WEAK BASE ANION RESIN POLYMERS COMPRISING ALKYLAMINE SEGMENTS AND CROSS-LINKING SEGMENTS, AND THEIR METHODS OF USE IN ION EXCHANGE
A weak base anion resin has alkylamine segments covalently bound to cross-linking segments, the alkylamine segments being selected from a group consisting of: vinylamine, N-methylvinylamine, N,N-dimethylvinylamine, N-methyl-N-ethylvinylamine, and N,N-diethylvinylamine, and the weak base anion resin including ions adsorbed to the alkylamine segments. A method for ion exchange includes providing a weak base anion resin, contacting the weak base anion resin with a solution containing ions to one of capture or adsorb ions from solution to the weak base anion resin, and regenerating the weak base anion resin. A method to capture and release an acid gas includes providing a weak base anion resin, contacting the weak base anion resin with a gas including an acid gas to one of capture or adsorb the acid gas from the gas to the weak base anion resin, and regenerating the weak base anion resin to release the acid gas.
1 . A weak base anion resin comprising:
alkylamine segments covalently bound to cross-linking segments, the alkylamine segments being selected from a group consisting of: vinylamine, N-methylvinylamine, N,N-dimethylvinylamine, N-methyl-N-ethylvinylamine, and N,N-diethylvinylamine, and the weak base anion resin further comprises ions adsorbed to the alkylamine segments.
2 . The weak base anion resin as claimed in claim 1 , wherein:
the cross-linking segments comprise divinylbenzene, and
the weak base anion resin comprises a polymer selected from a group consisting of: poly(vinylamine-co-divinylbenzene), poly(N-methylvinylamine-co-divinylbenzene), poly(N,N-dimethylvinylamine-co-divinylbenzene), poly(N-methyl-N-ethylvinylamine-co-divinylbenzene), and poly(N,N-diethylvinylamine-co-divinylbenzene).
3 . The weak base anion resin as claimed in claim 1 , wherein the cross-linking segments are selected from a group consisting of: diacrylate, dimethacrylate, 1,4-butanediol divinyl ether, 1,4-pentantane-3-ol, 1,4-butanediol divinyl ether, 1,4-pentantane-3-ol, and divinyl sulfone, and wherein the weak base anion resin comprises a polymer selected from a group consisting of: poly(vinylamine-co-dimethacrylate), poly(vinylamine-co-diacrylate), poly(vinylamine-co-1,4-butanediol divinyl ether), poly(vinylamine-co-1,4-pentantane-3-ol), poly(vinylamine-co-divinyl sulfone), poly(N-methylvinylamine-co-dimethacrylate), poly(N-methylvinylamine-co-diacrylate), poly(N-methylvinylamine-co-1,4-butanediol divinyl ether), poly(N-methylvinylamine-co-1,4-pentantane-3-ol), poly(N-methylvinylamine-co-divinyl sulfone), poly(N,N-dimethylvinylamine-co-dimethacrylate), poly(N,N-dimethylvinylamine-co-diacrylate), poly(N,N-dimethylvinylamine-co-1,4-butanediol divinyl ether), poly(N,N-dimethylvinylamine-co-1,4-pentantane-3-ol), poly(N,N-dimethylvinylamine-co-1,4-pentantane-3-ol), poly(N,N-dimethylvinylamine-co-divinyl sulfone), poly(N-methyl-N-ethylvinylamine-co-dimethacrylane), poly(N-methyl-N-ethylvinylamine-co-diacrylate), poly(N-methyl-N-ethylvinylamine-co-1,4-butanediol divinyl ether), poly(N-methyl-N-ethylvinylamine-co-1,4,-pentane-3-ol), poly(N-methyl-N-ethylvinylamine-co-divinyl sulfone), poly(N,N-diethylvinylamine-co-dimethacrylane), poly(N-methyl-N-ethylvinylamine-co-diacrylate), poly(N,N-diethylvinylamine-co-1,4-butanediol divinyl ether), and poly(N,N-diethylvinylamine-co-1,4,-pentane-3-ol), and poly(N,N-diethylvinylamine-co-divinyl sulfone).
