ORGANOMETALLIC COMPOUND AND ORGANIC LIGHT-EMITTING DIODE INCLUDING THE SAME

1 . An organometallic compound represented by Chemical Formula 1:

Ir(L A ) m (L B ) n   Chemical Formula 1

in Chemical Formula 1,

Ir represents iridium,

m is an integer from 1 to 3, n is an integer from 0 to 2, and a sum of m and n is 3,

L A is represented by one selected from Chemical Formula 2 to Chemical Formula 4, and L B is represented by Chemical Formula 5:

in Chemical Formula 2 to Chemical Formula 4,

X is one selected from C(Rx) 2 , NRx, oxygen (O), sulfur (S), and selenium (Se),

X 1 , X 2 , X 3 , and X 4 each independently represents one selected from C(Rx) and N; at least one of X 1 , X 2 , X 3 , and X 4 is N; each Rx independently represents one selected from hydrogen, C1 to C20 linear alkyl, and C3 to C20 branched alkyl; and optionally, C1 to C20 linear alkyl, and C3 to C20 branched alkyl is each independently substituted with at least one substituent selected from deuterium and halogen,

R 1-1 , R 1-2 , R 1-3 , R 1-4 , R 2-1 , R 2-2 , R 3-1 , and R 3-2 each independently represents one selected from the group consisting of hydrogen, deuterium, halogen, C1 to C20 linear alkyl, C3 to C20 branched alkyl, C3 to C20 cycloalkyl, C3 to C20 heteroalkyl, C7 to C30 arylalkyl, C1 to C10 alkoxy, C6 to C20 aryloxy, amino, silyl, C2 to C20 alkenyl, C3 to C20 cycloalkenyl, C2 to C20 heteroalkenyl, C2 to C20 alkynyl, C6 to C30 aryl, C2 to C30 heteroaryl, and acyl, and optionally, C1 to C20 linear alkyl, C3 to C20 branched alkyl, C3 to C20 cycloalkyl, C3 to C20 heteroalkyl, C7 to C30 arylalkyl, C1 to C10 alkoxy, C6 to C20 aryloxy, amino, silyl, C2 to C20 alkenyl, C3 to C20 cycloalkenyl, C2 to C20 heteroalkenyl, C2 to C20 alkynyl, C6 to C30 aryl, C2 to C30 heteroaryl, and acyl are each independently substituted with at least one substituent selected from deuterium and halogen, and

optionally, two adjacent groups among R 1-1 , R 1-2 , R 1-3 , and R 1-4 bind to each other to form a ring structure; optionally, R 2-1 and R 2-2 bind to each other to form a ring structure; and optionally, R 3-1 and R 3-2 bind to each other to form a ring structure; and

Chemical Formula 5 represents a bidentate ligand.

2 . The organometallic compound of claim 1 , wherein R 1-1 , R 1-2 , R 1-3 , and R 1-4 each independently represents one selected from the group consisting of hydrogen, C1 to C5 linear alkyl, C3 to C10 branched alkyl, C6 to C30 aryl, and C2 to C30 heteroaryl, and

optionally, C1 to C5 linear alkyl, C3 to C10 branched alkyl, C6 to C30 aryl, and C2 to C30 heteroaryl are each independently substituted with deuterium.

3 . The organometallic compound of claim 1 , wherein R 2-1 and R 2-2 each represents hydrogen.

4 . The organometallic compound of claim 1 , wherein R 3-1 and R 3-2 each represents hydrogen.

5 . The organometallic compound of claim 1 , wherein L B includes a compound represented by one selected from the group consisting of Chemical Formula 6 and Chemical Formula 7:

in Chemical Formula 6 and Chemical Formula 7,

R 5-1 , R 5-2 , R 5-3 , R 5-4 , R 6-1 , R 6-2 , R 6-3 , and R 6-4 each independently represents one selected from the group consisting of hydrogen, deuterium, C1 to C5 linear alkyl, C3 to C5 branched alkyl, C6 to C10 aryl, C7 to C30 alkylaryl, and C7 to C30 arylalkyl, and optionally, C1 to C5 linear alkyl, C3 to C5 branched alkyl, and C7 to C30 arylalkyl is each independently substituted with at least one substituent selected from deuterium and halogen, and

optionally, two adjacent groups among R 5-1 , R 5-2 , R 5-3 , and R 5-4 bind to each other to form a ring structure; and optionally, two adjacent groups among R 6-1 , R 6-2 , R 6-3 , and R 6-4 bind to each other to form a ring structure; and

R 7 , R 8 , and R 9 each independently represents one selected from the group consisting of hydrogen, deuterium, C1 to C5 linear alkyl, and C3 to C5 branched alkyl, and optionally, C1 to C5 linear alkyl, or C3 to C5 branched alkyl as at least one selected from R 7 , R 8 , and R 9 is each independently substituted with at least one substituent selected from deuterium and halogen, and

optionally, two adjacent groups among R 7 , R 8 , and R 9 bind to each other to form a ring structure.

6 . The organometallic compound of claim 1 , wherein m is 1 and n is 2.

7 . The organometallic compound of claim 1 , wherein m is 2 and n is 1.

8 . The organometallic compound of claim 1 , wherein m is 3 and n is 0.

9 . The organometallic compound of claim 1 wherein, the organometallic compound represented by Chemical Formula 1 includes one selected from the group consisting of following compounds 1 to 549:

10 . The organometallic compound of claim 1 , wherein the compound represented by Chemical Formula 1 is a green phosphorescent material.

