NICKEL-RICH BATTERY RECYCLING
A battery recycling process recovers lithium from nickel-rich cathode material in a recycling stream of end-of-life batteries. A dilute acid leach of a high nickel content cathode material contains a mixture of sulfuric acid based on a molar quantity of lithium in the cathode material. The highly selective leach generates a lithium rich solution with a small amount of nickel removable by nanofiltration to achieve a highly efficient recovery of the lithium contained in the recycling stream. A quantity of the leach acid based on the lithium content and a quantity of water based on a total black mass of the recycling stream results in a highly selective, near pure lithium leach when the recycling stream results from high nickel NMC batteries such as 811.
1 . A method for recycling lithium from Li-ion batteries, comprising:
combining an aqueous leach solution and a granular mass including a charge material from a Li-ion battery recycling stream, the granular mass comprising at least 80 mol % nickel;
heating the combined granular mass and aqueous leach solution to form a leach mixture; and
recovering lithium from the leach mixture, the recovered lithium comprising less than 10% nickel.
2 . The method of claim 1 , wherein the aqueous leach solution comprises a quantity of water and a quantity of a leach acid.
3 . The method of claim 2 , wherein the quantity of the leach acid is based on a molar quantity of lithium in the granular mass.
4 . The method of claim 3 , wherein the quantity of the leach acid is based on achieving a molar ratio of 0.4-0.7 of the leach acid to Li in the granular mass.
5 . The method of claim 4 , wherein the molar ratio of the leach acid to Li in the granular mass is 0.045-0.6.
6 . The method of claim 2 , wherein the leach acid is selected from the group consisting of sulfuric acid, hydrochloric acid, acetic acid, nitric acid, formic acid, oxalic acid and boric acid.
7 . The method of claim 6 , wherein the leach acid is sulfuric acid.
8 . The method of claim 2 , wherein the quantity of water is based on a weight of the granular mass.
9 . The method of claim 8 , wherein the quantity of water is based on achieving a volume/weight ratio of 1-5 of the water to the granular mass.
10 . The method of claim 1 , wherein the combined granular mass and aqueous leach solution is heated to 60-100° C.
11 . The method of claim 1 further comprising removing undissolved materials from the formed leach mixture by filtration.
12 . The method of claim 1 , wherein the recovered lithium comprises from 3%-10% nickel.
13 . The method of claim 1 , wherein the granular mass of charge materials is a black mass formed by crushing, grinding, or pulverizing end-of-life Li-ion batteries.
14 . The method of claim 13 , wherein the black mass is a comingled mass of charge materials, current collectors and casings.
15 . The method of claim 1 , wherein the granular mass of charge material is sourced from a recycling stream including batteries based on an NMC 811 chemistry.
16 . The method of claim 1 , wherein the recovered lithium is a lithium salt selected from the group consisting of lithium sulfate, lithium hydroxide, lithium carbonate, and lithium fluoride.
17 . The method of claim 16 , wherein the recovered lithium is lithium sulfate, and wherein the method comprises recovering the lithium sulfate by crystallization or by converting the lithium sulfate to lithium hydroxide, lithium carbonate, or lithium fluoride.
18 . The method of claim 1 further comprising substantially removing the nickel from the recovered lithium.
19 . The method of claim 18 , wherein the nickel is removed by nanofiltration to form an impurity-removed solution.
20 . The method of claim 19 further comprising concentrating the impurity-removed solution by reverse osmosis and crystallizing a lithium salt from the concentrated solution.