4 . The weak base anion resin as claimed in claim 1 , wherein the ions comprise an anion and a cation, and the cation is selected from a group consisting of: a proton, an inorganic cation, an organic acid, a metal cation, Li(I), Na(I), K(I), Cu(I), Rb(I), Ag(I), Cs(I), Au(I), Hg(I), Tl(I), At(I), Fr(I), Be(II), Mg(II), Ca(II), Ti(II), Cr(II), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Ge(II), Sr(II), Pd(II), Cd(II), Sn(II), Te(II), Ba(II), Pt(II), Hg(II), Pb(II), Po(II), Ra(II), Eu(II), Sm(II), Yb(II), No(II), Sc(III), Ti(III), V(III), Cr(III), Mn(III), Fe(III), Co(III), Ni(III), Ga(III), As(III), Y(III), Nb(III), Ru(III), In(III), Sb(III), La(III), Os(III), Ir(III), Au(III), Tl(III), Bi(III), Ac(III), Ce(III), Pr(III), Nd(III), Pm(III), Sm(III), Eu(III), Gd(III), Tb(III), Dy(III), Ho(III), Er(III), Tm(III), Yb(III), Lu(III), U(III), Np(III), Pu(III), Am(III), Cm(III), Bk(III), Cf(III), Es(III), Fm(III), Md(III), No(III), Lr(III), Ti(IV), V(IV), Mn(IV), Ge(IV), Zr(IV), Tc(IV), Pd(IV), Sn(IV), Te(IV), Hf(IV), Re(IV), Os(IV), Ir(IV), Pt(IV), Pb(IV), Po(IV), Ce(IV), Pa(IV), U(IV), Np(IV), Pu(IV), Am(IV), and Bk(IV), V(V), As(V), Nb(V), Sb(V), Ta(V), Bi(V), Pa(V), U(V), Np(V), Pu(V), Am(V), Cr(VI), Mo(VI), Tc(VI), Te(VI), W(VI), Re(VI), U(VI), Np(VI), Pu(VI), Am(VI), Mn(VII), Tc(VII), Re(VII), a rare earth element, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, yttrium, and a dye.
5 . The weak base anion resin as claimed in claim 1 , wherein:
the cross-linking segments comprise divinylbenzene,
the weak base anion resin comprises a polymer selected from a group consisting of: poly(vinylamine-co-divinylbenzene), poly(N-methylvinylamine-co-divinylbenzene), poly(N,N-dimethylvinylamine-co-divinylbenzene), poly(N-methyl-N-ethylvinylamine-co-divinylbenzene), and poly(N,N-diethylvinylamine-co-divinylbenzene), and
the ions comprise an anion and a cation, and the cation is selected from a group consisting of: a proton, an inorganic cation, an organic acid, a metal cation, Li(I), Na(I), K(I), Cu(I), Rb(I), Ag(I), Cs(I), Au(I), Hg(I), Tl(I), At(I), Fr(I), Be(II), Mg(II), Ca(II), Ti(II), Cr(II), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Ge(II), Sr(II), Pd(II), Cd(II), Sn(II), Te(II), Ba(II), Pt(II), Hg(II), Pb(II), Po(II), Ra(II), Eu(II), Sm(II), Yb(II), No(II), Sc(III), Ti(III), V(III), Cr(III), Mn(III), Fe(III), Co(III), Ni(III), Ga(III), As(III), Y(III), Nb(III), Ru(III), In(III), Sb(III), La(III), Os(III), Ir(III), Au(III), Tl(III), Bi(III), Ac(III), Ce(III), Pr(III), Nd(III), Pm(III), Sm(III), Eu(III), Gd(III), Tb(III), Dy(III), Ho(III), Er(III), Tm(III), Yb(III), Lu(III), U(III), Np(III), Pu(III), Am(III), Cm(III), Bk(III), Cf(III), Es(III), Fm(III), Md(III), No(III), Lr(III), Ti(IV), V(IV), Mn(IV), Ge(IV), Zr(IV), Tc(IV), Pd(IV), Sn(IV), Te(IV), Hf(IV), Re(IV), Os(IV), Ir(IV), Pt(IV), Pb(IV), Po(IV), Ce(IV), Pa(IV), U(IV), Np(IV), Pu(IV), Am(IV), and Bk(IV), V(V), As(V), Nb(V), Sb(V), Ta(V), Bi(V), Pa(V), U(V), Np(V), Pu(V), Am(V), Cr(VI), Mo(VI), Tc(VI), Te(VI), W(VI), Re(VI), U(VI), Np(VI), Pu(VI), Am(VI), Mn(VII), Tc(VII), Re(VII), a rare earth element, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, yttrium, and a dye.