11 . An organic light-emitting diode comprising:

a first electrode;

a second electrode facing the first electrode; and

an organic layer disposed between the first electrode and the second electrode, the organic layer including a light-emitting layer that includes a dopant material including the organometallic compound according to claim 1 .

12 . The organic light-emitting diode of claim 11 , wherein the light-emitting layer is a green phosphorescent light-emitting layer.

13 . The organic light-emitting diode of claim 11 , wherein the organic layer further includes at least one selected from the group consisting of a hole injection layer, a hole transport layer, an electron transport layer, and an electron injection layer.

14 . An organic light-emitting diode comprising:

a first electrode;

a second electrode facing the first electrode;

a first light-emitting stack; and

a second light-emitting stack,

wherein the first light-emitting stack and the second light-emitting stack are positioned between the first electrode and the second electrode,

wherein each of the first light-emitting stack and the second light-emitting stack includes at least one light-emitting layer, and

wherein at least one of the light-emitting layers includes a green phosphorescent light-emitting layer that includes a dopant material including the organometallic compound according to claim 1 .

15 . An organic light-emitting diode comprising:

a first electrode;

a second electrode facing the first electrode;

a first light-emitting stack;

a second light-emitting stack; and

a third light-emitting stack,

wherein the first light-emitting stack, the second light-emitting stack, and the third light-emitting stack are positioned between the first electrode and the second electrode,

wherein each of the first light-emitting stack, the second light-emitting stack and the third light-emitting stack includes at least one light-emitting layer, and

wherein at least one of the light-emitting layers includes a green phosphorescent light-emitting layer that includes a dopant material including the organometallic compound according to claim 1 .

16 . An organic light-emitting display device comprising:

a substrate;

a driving element positioned on the substrate; and

an organic light-emitting element disposed on the substrate and connected to the driving element, the organic light-emitting element including the organic light-emitting diode according to claim 11 .

17 . An organometallic compound represented by Chemical Formula 1:

Ir(L A ) m (L B ) n   Chemical Formula 1

in Chemical Formula 1,

Ir represents iridium,

m is an integer from 1 to 3, n is an integer from 0 to 2, and a sum of m and n is 3,

L A is represented by Chemical Formula, and L B is represented by Chemical Formula 5:

in Chemical Formula 2,

X is one selected from C(Rx) 2 , NRx, oxygen (O), sulfur (S), and selenium (Se),

X 1 , X 2 , X 3 , and X 4 each independently represents one selected from C(Rx) and N; at least one of X 1 , X 2 , X 3 , and X 4 is N; each Rx independently represents one selected from hydrogen, C1 to C20 linear alkyl, and C3 to C20 branched alkyl; and optionally, C1 to C20 linear alkyl, and C3 to C20 branched alkyl is each independently substituted with at least one substituent selected from deuterium and halogen,

R 1- , R 1-2 , R 1-3 , R 1-4 , R 2-1 , R 2-2 , R 3-1 , and R 3-2 each independently represents one selected from the group consisting of hydrogen, deuterium, halogen, C1 to C20 linear alkyl, C3 to C20 branched alkyl, C3 to C20 cycloalkyl, C3 to C20 heteroalkyl, C7 to C30 arylalkyl, C1 to C10 alkoxy, C6 to C20 aryloxy, amino, silyl, C2 to C20 alkenyl, C3 to C20 cycloalkenyl, C2 to C20 heteroalkenyl, C2 to C20 alkynyl, C6 to C30 aryl, C2 to C30 heteroaryl, and acyl, and optionally, C1 to C20 linear alkyl, C3 to C20 branched alkyl, C3 to C20 cycloalkyl, C3 to C20 heteroalkyl, C7 to C30 arylalkyl, C1 to C10 alkoxy, C6 to C20 aryloxy, amino, silyl, C2 to C20 alkenyl, C3 to C20 cycloalkenyl, C2 to C20 heteroalkenyl, C2 to C20 alkynyl, C6 to C30 aryl, C2 to C30 heteroaryl, and acyl are each independently substituted with at least one substituent selected from deuterium and halogen, and

optionally, two adjacent groups among R 1-1 , R 1-2 , R 1-3 , and R 1-4 bind to each other to form a ring structure; optionally, R 2-1 and R 2-2 bind to each other to form a ring structure; and optionally, R 3-1 and R 3-2 bind to each other to form a ring structure; and

in Chemical Formula 6, R 5-1 , R 5-2 , R 5-3 , R 5-4 , R 6-1 , R 6-2 , R 6-3 , and R 6-4 each independently represents one selected from the group consisting of hydrogen, deuterium, C1 to C5 linear alkyl, C3 to C5 branched alkyl, C6 to C10 aryl, and C7 to C30 arylalkyl, and optionally, C1 to C5 linear alkyl, C3 to C5 branched alkyl, and C7 to C30 arylalkyl is each independently substituted with at least one substituent selected from deuterium and halogen, and

optionally, two adjacent groups among R 5-1 , R 5-2 , R 5-3 , and R 5-4 bind to each other to form a ring structure; and optionally, two adjacent groups among R 6-1 , R 6-2 , R 6-3 , and R 6-4 bind to each other to form a ring structure.

18 . The organometallic compound of claim 17 , wherein R 5-2 , R 5-3 , and R 6-3 in Chemical Formula 6 are each independently an unsubstituted or deuterium-substituted methyl group.

19 . The organometallic compound of claim 18 , wherein X is O.

20 . The organometallic compound of claim 19 , wherein the organometallic compound represented by Chemical Formula 1 includes one selected from compounds 97, 101, 109, 121, 145, 157, 169, 137, 185, and 329: