Three-dimensional printing with polyamides and cubic lattice structured particles
A particulate build material for three-dimensional printing can include from about 80 wt % to about 99.5 wt % of a polyamide particles, and from about 0.5 w % to about 7.5 wt % of thermally conductive particles including cubic lattice structured particles of carbon, cubic lattice structured particles of boron and nitrogen, or a combination thereof.
1. A particulate build material for three-dimensional printing, comprising:
from about 80 wt % to about 99.5 wt % of a polyamide particles; and
from about 0.5 w % to about 7.5 wt % of thermally conductive particles including cubic lattice structured particles of carbon, cubic lattice structured particles of boron and nitrogen, or a combination thereof.
2. The particulate build material of claim 1 , wherein the thermally conductive particles include cubic boron nitride particles, amorphous boron nitride particles, or a combination thereof.
3. The particulate build material of claim 1 , wherein the thermally conductive particles include diamond particles, diamond-like carbon particles, or a combination thereof.
4. The particulate build material of claim 1 , wherein the polyamide particles have an aspect ratio of about 1:1 to about 2:1 and a D50 particle size from about 5 μm to about 150 μm.
5. The particulate build material of claim 1 , wherein the thermally conductive particles have an aspect ratio of about 1:1 to about 2:1 and a D50 particle size from about 30 nm to about 10 μm.
6. The particulate build material of claim 1 , wherein the melting point temperature of the polyamide particles is from about 100° C. to about 350° C.
7. The particulate build material of claim 1 , wherein the polyamide particles comprise polyamide-6, polyamide-8, polyamide-10, polyamide-11, polyamide-12, polyamide-6,6, polyamide 6,10, polyamide-6,12, thermoplastic polyamide elastomer, polyamide copolymer, or a combination thereof.
8. The particulate build material of claim 1 , wherein the particulate build material consists essentially of the polyamide particles and the thermally conductive particles.
9. A three-dimensional printing system, comprising:
a particulate build material including from about 80 wt % to about 99.5 wt % of a polyamide particles and from about 0.5 w % to about 7.5 wt % of thermally conductive particles including cubic lattice structured particles of carbon, cubic lattice structured particles of boron and nitrogen, or a combination thereof; and
a fusing agent to selectively apply to the particulate build material, wherein the fusing agent comprises water and a radiation absorber to absorb radiation energy and convert the radiation energy to heat.
10. The three-dimensional printing system of claim 9 , wherein the radiation absorber is carbon black pigment, glass fiber, titanium dioxide, clay, mica, talc, barium sulfate, calcium carbonate, metal dithiolene complex, near-infrared absorbing dye, near-infrared absorbing pigment, metal nanoparticles, conjugated polymer, or a combination thereof.
11. The three-dimensional printing system of claim 9 , further comprising a detailing agent comprising a detailing compound, wherein the detailing compound reduces the temperature of particulate build material onto which the detailing agent is applied.
12. The three-dimensional printing system of claim 9 , further comprising a radiant energy source positioned to expose a layer of particulate build material to radiation energy to selectively fuse the polyamide particles that have been contacted with the radiation absorber.
13. A method of printing a three-dimensional object comprising:
iteratively applying individual layers of a particulate build material to a powder bed, wherein the particulate build material comprises from about 80 wt % to about 99.5 wt % of a polyamide particles and from about 0.5 w % to about 7.5 wt % of thermally conductive particles including cubic lattice structured particles of carbon, cubic lattice structured particles of boron and nitrogen, or a combination thereof;
based on a three-dimensional object model, selectively applying a fusing agent onto the individual layers of particulate build material, wherein the fusing agent comprises water and a radiation absorber, wherein the radiation absorber absorbs radiation energy and converts the radiation energy to heat; and
exposing the powder bed to radiation energy to selectively fuse the polyamide particles in contact with the radiation absorber at individual layers to iteratively form the three-dimensional object with the thermally conductive particles dispersed therein.
14. The method of claim 13 , wherein the thermally conductive particles include cubic boron nitride particles, amorphous boron nitride particles, diamond particles, diamond-like carbon particles, or a combination thereof; and wherein the thermally conductive particles have an aspect ratio of about 1:1 to about 1:2 and a D50 particle size from about 30 nm to about 10 μm.
15. The method of claim 13 , wherein the particulate build material consists essentially of the polyamide particles and the thermally conductive particles.