6 . The weak base anion resin as claimed in claim 1 , wherein:
the cross-linking segments are selected from a group consisting of: diacrylate, dimethacrylate, 1,4-butanediol divinyl ether, 1,4-pentantane-3-ol, 1,4-butanediol divinyl ether, 1,4-pentantane-3-ol, and divinyl sulfone,
the weak base anion resin comprises a polymer selected from a group consisting of: poly(vinylamine-co-dimethacrylate), poly(vinylamine-co-diacrylate), poly(vinylamine-co-1,4-butanediol divinyl ether), poly(vinylamine-co-1,4-pentantane-3-ol), poly(vinylamine-co-divinyl sulfone), poly(N-methylvinylamine-co-dimethacrylate), poly(N-methylvinylamine-co-diacrylate), poly(N-methylvinylamine-co-1,4-butanediol divinyl ether), poly(N-methylvinylamine-co-1,4-pentantane-3-ol), poly(N-methylvinylamine-co-divinyl sulfone), poly(N,N-dimethylvinylamine-co-dimethacrylate), poly(N,N-dimethylvinylamine-co-diacrylate), poly(N,N-dimethylvinylamine-co-1,4-butanediol divinyl ether), poly(N,N-dimethylvinylamine-co-1,4-pentantane-3-ol), poly(N,N-dimethylvinylamine-co-1,4-pentantane-3-ol), poly(N,N-dimethylvinylamine-co-divinyl sulfone), poly(N-methyl-N-ethylvinylamine-co-dimethacrylane), poly(N-methyl-N-ethylvinylamine-co-diacrylate), poly(N-methyl-N-ethylvinylamine-co-1,4-butanediol divinyl ether), poly(N-methyl-N-ethylvinylamine-co-1,4,-pentane-3-ol), poly(N-methyl-N-ethylvinylamine-co-divinyl sulfone), poly(N,N-diethylvinylamine-co-dimethacrylane), poly(N-methyl-N-ethylvinylamine-co-diacrylate), poly(N,N-diethylvinylamine-co-1,4-butanediol divinyl ether), and poly(N,N-diethylvinylamine-co-1,4,-pentane-3-ol), poly(N,N-diethylvinylamine-co-divinyl sulfone), and
the ions comprise an anion and a cation, and the cation is selected from a group consisting of: a proton, an inorganic cation, an organic acid, a metal cation, Li(I), Na(I), K(I), Cu(I), Rb(I), Ag(I), Cs(I), Au(I), Hg(I), Tl(I), At(I), Fr(I), Be(II), Mg(II), Ca(II), Ti(II), Cr(II), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Ge(II), Sr(II), Pd(II), Cd(II), Sn(II), Te(II), Ba(II), Os(III), Ir(III), Au(III), Tl(III), Bi(III), Ac(III), Ce(III), Pr(III), Nd(III), Pm(III), Sm(III), Eu(III), Gd(III), Tb(III), Dy(III), Ho(III), Er(III), Tm(III), Yb(III), Lu(III), U(III), Np(III), Pu(III), Am(III), Cm(III), Bk(III), Cf(III), Es(III), Fm(III), Md(III), No(III), Lr(III), Ti(IV), V(IV), Mn(IV), Ge(IV), Zr(IV), Tc(IV), Pd(IV), Sn(IV), Te(IV), Hf(IV), Re(IV), Os(IV), Ir(IV), Pt(IV), Pb(IV), Po(IV), Ce(IV), Pa(IV), U(IV), Np(IV), Pu(IV), Am(IV), and Bk(IV), V(V), As(V), Nb(V), Sb(V), Ta(V), Bi(V), Pa(V), U(V), Np(V), Pu(V), Am(V), Cr(VI), Mo(VI), Tc(VI), Te(VI), W(VI), Re(VI), U(VI), Np(VI), Pu(VI), Am(VI), Mn(VII), Tc(VII), Re(VII), a rare earth element, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, yttrium, and a dye.
7 . A method for ion exchange, the method comprising:
providing a weak base anion resin;
contacting the weak base anion resin with a solution containing ions to one of either capture or adsorb ions from solution to the weak base anion resin; and
regenerating the weak base anion resin, the weak base anion resin comprising alkylamine segments covalently bound to cross-linking segments, and the alkylamine segments are selected from a group consisting of: vinylamine, N-methylvinylamine, N,N-dimethylvinylamine, N-methyl-N-ethylvinylamine, and N,N-diethylvinylamine.
8 . The method as claimed in claim 7 , wherein:
the cross-linking segments comprise divinylbenzene, and the weak base anion resin comprises a polymer selected from a group consisting of: poly(vinylamine-co-divinylbenzene), poly(N-methylvinylamine-co-divinylbenzene), poly(N,N-dimethylvinylamine-co-divinylbenzene), poly(N-methyl-N-ethylvinylamine-co-divinylbenzene), and poly(N,N-diethylvinylamine-co-divinylbenzene).
9 . The method as claimed in claim 7 , wherein:
the cross-linking segments are selected from a group consisting of: diacrylate, dimethacrylate, 1,4-butanediol divinyl ether, 1,4-pentantane-3-ol, 1,4-butanediol divinyl ether, 1,4-pentantane-3-ol, and divinyl sulfone, and
the weak base anion resin comprises a polymer selected from a group consisting of: poly(vinylamine-co-dimethacrylate), poly(vinylamine-co-diacrylate), poly(vinylamine-co-1,4-butanediol divinyl ether), poly(vinylamine-co-1,4-pentantane-3-ol), poly(vinylamine-co-divinyl sulfone), poly(N-methylvinylamine-co-dimethacrylate), poly(N-methylvinylamine-co-diacrylate), poly(N-methylvinylamine-co-1,4-butanediol divinyl ether), poly(N-methylvinylamine-co-1,4-pentantane-3-ol), poly(N-methylvinylamine-co-divinyl sulfone), poly(N,N-dimethylvinylamine-co-dimethacrylate), poly(N,N-dimethylvinylamine-co-diacrylate), poly(N,N-dimethylvinylamine-co-1,4-butanediol divinyl ether), poly(N,N-dimethylvinylamine-co-1,4-pentantane-3-ol), poly(N,N-dimethylvinylamine-co-1,4-pentantane-3-ol), poly(N,N-dimethylvinylamine-co-divinyl sulfone), poly(N-methyl-N-ethylvinylamine-co-dimethacrylane), poly(N-methyl-N-ethylvinylamine-co-diacrylate), poly(N-methyl-N-ethylvinylamine-co-1,4-butanediol divinyl ether), poly(N-methyl-N-ethylvinylamine-co-1,4,-pentane-3-ol), poly(N-methyl-N-ethylvinylamine-co-divinyl sulfone), poly(N,N-diethylvinylamine-co-dimethacrylane), poly(N-methyl-N-ethylvinylamine-co-diacrylate), poly(N,N-diethylvinylamine-co-1,4-butanediol divinyl ether), and poly(N,N-diethylvinylamine-co-1,4,-pentane-3-ol), and poly(N,N-diethylvinylamine-co-divinyl sulfone).
