Granted Patent B2

US 6,908,960 · App. 09/748,261 · Granted Jun 21, 2005

Assignee: TDK Corporation

Abstract

Claims (73)

1. A double side metal-clad composite dielectric substrate, prepared by placing a prepreg between a pair of metal foils, followed by laminating press, and

wherein the prepreg is prepared by dispersing a polyvinylbenzyl ether compound and a dielectric ceramic powder in a solvent to form a slurry, applying the slurry to a cloth base, and drying, and wherein

the content of the dielectric ceramic powder is from 10 to 65 vol %, based on the dielectric ceramic powder and the polyvinylbenzyl ether compound combined, and

wherein the polyvinylbenzyl ether compound has the following formula (1):

wherein R 1 denotes methyl or ethyl, R 2 denotes hydrogen or a hydrocarbon group of 1 to 10 carbon atoms, R 3 denotes hydrogen or a vinylbenzyl group in a molar ratio of hydrogen to vinylbenzyl of from 60:40 to 0:100, and n is a number from 2 to 4.

2. A double side metal-clad composite dielectric substrate prepared by dispersing a polyvinylbenzyl ether compound and a dielectric ceramic powder in a solvent to form a slurry, applying the slurry onto a metal foil to form a coating, drying the coating to form a coated metal foil, and placing a cloth base between a pair of the coated metal foils, such that the coating is in contact with the cloth base, followed by laminating press, and wherein

the content of the dielectric ceramic powder is from 10 to 65 vol %, based on the dielectric ceramic powder and the polyvinylbenzyl ether compound combined, and

wherein the polyvinylbenzyl ether compound has the following formula (1):

wherein R 1 denotes methyl or ethyl, R 2 denotes hydrogen or a hydrocarbon group of 1 to 10 carbon atoms, R 3 denotes hydrogen or a vinylbenzyl group in a molar ratio of hydrogen to vinylbenzyl of from 60:40 to 0:100, and n is a number from 2 to 4.

3. The substrate of claim 2 , wherein the cloth base is glass cloth.

4. The substrate of claim 2 , wherein the dielectric ceramic powder has a mean particle size of 0.5 to 100 μm.

5. A coated metal foil, comprising a metal foil having thereon a dielectric substrate prepared from a polyvinylbenzyl ether compound and a dielectric ceramic power, and wherein the content of the dielectric ceramic powder is from 10 to 65 vol %, based on the dielectric ceramic powder and the polyvinylbenzyl ether compound combined, and

wherein the polyvinylbenzyl ether compound has the following formula (1):

wherein R 1 denotes methyl or ethyl, R 2 denotes hydrogen or a hydrocarbon group of 1 to 10 carbon atoms, R 3 denotes hydrogen or a vinylbenzyl group in a molar ratio of hydrogen to vinylbenzyl of from 60:40 to 0:100, and n is a number from 2 to 4.

6. The coated metal foil of claim 5 , wherein the metal foil is copper foil.

7. A double side metal-clad composite dielectric substrate, prepared by dispersing a polyvinylbenzyl ether compound and a dielectric ceramic powder in a solvent to form a slurry, drying and molding the slurry into a molded sheet, and placing the molded sheet between a pair of metal foils, followed by laminating press, wherein

the content of the dielectric ceramic powder is from 10 to 65 vol % based on the dielectric ceramic powder and the polyvinylbenzyl ether compound combined, and

wherein the polyvinylbenzyl ether compound has the following formula (1):

wherein R 1 denotes methyl or ethyl, R 2 denotes hydrogen or a hydrocarbon group of 1 to 10 carbon atoms, R 3 denotes hydrogen or a vinylbenzyl group in a molar ratio of hydrogen to vinylbenzyl of from 60:40 to 0:100, and n is a number from 2 to 4.

8. The composite dielectric substrate of claim 1 , wherein the metal foil is copper foil.

9. A composite dielectric substrate of multilayer construction, prepared by laminating press the coated metal foil of claim 5 .

10. The composite dielectric substrate of claim 1 , wherein the substrate maintains its dielectric constant in a high-frequency region of at least 100 MHz.

11. A prepreg prepared by dispersing a polyvinylbenzyl ether compound and a magnetic powder in a solvent to form a slurry, applying the slurry to a metal foil, and drying, and

wherein the polyvinylbenzyl ether compound has the following formula (1):

wherein R 1 denotes methyl or ethyl, R 2 denotes hydrogen or a hydrocarbon group of 1 to 10 carbon atoms, R 3 denotes hydrogen or a vinylbenzyl group in a molar ratio of hydrogen to vinylbenzyl of from 60:40 to 0:100, and n is a number from 2 to 4.

12. A substrate prepared by laminating press a prepreg prepared by dispersing a polyvinylbenzyl ether compound and a magnetic powder in a solvent to form a slurry, applying the slurry to a glass cloth, and drying, and

wherein the polyvinylbenzyl ether compound has the following formula (1):

wherein R 1 denotes methyl or ethyl, R 2 denotes hydrogen or a hydrocarbon group of 1 to 10 carbon atoms, R 3 denotes hydrogen or a vinylbenzyl group in a molar ratio of hydrogen to vinylbenzyl of from 60:40 to 0:100, and n is a number from 2 to 4.

13. A double side metal foil-clad substrate, prepared by placing metal foils on opposite surfaces of a prepreg, followed by laminating press,

wherein the prepreg is prepared by dispersing a polyvinylbenzyl ether compound and a magnetic powder in a solvent to form a slurry, applying the slurry to a glass cloth, and drying, and

wherein the polyvinylbenzyl ether compound has the following formula (1):

wherein R 1 denotes methyl or ethyl, R 2 denotes hydrogen or a hydrocarbon group of 1 to 10 carbon atoms, R 3 denotes hydrogen or a vinylbenzyl group in a molar ratio of hydrogen to vinylbenzyl of from 60:40 to 0:100, and n is a number from 2 to 4.

14. A double side metal foil-clad substrate prepared by placing two plies of the prepreg of claim 11 on opposite surfaces of a glass cloth, such that the metal foils are positioned outside, followed by laminating press.

15. A substrate prepared by laminating press a prepreg, prepared by mixing a polyvinylbenzyl ether compound and a magnetic powder at a temperature of not lower than the melting point of the polyvinylbenzyl ether compound, and molding the resulting solid mixture under pressure, and

wherein the polyvinylbenzyl ether compound has the following formula (1):

wherein R 1 denotes methyl or ethyl, R 2 denotes hydrogen or a hydrocarbon group of 1 to 10 carbon atoms, R 3 denotes hydrogen or a vinylbenzyl group in a molar ratio of hydrogen to vinylbenzyl of from 60:40 to 0:100, and n is a number from 2 to 4.

16. A double side metal foil-clad substrate, prepared by placing metal foils on opposite surfaces of a prepreg, followed by laminating press, and

wherein the prepreg is prepared by mixing a polyvinylbenzyl ether compound and a magnetic powder at a temperature of not lower than the melting point of the polyvinylbenzyl ether compound, and molding the resulting solid mixture under pressure, and

wherein the polyvinylbenzyl ether compound has the following formula (1):

wherein R 1 denotes methyl or ethyl, R 2 denotes hydrogen or a hydrocarbon group of 1 to 10 carbon atoms, R 3 denotes hydrogen or a vinylbenzyl group in a molar ratio of hydrogen to vinylbenzyl of from 60:40 to 0:100, and n is a number from 2 to 4.

17. A multilayer substrate, prepared by stacking at least two plies of a prepreg, followed by laminating press, and

wherein the prepreg is prepared by mixing a polyvinylbenzyl ether compound and a magnetic powder at a temperature of not lower than the melting point of the polyvinylbenzyl ether compound, and molding the resulting solid mixture under pressure, and

wherein the polyvinylbenzyl ether compound has the following formula (1):

wherein R 1 denotes methyl or ethyl, R 2 denotes hydrogen or a hydrocarbon group of 1 to 10 carbon atoms, R 3 denotes hydrogen or a vinylbenzyl group in a molar ratio of hydrogen to vinylbenzyl of from 60:40 to 0:100, and n is a number from 2 to 4.

18. A prepreg prepared by dispersing a polyvinylbenzyl ether compound and a flame retardant in a solvent to form a slurry, applying the slurry to a metal foil, and drying, and

wherein the polyvinylbenzyl ether compound has the following formula (1):

wherein R 1 denotes methyl or ethyl, R 2 denotes hydrogen or a hydrocarbon group of 1 to 10 carbon atoms, R 3 denotes hydrogen or a vinylbenzyl group in a molar ratio of hydrogen to vinylbenzyl of from 60:40 to 0:100, and n is a number from 2 to 4.

19. A substrate, prepared by laminating press a prepreg, prepared by dispersing a polyvinylbenzyl ether compound and a flame retardant in a solvent to form a slurry, applying the slurry to a glass cloth, and drying, and

wherein the polyvinylbenzyl ether compound has the following formula (1):

wherein R 1 denotes methyl or ethyl, R 2 denotes hydrogen or a hydrocarbon group of 1 to 10 carbon atoms, R 3 denotes hydrogen or a vinylbenzyl group in a molar ratio of hydrogen to vinylbenzyl of from 60:40 to 0:100, and n is a number from 2 to 4.

