IP Library Granted Patent US 12,589,599
Granted Patent B2
US 12,589,599 · App. 18/594,923 · Granted Mar 31, 2026

Diagnostic sheet and detection method for inkjet prints using paper precoat solutions

Inventors: Varun Sambhy (Pittsford, NY); Mark C. Petropoulos, Jr. (Webster, NY); Peter M. Gulvin (Webster, NY); Anthony S. Condello (Webster, NY); Seemit Praharaj (Webster, NY); Douglas K. Herrmann (Webster, NY); Christine A. Steurrys (Williamson, NY); Jason M. LeFevre (Penfield, NY); Palghat S. Ramesh (Pittsford, NY); Jorge A. Alvarez (Webster, NY); Brian Lindstrom (Victor, NY)
Assignee: XEROX CORPORATION
B41J2/2139B41J2/2114B41J2/2135B41J2/2142C09D11/54G01N31/221G06T7/001G06T7/90G06T2207/10024G06T2207/30144
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Quick Facts
Patent No.
US 12,589,599
App. No.
18/594,923
Granted
Mar 31, 2026
Kind
B2
Abstract

A diagnostic system for measuring inkjet printing system performance includes a printhead that deposits a colorless precoat solution from one or more of a plurality of ejector jets. The diagnostic system includes a diagnostic sheet, having a substrate, and a layer of material disposed on a first surface of the substrate, where the layer of material changes color after contacting the precoat solution, and an image scanner configured to capture a pattern on a surface of the diagnostic sheet after the precoat solution is deposited. The layer of material of the diagnostic sheet may include a moisture sensitive composition or a pH indicator. A method includes providing a diagnostic sheet to an inkjet printing system, where the diagnostic sheet may include a layer of material that changes color after contacting a precoat solution, and when needed, correcting one or more jetting operations.

Claims (32)

1 . A diagnostic system for measuring inkjet printing system performance, comprising:

a printhead, configured to deposit a colorless precoat solution from one or more of a plurality of ejector jets;

a diagnostic sheet, comprising:

a substrate having a first surface and a second surface; and

a layer of material disposed on the first surface of the substrate, wherein the layer of material comprises 1-(1-Hydroxy-2-naphthylazo)-6-nitro-2-naphthol-4-sulfonicacidsodium salt, 3-hydroxy-4-[(2-hydroxy-4-sulfonaphthalen-1-yl)diazenyl]naphthalene-2-carboxylic acid, 1-(1-hydroxy-4-methyl-2-phenylazo)-2-naphthol-4-sulfonic acid, or a combination thereof and the layer of material changes color after contacting the precoat solution; and

an image scanner configured to capture a color pattern on a surface of the diagnostic sheet after the precoat solution is deposited on the layer of material disposed on the first surface of the substrate.

2 . The diagnostic system of claim 1 , wherein the precoat solution comprises 5% wt to 40% wt of a salt in an aqueous solution.

3 . The diagnostic system of claim 1 , wherein the image scanner is inline with respect to the system.

4 . The diagnostic system of claim 1 , wherein the layer of material of the diagnostic sheet comprises a moisture sensitive composition.

5 . The diagnostic system of claim 4 , wherein the moisture sensitive composition comprises cobalt chloride.

6 . The diagnostic system of claim 1 , wherein the layer of material of the diagnostic sheet comprises a pH indicator.

7 . The diagnostic system of claim 1 , wherein the substrate comprises paper.

8 . The diagnostic system of claim 1 , wherein the precoat solution comprises magnesium chloride, calcium nitrate, barium, or a combination thereof.

9 . A method for diagnosing inkjet printing system performance, comprising:

providing a diagnostic sheet to an inkjet printing system, wherein the diagnostic sheet comprises a top surface comprising a layer of material that changes color after contacting a precoat solution;

depositing a quantity of a colorless precoat solution on a top surface of the diagnostic sheet, resulting in a colorimetric change of the layer of material by jetting a plurality of drops of precoat solution using a printhead comprising a plurality of individual jets;

analyzing the colorimetric change to identify a presence or location of precoat solution corresponding to one or more locations where the quantity of colorless precoat solution was deposited; and

disabling one or more jets if the presence or location of precoat solution identified on the diagnostic sheet is different than an expected presence or location.

10 . The method for diagnosing inkjet printing system performance of claim 9 , wherein the layer of material of the diagnostic sheet comprises a moisture sensitive composition.

11 . The method for diagnosing inkjet printing system performance of claim 10 , wherein the moisture sensitive composition comprises cobalt chloride.

12 . The method for diagnosing inkjet printing system performance of claim 9 , wherein layer of material of the diagnostic sheet comprises 1-(1-Hydroxy-2-naphthylazo)-6-nitro-2-naphthol-4-sulfonicacidsodium salt.

13 . The method for diagnosing inkjet printing system performance of claim 9 , wherein layer of material of the diagnostic sheet comprises a pH indicator.

14 . The method for diagnosing inkjet printing system performance of claim 9 , wherein:

analyzing the colorimetric change comprises scanning the diagnostic sheet with an image scanner; and

analyzing the colorimetric change comprises comparing a pattern of deposited precoat solution with a colorimetric change in one or more locations of the pattern of deposited precoat solution.

15 . The method for diagnosing inkjet printing system performance of claim 10 , further comprising correcting a jetting operation of one or more of the individual jets if the presence or location of precoat solution identified on the diagnostic sheet is different than an expected presence or location; and

wherein correcting a jetting operation comprises supplementing jetting using one or more additional jets, adjusting a timing of one or more individual jets, or a combination thereof.

16 . A diagnostic sheet, comprising:

a substrate having a first surface and a second surface; and

a layer of material disposed on the first surface of the substrate; and

wherein the layer of material comprises 1-(1-Hydroxy-2-naphthylazo)-6-nitro-2-naphthol-4-sulfonicacidsodium salt, 3-hydroxy-4-[(2-hydroxy-4-sulfonaphthalen-1-yl)diazenyl]naphthalene-2-carboxylic acid, 1-(1-hydroxy-4-methyl-2-phenylazo)-2-naphthol-4-sulfonic acid, or a combination thereof, and the layer of material changes color when in contact with a precoat solution.

17 . The diagnostic sheet of claim 16 , wherein the layer of material of the diagnostic sheet comprises a moisture sensitive composition or a pH indicator.

Assignments (5)
SECOND LIEN NOTES PATENT SECURITY AGREEMENT Recorded Jul 2, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 071785/0550 →
FIRST LIEN NOTES PATENT SECURITY AGREEMENT Recorded Apr 11, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 070824/0001 →
SECURITY INTEREST Recorded Apr 11, 2025
From: XEROX CORPORATION
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 070821/0219 →
SECURITY INTEREST Recorded Apr 11, 2025
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 070821/0240 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 4, 2024
From: SAMBHY, VARUN; PETROPOULOS, MARK C.; GULVIN, PETER M.; CONDELLO, ANTHONY S.; PRAHARAJ, SEEMIT; HERRMANN, DOUGLAS K.; STEURRYS, CHRISTINE A.; LEFEVRE, JASON M.; RAMESH, PALGHAT S.; ALVAREZ, JORGE A.; LINDSTROM, BRIAN
To: XEROX CORPORATION
Reel/Frame 066639/0482 →
Continuity (1)
Related Publication 20250276533A1 · Sep 4, 2025
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