10 . The method as claimed in claim 7 , wherein the solution containing ions comprises an anion and a cation, and the cation is selected from a group consisting of: a proton, an inorganic cation, an organic acid, a metal cation, Li(I), Na(I), K(I), Cu(I), Rb(I), Ag(I), Cs(I), Au(I), Hg(I), Tl(I), At(I), Fr(I), Be(II), Mg(II), Ca(II), Ti(II), Cr(II), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Ge(II), Sr(II), Pd(II), Cd(II), Sn(II), Te(II), Ba(II), Pt(II), Hg(II), Pb(II), Po(II), Ra(II), Eu(II), s(II), Yb(II), No(II), Sc(III), Ti(III), V(III), Cr(III), Mn(III), Fe(III), Co(III), Ni(III), Ga(III), As(III), Y(III), Nb(III), Ru(III), In(III), Sb(III), La(III), Os(III), Ir(III), Au(III), Tl(III), Bi(III), Ac(III), Ce(III), Pr(III), Nd(III), Pm(III), Sm(III), Eu(III), Gd(III), Tb(III), Dy(III), Ho(III), Er(III), Tm(III), Yb(III), Lu(III), U(III), Np(III), Pu(III), Am(III), Cm(III), Bk(III), Cf(III), Es(III), Fm(III), Md(III), No(III), Lr(III), Ti(IV), V(IV), Mn(IV), Ge(IV), Zr(IV), Tc(IV), Pd(IV), Sn(IV), Te(IV), Hf(IV), Re(IV), Os(IV), Ir(IV), Pt(IV), Pb(IV), Po(IV), Ce(IV), Pa(IV), U(IV), Np(IV), Pu(IV), Am(IV), and Bk(IV), V(V), As(V), Nb(V), Sb(V), Ta(V), Bi(V), Pa(V), U(V), Np(V), Pu(V), Am(V), Cr(VI), Mo(VI), Tc(VI), Te(VI), W(VI), Re(VI), U(VI), Np(VI), Pu(VI), Am(VI), Mn(VII), Tc(VII), Re(VII), a rare earth element, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, yttrium, and a dye.
11 . The method as claimed in claim 7 , wherein:
the cross-linking segments comprise divinylbenzene,
the weak base anion resin comprises a polymer selected from a group consisting of: poly(vinylamine-co-divinylbenzene), poly(N-methylvinylamine-co-divinylbenzene), poly(N,N-dimethylvinylamine-co-divinylbenzene), poly(N-methyl-N-ethylvinylamine-co-divinylbenzene), and poly(N,N-diethylvinylamine-co-divinylbenzene), the solution containing ions comprises an anion and a cation, and the cation is selected from a group consisting of: a proton, an inorganic cation, an organic acid, a metal cation, Li(I), Na(I), K(I), Cu(I), Rb(I), Ag(I), Cs(I), Au(I), Hg(I), Tl(I), At(I), Fr(I), Be(II), Mg(II), Ca(II), Ti(II), Cr(II), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Ge(II), Sr(II), Pd(II), Cd(II), Sn(II), Te(II), Ba(II), Pt(II), Hg(II), Pb(II), Po(II), Ra(II), Eu(II), s(II), Yb(II), No(II), Sc(III), Ti(III), V(III), Cr(III), Mn(III), Fe(III), Co(III), Ni(III), Ga(III), As(III), Y(III), Nb(III), Ru(III), In(III), Sb(III), La(III), Os(III), Ir(III), Au(III), Tl(III), Bi(III), Ac(III), Ce(III), Pr(III), Nd(III), Pm(III), Sm(III), Eu(III), Gd(III), Tb(III), Dy(III), Ho(III), Er(III), Tm(III), Yb(III), Lu(III), U(III), Np(III), Pu(III), Am(III), Cm(III), Bk(III), Cf(III), Es(III), Fm(III), Md(III), No(III), Lr(III), Ti(IV), V(IV), Mn(IV), Ge(IV), Zr(IV), Tc(IV), Pd(IV), Sn(IV), Te(IV), Hf(IV), Re(IV), Os(IV), Ir(IV), Pt(IV), Pb(IV), Po(IV), Ce(IV), Pa(IV), U(IV), Np(IV), Pu(IV), Am(IV), and Bk(IV), V(V), As(V), Nb(V), Sb(V), Ta(V), Bi(V), Pa(V), U(V), Np(V), Pu(V), Am(V), Cr(VI), Mo(VI), Tc(VI), Te(VI), W(VI), Re(VI), U(VI), Np(VI), Pu(VI), Am(VI), Mn(VII), Tc(VII), Re(VII), a rare earth element, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, yttrium, and a dye.
12 . The method as claimed in claim 7 , wherein:
the cross-linking segments are selected from a group consisting of: diacrylate, dimethacrylate, 1,4-butanediol divinyl ether, 1,4-pentantane-3-ol, 1,4-butanediol divinyl ether, 1,4-pentantane-3-ol, and divinyl sulfone,
the weak base anion resin comprises a polymer selected from a group consisting of: poly(vinylamine-co-dimethacrylate), poly(vinylamine-co-diacrylate), poly(vinylamine-co-1,4-butanediol divinyl ether), poly(vinylamine-co-1,4-pentantane-3-ol), poly(vinylamine-co-divinyl sulfone), poly(N-methylvinylamine-co-dimethacrylate), poly(N-methylvinylamine-co-diacrylate), poly(N-methylvinylamine-co-1,4-butanediol divinyl ether), poly(N-methylvinylamine-co-1,4-pentantane-3-ol), poly(N-methylvinylamine-co-divinyl sulfone), poly(N,N-dimethylvinylamine-co-dimethacrylate), poly(N,N-dimethylvinylamine-co-diacrylate), poly(N,N-dimethylvinylamine-co-1,4-butanediol divinyl ether), poly(N,N-dimethylvinylamine-co-1,4-pentantane-3-ol), poly(N,N-dimethylvinylamine-co-1,4-pentantane-3-ol), poly(N,N-dimethylvinylamine-co-divinyl sulfone), poly(N-methyl-N-ethylvinylamine-co-dimethacrylane), poly(N-methyl-N-ethylvinylamine-co-diacrylate), poly(N-methyl-N-ethylvinylamine-co-1,4-butanediol divinyl ether), poly(N-methyl-N-ethylvinylamine-co-1,4,-pentane-3-ol), poly(N-methyl-N-ethylvinylamine-co-divinyl sulfone), poly(N,N-diethylvinylamine-co-dimethacrylane), poly(N-methyl-N-ethylvinylamine-co-diacrylate), poly(N,N-diethylvinylamine-co-1,4-butanediol divinyl ether), and poly(N,N-diethylvinylamine-co-1,4,-pentane-3-ol), and poly(N,N-diethylvinylamine-co-divinyl sulfone), and
the solution containing ions comprises an anion and a cation, and the cation is selected from a group consisting of: a proton, an inorganic cation, an organic acid, a metal cation, Li(I), Na(I), K(I), Cu(I), Rb(I), Ag(I), Cs(I), Au(I), Hg(I), Tl(I), At(I), Fr(I), Be(II), Mg(II), Ca(II), Ti(II), Cr(II), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Ge(II), Sr(II), Pd(II), Cd(II), Sn(II), Te(II), Ba(II), Pt(II), Hg(II), Pb(II), Po(II), Ra(II), Eu(II), Sm(II), Yb(II), No(II), Sc(III), Ti(III), V(III), Cr(III), Mn(III), Fe(III), Co(III), Ni(III), Ga(III), As(III), Y(III), Nb(III), Ru(III), In(III), Sb(III), La(III), Os(III), Ir(III), Au(III), Tl(III), Bi(III), Ac(III), Ce(III), Pr(III), Nd(III), Pm(III), Sm(III), Eu(III), Gd(III), Tb(III), Dy(III), Ho(III), Er(III), Tm(III), Yb(III), Lu(III), U(III), Np(III), Pu(III), Am(III), Cm(III), Bk(III), Cf(III), Es(III), Fm(III), Md(III), No(III), Lr(III), Ti(IV), V(IV), Mn(IV), Ge(IV), Zr(IV), Tc(IV), Pd(IV), Sn(IV), Te(IV), Hf(IV), Re(IV), Os(IV), Ir(IV), Pt(IV), Pb(IV), Po(IV), Ce(IV), Pa(IV), U(IV), Np(IV), Pu(IV), Am(IV), and Bk(IV), V(V), As(V), Nb(V), Sb(V), Ta(V), Bi(V), Pa(V), U(V), Np(V), Pu(V), Am(V), Cr(VI), Mo(VI), Tc(VI), Te(VI), W(VI), Re(VI), U(VI), Np(VI), Pu(VI), Am(VI), Mn(VII), Tc(VII), Re(VII), a rare earth element, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, yttrium, and a dye.
13 . A method to capture and release an acid gas, the method comprising:
providing a weak base anion resin;
contacting the weak base anion resin with a gas comprising an acid gas to one of capture or adsorb the acid gas from the gas to the weak base anion resin; and
regenerating the weak base anion resin to release the acid gas, the weak base anion resin comprising alkylamine segments covalently bound to cross-linking segments, the alkylamine segments being selected from a group consisting of: vinylamine, N-methylvinylamine, N,N-dimethylvinylamine, N-methyl-N-ethylvinylamine, and N,N-diethylvinylamine, and the weak base anion resin further comprises ions adsorbed to the alkylamine segments.