20. A double side metal foil-clad composite dielectric substrate, prepared by placing metal foils on opposite surfaces of a prepreg, followed by laminating press, and

wherein the prepreg is prepared by dispersing a polyvinylbenzyl ether compound and a flame retardant in a solvent to form a slurry, applying the slurry to a glass cloth, and drying, and

wherein the polyvinylbenzyl ether compound has the following formula (1):

wherein R 1 denotes methyl or ethyl, R 2 denotes hydrogen or a hydrocarbon group of 1 to 10 carbon atoms, R 3 denotes hydrogen or a vinylbenzyl group in a molar ratio of hydrogen to vinylbenzyl of from 60:40 to 0:100, and n is a number from 2 to 4.

21. A double side metal foil-clad substrate, prepared by placing two plies of the prepreg of claim 18 on opposite surfaces of a glass cloth, such that the metal foils are positioned outside, followed by laminating press.

22. A prepreg prepared by mixing a polyvinylbenzyl ether compound and a flame retardant at a temperature of not lower than the melting point of the polyvinylbenzyl ether compound, and molding the resulting solid mixture under pressure, and

wherein the polyvinylbenzyl ether compound has the following formula (1):

wherein R 1 denotes methyl or ethyl, R 2 denotes hydrogen or a hydrocarbon group of 1 to 10 carbon atoms, R 3 denotes hydrogen or a vinylbenzyl group in a molar ratio of hydrogen to vinylbenzyl of from 60:40 to 0:100, and n is a number from 2 to 4.

23. A substrate which is prepared by laminating press the prepreg of claim 22 .

24. A double side metal foil-clad substrate which is prepared by placing metal foils on opposite surfaces of the prepreg of claim 22 , followed by laminating press.

25. A multilayer substrate, prepared by stacking at least two plies of a prepreg, followed by laminating press, and

wherein the prepreg is prepared by dispersing a polyvinylbenzyl ether compound and a flame retardant in a solvent to form a slurry, applying the slurry to a glass cloth, and drying, and

wherein the polyvinylbenzyl ether compound has the following formula (1):

wherein R 1 denotes methyl or ethyl, R 2 denotes hydrogen or a hydrocarbon group of 1 to 10 carbon atoms, R 3 denotes hydrogen or a vinylbenzyl group in a molar ratio of hydrogen to vinylbenzyl of from 60:40 to 0:100, and n is a number from 2 to 4.

26. An electronic part comprising at least one organic dielectric layer containing at least a polyvinylbenzyl ether compound, at least one composite magnetic layer having a magnetic powder dispersed in a polyvinylbenzyl ether compound, or at least one composite dielectric layer having a dielectric powder dispersed in a polyvinylbenzyl ether compound, and

wherein the polyvinylbenzyl ether compound has the following formula (1):

wherein R 1 denotes methyl or ethyl, R 2 denotes hydrogen or a hydrocarbon group of 1 to 10 carbon atoms, R 3 denotes hydrogen or a vinylbenzyl group in a molar ratio of hydrogen to vinylbenzyl of from 60:40 to 0:100, and n is a number from 2 to 4.

27. The electronic part of claim 26 , further comprising at least one layer containing at least reinforcing fibers.

28. The electronic part of claim 26 comprising the at least one organic dielectric layer containing the polyvinylbenzyl ether compound, and having a dielectric constant of 2.6 to 3.5 and a dielectric dissipation factor of 0.0025 to 0.005.

29. The electronic part of claim 26 , comprising the at least one composite dielectric layer having a dielectric powder dispersed in a polyvinylbenzyl ether compound, and said dielectric powder having a dielectric constant of 20 to 10,000 and a dielectric dissipation factor of 0.01 to 0.001, and said composite dielectric layer having a dielectric constant of 5 to 20 and a dielectric dissipation factor of 0.0025 to 0.0075.

30. The electronic part of claim 26 , further comprising at least one second composite dielectric layer, having a dielectric powder dispersed in a polyvinylbenzyl ether compound, and said dielectric powder having a dielectric constant of 20 to 10,000 and a dielectric dissipation factor of 0.01 to 0.0001 and being present in an amount of 40 to 65 vol %, and said second composite dielectric layer having a dielectric constant of 10 to 40 and a dielectric dissipation factor of 0.0075 to 0.025.

31. The electronic part of claim 26 , comprising the at least one composite magnetic layer, having a magnetic powder dispersed in a polyvinylbenzyl ether compound, and said magnetic powder being present in an amount of 25 to 65 vol %, and said composite magnetic layer having a magnetic permeability of 3 to 20.

32. The electronic part of claim 26 , wherein at least any one layer contains at least one flame retardant.

Assignments (1)

Priority Claims (10)

Continuity (1)