim 1 , the method comprising:

physically mixing:

an aqueous medium for providing a viscosity for application of the radiative cooling material onto a surface to be passively cooled;

a binder for the radiative cooling material's integrity and bonding to the surface to be passively cooled, wherein the binder comprises a latex;

a solar reflector material embedded in the binder, the solar reflector material comprising particles of barium sulfate (BaSO 4 ) wherein at least half of the particles of BaSO 4 are smaller than 2 microns (μm); and

a polymer in combination with the binder for providing properties including a first thermal emissivity peak value greater than 0.85 at a first wavelength in a range of 8 to 13 microns (μm).

9 . The method of claim 8 , wherein the aqueous medium in total is about 30% by weight of the radiative cooling material, accounting for respective media or solvents in the binder and the polymer.

10 . The method of claim 8 , wherein the binder comprises a dispersion of one or more polymers in the aqueous medium.

11 . The method of claim 10 , wherein the binder comprises nanoparticles having a particle size from about 10 nm to 500 nm dispersed in the aqueous medium, and wherein the dispersion is about 80% by weight of the radiative cooling material.

12 . The method of claim 8 , wherein the polymer comprises a styrene based copolymer about 15% by weight of the radiative cooling material.

13 . The method of claim 12 , wherein the styrene based copolymer is a latex material formed by one or more of:

a surfactant;

a medium or media;

a plurality of monomers; and

an initiator.

14 . The method of claim 8 , wherein the binder comprises a solar reflector material.

Assignments (8)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 31, 2025
From: XEROX CORPORATION
To: GENESEE VALLEY INNOVATIONS, LLC
Reel/Frame 073225/0116 →
SECOND LIEN NOTES PATENT SECURITY AGREEMENT Recorded Jul 2, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 071785/0550 →
FIRST LIEN NOTES PATENT SECURITY AGREEMENT Recorded Apr 11, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 070824/0001 →
SECURITY INTEREST Recorded Feb 13, 2024
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 066741/0001 →
SECURITY INTEREST Recorded Nov 20, 2023
From: XEROX CORPORATION
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 065628/0019 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVAL OF US PATENTS 9356603, 10026651, 10626048 AND INCLUSION OF US PATENT 7167871 PREVIOUSLY RECORDED ON REEL 064038 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jun 28, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064161/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 20, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064038/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 11, 2023
From: TEHRANI, SEPEHR; VAN OVERMEERE, QUENTIN; ELROD, SCOTT ALAN; SOLBERG, SCOTT E.; IFTIME, GABRIEL; NEELAKANTAN, RAVI; CASSE, BERNARD D.
To: PALO ALTO RESEARCH CENTER INCORPORATED
Reel/Frame 063611/0257 →
Continuity (5)
Continuation In Part 17392028 · Aug 2, 2021
Continuation 16683666 · Nov 14, 2019
Continuation 16403285 · May 3, 2019
Division 15444029 · Feb 27, 2017
Related Publication 20240101833A1 · Mar 28, 2024
References Cited (14)
US 7503971B2 · Wojtysiak et al. · 2009 [cited by applicant]
US 10584250B2 · Van Overmeere · 2020 [cited by examiner]
US 11084944B2 · Van Overmeere · 2021 [cited by examiner]
US 11667795B2 · Van Overmeere · 2023 [cited by examiner]
US 20050064094A1 · Wojtysiak · 2005 [cited by examiner]
US 20060141162A1 · Egusa · 2006 [cited by examiner]
US 20120057224A1 · Story · 2012 [cited by examiner]
US 20160363394A1 · Liu et al. · 2016 [cited by applicant]
US 20160363396A1 · Liu et al. · 2016 [cited by applicant]
US 20170248381A1 · Yang · 2017 [cited by examiner]
WO WO2016205717A1 · 2016 [cited by examiner]
Chen, Zhen, et al. “Radiative cooling to deep sub-freezing temperatures through a 24-h day-night cycle.” Nature Communications 7 (Dec. 13, 2016). [cited by applicant]
Gentle, Angus R., and Geoff B. Smith. “A subambient open roof surface under the Mid-Summer sun.” Advanced Science 2.9 (May 26, 2015). [cited by applicant]
Raman, Aaswath P., et al. “Passive radiative cooling below ambient air temperature under direct sunlight.” Nature 515.7528 (Nov. 2014): 540-544. [cited by applicant]