14 . The method as claimed in claim 13 , wherein the acid gas is selected from a group consisting of: sulfur oxide, sulfur monoxide, sulfur dioxide, sulfur trioxide, nitrogen oxide, nitrogen dioxide, nitrogen trioxide, nitrous oxide, dinitrogen dioxide, dinitrogen trioxide, dinitrogen tetroxide, dinitrogen pentoxide, nitrosylazide, oxatetrazol, trinitramide, hydrogen sulfide, and carbon dioxide.
15 . The method as claimed in claim 13 , wherein:
the cross-linking segments comprise divinylbenzene, and
the weak base anion resin comprises a polymer selected from a group consisting of: poly(vinylamine-co-divinylbenzene), poly(N-methylvinylamine-co-divinylbenzene), poly(N,N-dimethylvinylamine-co-divinylbenzene), poly(N-methyl-N-ethylvinylamine-co-divinylbenzene), and poly(N,N-diethylvinylamine-co-divinylbenzene).
16 . The method as claimed in claim 13 , wherein:
the cross-linking segments are selected from a group consisting of: diacrylate, dimethacrylate, 1,4-butanediol divinyl ether, 1,4-pentantane-3-ol, 1,4-butanediol divinyl ether, 1,4-pentantane-3-ol, and divinyl sulfone, and
the weak base anion resin comprises a polymer selected from a group consisting of: poly(vinylamine-co-dimethacrylate), poly(vinylamine-co-diacrylate), poly(vinylamine-co-1,4-butanediol divinyl ether), poly(vinylamine-co-1,4-pentantane-3-ol), poly(vinylamine-co-divinyl sulfone), poly(N-methylvinylamine-co-dimethacrylate), poly(N-methylvinylamine-co-diacrylate), poly(N-methylvinylamine-co-1,4-butanediol divinyl ether), poly(N-methylvinylamine-co-1,4-pentantane-3-ol), poly(N-methylvinylamine-co-divinyl sulfone), poly(N,N-dimethylvinylamine-co-dimethacrylate), poly(N,N-dimethylvinylamine-co-diacrylate), poly(N,N-dimethylvinylamine-co-1,4-butanediol divinyl ether), poly(N,N-dimethylvinylamine-co-1,4-pentantane-3-ol), poly(N,N-dimethylvinylamine-co-1,4-pentantane-3-ol), poly(N,N-dimethylvinylamine-co-divinyl sulfone), poly(N-methyl-N-ethylvinylamine-co-dimethacrylane), poly(N-methyl-N-ethylvinylamine-co-diacrylate), poly(N-methyl-N-ethylvinylamine-co-1,4-butanediol divinyl ether), poly(N-methyl-N-ethylvinylamine-co-1,4,-pentane-3-ol), poly(N-methyl-N-ethylvinylamine-co-divinyl sulfone), poly(N,N-diethylvinylamine-co-dimethacrylane), poly(N-methyl-N-ethylvinylamine-co-diacrylate), poly(N,N-diethylvinylamine-co-1,4-butanediol divinyl ether), and poly(N,N-diethylvinylamine-co-1,4,-pentane-3-ol), and poly(N,N-diethylvinylamine-co-divinyl sulfone).
17 . The method as claimed in claim 13 , wherein the ions are selected from the group consisting of: a proton, an inorganic cation, an organic acid, a metal cation, Li(I), Na(I), K(I), Cu(I), Rb(I), Ag(I), Cs(I), Au(I), Hg(I), Tl(I), At(I), Fr(I), Be(II), Mg(II), Ca(II), Ti(II), Cr(II), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Ge(II), Sr(II), Pd(II), Cd(II), Sn(II), Te(II), Ba(II), Pt(II), Hg(II), Pb(II), Po(II), Ra(II), Eu(II), Sm(II), Yb(II), No(II), Sc(III), Ti(III), V(III), Cr(III), Mn(III), Fe(III), Co(III), Ni(III), Ga(III), As(III), Y(III), Nb(III), Ru(III), In(III), Sb(III), La(III), Os(III), Ir(III), Au(III), Tl(III), Bi(III), Ac(III), Ce(III), Pr(III), Nd(III), Pm(III), Sm(III), Eu(III), Gd(III), Tb(III), Dy(III), Ho(III), Er(III), Tm(III), Yb(III), Lu(III), U(III), Np(III), Pu(III), Am(III), Cm(III), Bk(III), Cf(III), Es(III), Fm(III), Md(III), No(III), Lr(III), Ti(IV), V(IV), Mn(IV), Ge(IV), Zr(IV), Tc(IV), Pd(IV), Sn(IV), Te(IV), Hf(IV), Re(IV), Os(IV), Ir(IV), Pt(IV), Pb(IV), Po(IV), Ce(IV), Pa(IV), U(IV), Np(IV), Pu(IV), Am(IV), and Bk(IV), V(V), As(V), Nb(V), Sb(V), Ta(V), Bi(V), Pa(V), U(V), Np(V), Pu(V), Am(V), Cr(VI), Mo(VI), Tc(VI), Te(VI), W(VI), Re(VI), U(VI), Np(VI), Pu(VI), Am(VI), Mn(VII), Tc(VII), Re(VII), a rare earth element, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, yttrium, and a dye.
18 . The method as claimed in claim 13 , wherein:
the cross-linking segments comprise divinylbenzene,
the weak base anion resin comprises a polymer selected from a group consisting of: poly(vinylamine-co-divinylbenzene), poly(N-methylvinylamine-co-divinylbenzene), poly(N,N-dimethylvinylamine-co-divinylbenzene), poly(N-methyl-N-ethylvinylamine-co-divinylbenzene), and poly(N,N-diethylvinylamine-co-divinylbenzene), and
the ions comprise an anion and a cation, and wherein the cation is selected from a group consisting of: a proton, an inorganic cation, an organic acid, a metal cation, Li(I), Na(I), K(I), Cu(I), Rb(I), Ag(I), Cs(I), Au(I), Hg(I), Tl(I), At(I), Fr(I), Be(II), Mg(II), Ca(II), Ti(II), Cr(II), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Ge(II), Sr(II), Pd(II), Cd(II), Sn(II), Te(II), Ba(II), Pt(II), Hg(II), Pb(II), Po(II), Ra(II), Eu(II), Sm(II), Yb(II), No(II), Sc(III), Ti(III), V(III), Cr(III), Mn(III), Fe(III), Co(III), Ni(III), Ga(III), As(III), Y(III), Nb(III), Ru(III), In(III), Sb(III), La(III), Os(III), Ir(III), Au(III), Tl(III), Bi(III), Ac(III), Ce(III), Pr(III), Nd(III), Pm(III), Sm(III), Eu(III), Gd(III), Tb(III), Dy(III), Ho(III), Er(III), Tm(III), Yb(III), Lu(III), U(III), Np(III), Pu(III), Am(III), Cm(III), Bk(III), Cf(III), Es(III), Fm(III), Md(III), No(III), Lr(III), Ti(IV), V(IV), Mn(IV), Ge(IV), Zr(IV), Tc(IV), Pd(IV), Sn(IV), Te(IV), Hf(IV), Re(IV), Os(IV), Ir(IV), Pt(IV), Pb(IV), Po(IV), Ce(IV), Pa(IV), U(IV), Np(IV), Pu(IV), Am(IV), and Bk(IV), V(V), As(V), Nb(V), Sb(V), Ta(V), Bi(V), Pa(V), U(V), Np(V), Pu(V), Am(V), Cr(VI), Mo(VI), Tc(VI), Te(VI), W(VI), Re(VI), U(VI), Np(VI), Pu(VI), Am(VI), Mn(VII), Tc(VII), Re(VII), a rare earth element, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, yttrium, and a dye.
19 . The method as claimed in claim 13 , wherein:
the cross-linking segments comprise divinylbenzene,
the weak base anion resin comprises a polymer selected from a group consisting of: poly(vinylamine-co-divinylbenzene), poly(N-methylvinylamine-co-divinylbenzene), poly(N,N-dimethylvinylamine-co-divinylbenzene), poly(N-methyl-N-ethylvinylamine-co-divinylbenzene), and poly(N,N-diethylvinylamine-co-divinylbenzene), and
the ions comprise an anion and a cation, wherein the cation is selected from a group consisting of: a proton, an inorganic cation, an organic acid, a metal cation, Li(I), Na(I), K(I), Cu(I), Rb(I), Ag(I), Cs(I), Au(I), Hg(I), Tl(I), At(I), Fr(I), Be(II), Mg(II), Ca(II), Ti(II), Cr(II), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Ge(II), Sr(II), Pd(II), Cd(II), Sn(II), Te(II), Ba(II), Pt(II), Hg(II), Pb(II), Po(II), Ra(II), Eu(II), Sm(II), Yb(II), No(II), Sc(III), Ti(III), V(III), Cr(III), Mn(III), Fe(III), Co(III), Ni(III), Ga(III), As(III), Y(III), Nb(III), Ru(III), In(III), Sb(III), La(III), Os(III), Ir(III), Au(III), Tl(III), Bi(III), Ac(III), Ce(III), Pr(III), Nd(III), Pm(III), Sm(III), Eu(III), Gd(III), Tb(III), Dy(III), Ho(III), Er(III), Tm(III), Yb(III), Lu(III), U(III), Np(III), Pu(III), Am(III), Cm(III), Bk(III), Cf(III), Es(III), Fm(III), Md(III), No(III), Lr(III), Ti(IV), V(IV), Mn(IV), Ge(IV), Zr(IV), Tc(IV), Pd(IV), Sn(IV), Te(IV), Hf(IV), Re(IV), Os(IV), Ir(IV), Pt(IV), Pb(IV), Po(IV), Ce(IV), Pa(IV), U(IV), Np(IV), Pu(IV), Am(IV), and Bk(IV), V(V), As(V), Nb(V), Sb(V), Ta(V), Bi(V), Pa(V), U(V), Np(V), Pu(V), Am(V), Cr(VI), Mo(VI), Tc(VI), Te(VI), W(VI), Re(VI), U(VI), Np(VI), Pu(VI), Am(VI), Mn(VII), Tc(VII), Re(VII), a rare earth element, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, yttrium, and a dye, and wherein the acid gas is selected from a group consisting of: sulfur oxide, sulfur monoxide, sulfur dioxide, sulfur trioxide, nitrogen oxide, nitrogen dioxide, nitrogen trioxide, nitrous oxide, dinitrogen dioxide, dinitrogen trioxide, dinitrogen tetroxide, dinitrogen pentoxide, nitrosylazide, oxatetrazol, trinitramide, hydrogen sulfide, and carbon dioxide.
20 . The method as claimed in claim 13 , wherein:
the cross-linking segments are selected from a group consisting of: diacrylate, dimethacrylate, 1,4-butanediol divinyl ether, 1,4-pentantane-3-ol, 1,4-butanediol divinyl ether, 1,4-pentantane-3-ol, and divinyl sulfone, and
the weak base anion resin comprises a polymer selected from a group consisting of: poly(vinylamine-co-dimethacrylate), poly(vinylamine-co-diacrylate), poly(vinylamine-co-1,4-butanediol divinyl ether), poly(vinylamine-co-1,4-pentantane-3-ol), poly(vinylamine-co-divinyl sulfone), poly(N-methylvinylamine-co-dimethacrylate), poly(N-methylvinylamine-co-diacrylate), poly(N-methylvinylamine-co-1,4-butanediol divinyl ether), poly(N-methylvinylamine-co-1,4-pentantane-3-ol), poly(N-methylvinylamine-co-divinyl sulfone), poly(N,N-dimethylvinylamine-co-dimethacrylate), poly(N,N-dimethylvinylamine-co-diacrylate), poly(N,N-dimethylvinylamine-co-1,4-butanediol divinyl ether), poly(N,N-dimethylvinylamine-co-1,4-pentantane-3-ol), poly(N,N-dimethylvinylamine-co-1,4-pentantane-3-ol), poly(N,N-dimethylvinylamine-co-divinyl sulfone), poly(N-methyl-N-ethylvinylamine-co-dimethacrylane), poly(N-methyl-N-ethylvinylamine-co-diacrylate), poly(N-methyl-N-ethylvinylamine-co-1,4-butanediol divinyl ether), poly(N-methyl-N-ethylvinylamine-co-1,4,-pentane-3-ol), poly(N-methyl-N-ethylvinylamine-co-divinyl sulfone), poly(N,N-diethylvinylamine-co-dimethacrylane), poly(N-methyl-N-ethylvinylamine-co-diacrylate), poly(N,N-diethylvinylamine-co-1,4-butanediol divinyl ether), and poly(N,N-diethylvinylamine-co-1,4,-pentane-3-ol), and poly(N,N-diethylvinylamine-co-divinyl sulfone), and the ions comprise an anion and a cation, and the cation is selected from a group consisting of: a proton, an inorganic cation, an organic acid, a metal cation, Li(I), Na(I), K(I), Cu(I), Rb(I), Ag(I), Cs(I), Au(I), Hg(I), Tl(I), At(I), Fr(I), Be(II), Mg(II), Ca(II), Ti(II), Cr(II), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Ge(II), Sr(II), Pd(II), Cd(II), Sn(II), Te(II), Ba(II), Pt(II), Hg(II), Pb(II), Po(II), Ra(II), Eu(II), Sm(II), Yb(II), No(II), Sc(III), Ti(III), V(III), Cr(III), Mn(III), Fe(III), Co(III), Ni(III), Ga(III), As(III), Y(III), Nb(III), Ru(III), In(III), Sb(III), La(III), Os(III), Ir(III), Au(III), Tl(III), Bi(III), Ac(III), Ce(III), Pr(III), Nd(III), Pm(III), Sm(III), Eu(III), Gd(III), Tb(III), Dy(III), Ho(III), Er(III), Tm(III), Yb(III), Lu(III), U(III), Np(III), Pu(III), Am(III), Cm(III), Bk(III), Cf(III), Es(III), Fm(III), Md(III), No(III), Lr(III), Ti(IV), V(IV), Mn(IV), Ge(IV), Zr(IV), Tc(IV), Pd(IV), Sn(IV), Te(IV), Hf(IV), Re(IV), Os(IV), Ir(IV), Pt(IV), Pb(IV), Po(IV), Ce(IV), Pa(IV), U(IV), Np(IV), Pu(IV), Am(IV), and Bk(IV), V(V), As(V), Nb(V), Sb(V), Ta(V), Bi(V), Pa(V), U(V), Np(V), Pu(V), Am(V), Cr(VI), Mo(VI), Tc(VI), Te(VI), W(VI), Re(VI), U(VI), Np(VI), Pu(VI), Am(VI), Mn(VII), Tc(VII), Re(VII), a rare earth element, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, yttrium, and a dye, and wherein the acid gas is selected from a group consisting of: sulfur oxide, sulfur monoxide, sulfur dioxide, sulfur trioxide, nitrogen oxide, nitrogen dioxide, nitrogen trioxide, nitrous oxide, dinitrogen dioxide, dinitrogen trioxide, dinitrogen tetroxide, dinitrogen pentoxide, nitrosylazide, oxatetrazol, trinitramide, hydrogen sulfide, and carbon dioxide.